CAS 12083-48-6 MFCD00014260-Bis(Cyclopentadienyl)Vanadiumdichloride 二氯化二茂钒 TAO{mole}

Bis(Cyclopentadienyl)Vanadiumdichloride 二氯化二茂钒

CAS 12083-48-6 MFCD00014260

化学结构图

SMILES: Cl[V]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 |^1:3,4,5,6,7,8,9,10,11,12|

化学属性

Mol. Formula	C10H10Cl2V
Mol. Weight	252.03
Melting Point	250° dec.
Density	1.60
TSCA	No
Appearance	green xtl.
Stability	moisture sensitive, store cold

别名和识别编码

Chemical Name	Bis(Cyclopentadienyl)Vanadiumdichloride
MDL Number	MFCD00014260
PubChem Substance ID	87558764
Synonym	Dicyclopentadienevanadium dichloride; Dicyclopentadienyldichlorovanadium; Vanadocene, dichloride Dichlorodi-pi-cyclopentadienylvanadium 双(环戊二烯基)二氯化钒(IV) Di-π-Cyclopentadienylvanadium dichloride Dichlorobis(cyclopentadienyl)vanadium Dichlorovanadocene Vanadocene dichloride Dichlorovanadocene Vanadocene dichloride
EC Number	235-150-8
CAS Number	12083-48-6
Reaxys-RN	3940231
Beilstein Registry Number	16(4)1772
Chemical Name Translation	二氯化二茂钒

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安全信息

WGK Germany3

GHS Symbol

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310+P330
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P332+P313
P302+P352+P332+P313+P362+P364
P301+P310
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P405 Store locked up. 上锁保管。
P305+P351+P338+P337+P313
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P302+P350
P337+P313

Signal word Danger

Hazard statements

H301 Toxic if swallowed 吞食有毒
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S20 When using do not eat or drink 使用时，不得进食，饮水；

Packing GroupIII

UN Number UN3096 3285 UN3285

Risk Statements

R25 Toxic if swallowed 吞咽有毒
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R34 Causes burns 会导致灼伤

Storage condition Air & Moisture Sensitive

RTECSYW1580000

Hazard Codes T

Hazard Class6.1

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 87 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - aggression
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(3),48,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 33 ug/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   19(Suppl 21),2,1992