CAS 76-87-9 MFCD00013928-Triphenyltin Hydroxide 三苯基氢氧化锡 TAO{mole}

Triphenyltin Hydroxide 三苯基氢氧化锡

CAS 76-87-9 MFCD00013928

化学结构图

SMILES: O[Sn](c1ccccc1)(c1ccccc1)c1ccccc1

化学属性

Mol. Formula	C18H16OSn
Mol. Weight	367
Melting Point	124-126 °C(lit.)
Solubility	<0.1 G/100 ML AT 21 ºC
TSCA	Yes
Density	1.54

别名和识别编码

Chemical Name	Triphenyltin Hydroxide
CAS Number	76-87-9
Synonym	K 19 Hydroxytriphenyltin 三苯基羟基锡 TRIPHENYLTIN HYDROXIDE DU-TER(R) Triphenyltin hy Duter extra 三苯羟基锡 Fintin idrossido SUZU H(R) Triphenyl tin hydroxide fentin hydroxide (ISO) FENTIN HYDROXIDE Haitin Triphenylstannyl hydroxide ######## Triphenylstannium hydroxide brestanh47.5wpfungicide. {Chemi {Chemicalb TUBOTIN 羟基三苯基锡 Fintine hydroxyde Fentinhydroxid (ISO) duter hydroxytriphenylstannate Suzu H {uni_hambu Triphenylzinnhydroxid ENT 28009 Tptoh Fentin hydroxide SuperTin Triphenylhydroxytin; Triphenyltin hydroxide SUPER-TIN OMS 1017 Fintin hydroxid Tubotin TRIPHENYLTIN(IV) HYDROXIDE 毒菌锡氫氧化三苯錫 148-02 [3] Hydroxyde de triphenyl-etain TRIPHENYLHYDROXYTIN triph Tin, hydroxytriphenyl- Hydroxytriphenylzinn stannane, hydroxytriphenyl- 海丁三苯基 Idrossido di stagno Fenolovo TPTOH Fentinhydroxid SUZU-H Duter Ashlade flotin Hydroxytriphenylstannane dowco186 Vancide KS TPTH Triphenylhydroxytin Phenostat-H 氢氧化三苯基锡 TUBOTIN(R) {uni_ham Sunitron H Fintin hydroxyde Du-Ter NCI-C00260
MDL Number	MFCD00013928
PubChem Substance ID	6327657
Beilstein Registry Number	4139186
EC Number	200-990-6
Merck Number	14,9745
Chemical Name Translation	三苯基氢氧化锡
Wiswesser Line Notation	Q-SN-R&R&R
InChI	InChI=1S/3C6H5.H2O.Sn/c31-2-4-6-5-3-1;;/h31-5H;1H2;

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分类

Algicides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Baby Food Directives 13/2003 EC & 14/2003 EC, Chromatography, E-G, Environmental Standards, European Community: ISO, DIN and DL 152, F, FA - FL, Fungicides, Method Specific, Molluscicides, Organotins, Others, Pesticides, Pesticides & Metabolites
{uni_hamburg} no charge; metal-organic; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
{SA} Algicides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography,
{SNA} Chemical Synthesis, Organometallic

产品应用

########

安全信息

RTECSWH8575000

GHS Symbol

Precautionary statements

P273 Avoid release to the environment. 避免释放到环境中。
P301+P310
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H330 Fatal if inhaled 吸入致命
H311 Toxic in contact with skin 皮肤接触中毒
H301 Toxic if swallowed 吞食有毒
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H318 Causes serious eye damage 严重伤害眼睛
H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害

Hazard Codes T+,N T+;N

WGK Germany3

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Signal word Danger

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S1/2 None 上锁保管并避免儿童触及；

UN Number 3146 UN 3146 6.1/PG 2 UN3146

Risk Statements

R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R48/23
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R50/53
R26 Very toxic by inhalation 吸入极毒
R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性

Packing GroupIII

Hazard Class6.1

Storage condition APPROX 4°C

Restrict 剧毒化学品

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 8500 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   23,288,1972

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - mydriasis (pupillary dilation)
   Behavioral - convulsions or effect on seizure threshold
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(i

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,302,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 46 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCILB* Progress Report for Contract No. NIH-NCI-E-C-72-3252, Submitted to
   the National Cancer Institute by Litton Bionetics, Inc.  (Bethesda, MD)
   Volume(issue)/page/year: NCI-E-C-72-3252,1973

TYPE OF TEST

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - rat Embryo
DOSE/DURATION           : 19 ng/plate
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 1,190,1981

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 60 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 300,5,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 105 mg/kg
SEX/DURATION            : female 8-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(issue)/page/year: 13,281,1978

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 140 mg/kg
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - other measures of fertility
REFERENCE :
   TOANDB Toxicology Annual.  (New York, NY)  1974/75-79.  Discontinued.
   Volume(issue)/page/year: 3,281,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 140 mg/kg
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(issue)/page/year: 13,281,1978

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 130 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc.,

其他信息

注意事项:[1]与春雷霉素的混剂对苹果、葡萄、大豆和藕等作物的嫩叶敏感，因此一定要注意浓度，宜在下午4点后喷药。 [2]不能与酸和多硫化钙混用
灭火剂:砂土、干粉、泡沫
外观性质:无味白色粉末。
图谱信息:三苯基氢氧化锡(76-87-9)红外图谱(IR2) 三苯基氢氧化锡(76-87-9)质谱(MS) 三苯基氢氧化锡(76-87-9)核磁图( 13 CNMR) 三苯基氢氧化锡(76-87-9)红外图谱(IR1) 三苯基氢氧化锡(76-87-9)核磁图( 1 HNMR)
类别:农药
用途一:为非内吸保护性杀菌剂，能有效防治对铜类杀菌剂敏感的一些菌类，可防治甜菜褐斑病，马铃薯晚疫病等
Alfa Aesar:Triphenyltin hydroxide(76-87-9)
毒性分级:剧毒
储运特性:库房通风低温干燥; 与食品原料分开储运
可燃性危险特性:受热分解有毒含锡气体
用途二:保护性杀菌剂，无内吸作用。主要用于防治马铃薯晚疫病，甜菜褐斑病，大豆炭疽病、褐纹病、紫斑病，水稻稻瘟病、条斑病，胡麻叶枯病，洋葱黑班病，芹菜叶枯病，菜豆炭疽病等。除杀菌外，也可用于防治水田中的藻类和水蜗牛。用于甜菜、大豆，还有增糖、增产的作用。
急救治疗:经口中毒，立即催吐、洗胃。解毒剂为依地酸二钠钙，并配合对症治疗。
MOL 文件:76-87-9.mol
下游产品:三苯基锡醋酸盐
MSDS 信息:毒菌锡(76-87-9).msds
急性毒性:口服-大鼠 LD50: 46 毫克/公斤; 口服-小鼠 LD50: 209 毫克/公斤
刺激数据:眼睛-兔子 10 毫克中度
中毒症状:误食引起急性中毒，表现为头痛、头晕、乏力、口腔粘膜呈蓝色，口内有金属味，齿龈出血，舌发青，腹泻，腹绞痛，黑大便，重者昏迷、痉挛，血压下降等。
职业标准:TWA 0.1 毫克 (锡)/立方米; STEL 0.2 毫克 (锡)/立方米
Sigma Aldrich:76-87-9(sigmaaldrich)
TSCA:Yes