4-Tert-Butylphenylmagnesium Bromide 4-叔丁基苯基溴化镁
CAS 63488-10-8 MFCD00013244
化学结构图
SMILES: CC(C)(C)c1ccc([Mg]Br)cc1
化学属性
| Mol. Formula | C10H13BrMg |
|---|---|
| Mol. Weight | 237.42 |
| TSCA | No |
| Density | 0.952 |
| Boiling Point | 65-67 |
别名和识别编码
| Chemical Name | 4-Tert-Butylphenylmagnesium Bromide |
|---|---|
| MDL Number | MFCD00013244 |
| CAS Number | 63488-10-8 |
| PubChem Substance ID | 24859458 |
| Synonym | 4-叔丁基苯基溴化镁 溶液 |
| Chemical Name Translation | 4-叔丁基苯基溴化镁 |
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分类
- {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
安全信息
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S29 Do not empty into drains 不要排入下水道；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S39 Wear eye/face protection 戴眼睛/面孔保护装置；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R11 Highly flammable 非常易燃
- R14 Reacts violently with water 遇水会猛烈反应
- R17 Spontaneously flammable in air 在空气中能够自燃
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R34 Causes burns 会导致灼伤
- R37 Irritating to respiratory system 刺激呼吸道
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
GHS Symbol
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P222 Do not allow contact with air. 不要与空气接触。
- P231+P232
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P422 Store contents under… 存储目录在…之下。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H351 Suspected of causing cancer 怀疑致癌
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H302 Harmful if swallowed 吞食有害
