CAS 6867-30-7 MFCD00013183-Lithium, (1,2-ethanediamine-kappaN1,kappaN2)ethynyl- 乙炔锂乙二胺络合物 TAO{mole}

Lithium, (1,2-ethanediamine-kappaN1,kappaN2)ethynyl- 乙炔锂乙二胺络合物

CAS 6867-30-7 MFCD00013183

化学结构图

SMILES:

化学属性

Mol. Formula	C4H9LiN2
Mol. Weight	92
Boiling Point	110.6 °C(lit.)
Melting Point	76 °C (dec.)
Density	1.04
TSCA	Yes
Stability	对水分敏感
Flash Point	7 °F
Danger-Level	-
pH	-:-
Redox	-

别名和识别编码

Chemical Name	Lithium Acetylide-ethylenediamine
MDL Number	MFCD00013183
CAS Number	6867-30-7
PubChem Substance ID	2724010
Beilstein Registry Number	3593824
EC Number	229-967-9
Synonym	1,2-ethanediamine,compd.withlithiumacetylide(li(c2h))(1:1) LITHIUM ACETYLIDE LITHIUM ACETYLIDE ETHYLENEDIAMINE COMPLEX LITHIUM ACETYLIDE ETHYLENEDIAMINE COMPLEX: TECH., 90% LITHIUM ACETYLIDE-ETHYLENEDIAMINE COMPLE X, 25 WT. % SLURRY IN TOLUENE Lithium Acetylide-ethylenediamine (1:1) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation	乙炔锂乙二胺络合物
InChIKey	WMWSRIHFAVOHSW-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00236043
Reaxys-RN	3593824
InChI	InChI=1S/C2H8N2.C2H.Li/c3-1-2-4;1-2;/h1-4H2;1H;/q;-1;+1

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安全信息

WGK Germany3

GHS Symbol

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
P231+P232
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P301+P317
P301+P330+P331
P301+P330+P331+P310
P302+P335+P334
P302+P361+P354
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P305+P354+P338
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P316
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P335+P334
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P402+P404
P405 Store locked up. 上锁保管。
P422 Store contents under… 存储目录在…之下。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
H302 Harmful if swallowed 吞食有害
H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Signal word Danger

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；

Packing GroupII

UN Number 3131

Risk Statements

R11 Highly flammable 非常易燃
R48/20
R34 Causes burns 会导致灼伤
R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
R35 Causes severe burns 会导致严重灼伤
R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体

Storage condition +4°C 0-10°C 2-8°C 4 4℃ Moisture Sensitive 储存温度2-8℃

Hazard Codes F,C

Hazard Class4.3/8

Restrict -

其他信息

乙炔锂乙二胺络合物价格(试剂级):更新日期产品编号产品名称包装价格 2010/06/21 181250500 乙炔锂乙二胺络合物 Lithium acetylide ethylenediamine complex 85% 50 GR 1942元 2010/06/21 181251000 乙炔锂乙二胺络合物 Lithium acetylide ethylenediamine complex 85% 100 GR 3043元 2010/05/25 L12401 乙炔乙二胺共聚体锂, tech. 90% Lithium acetylide ethylenediamine complex, tech. 90% 25g 780元
下游产品:1-乙炔基-2-甲基戊烯-2-醇
Sigma Aldrich:6867-30-7(sigmaaldrich)
F:10-21
Alfa Aesar:乙炔乙二胺共聚体锂,tech.90% Lithium acetylide ethylenediamine complex, tech. 90%(6867-30-7)
敏感性:Moisture Sensitive
MOL 文件:6867-30-7.mol
Acros Organics:乙炔基锂乙二胺络合物 Lithium acetylide ethylenediamine complex, 85%(6867-30-7)