CAS 532-82-1 MFCD00012976-Chrysoidine 碱性橙2 TAO{mole}

Chrysoidine 碱性橙2

CAS 532-82-1 MFCD00012976

化学结构图

SMILES: Cl.Nc1ccc(/N=N/c2ccccc2)c(N)c1

化学属性

Mol. Formula	C12H12N4·HCl
Mol. Weight	249
Melting Point	235
Appearance	闪光棕红色结晶或粉末。溶于水呈黄光橙色，溶于乙醇和乙二醇乙醚，微溶于丙酮，不溶于苯。熔点 118-118.5℃。

别名和识别编码

Chemical Name	Chrysoidine
MDL Number	MFCD00012976
CAS Number	532-82-1
Synonym	2,4-二氨基偶氮苯盐酸盐 4-(Phenylazo)-1,3-benzenediamine, monohydrochloride 4-PHENYLAZO-1,3-PHENYLENEDIAMINE MONOHYDROCHLORIDE 4-Phenyla 4-Phenylazo-m-phenylenediamine monohydrochloride 4-Phenylazo-m-phenylenediamine monohydrochloride, Basic Orange 2, Chrysoidine Y 4-苯基偶氮-1,3-苯二胺单盐酸盐碱性橙 2 黄叱精 Y CALCOZINE CHRYSOID CHRYSOIDINE CI NO 11270 Chrysoidin Chrysoidine A Chrysoidine GN Chrysoidine GS Chrysoidine PRR Chrysoidine SL Chrysoidine SS Chrysoidine Y crystals Chrysoidine hydrochloride Diazocard chrysoidine G Sugai chrysoidine chrysoidine orange {} {} { {} {} {Ch 橘红橘黄碱性橙2 碱性菊橙菊橙黄 {Chemicalboo
Beilstein Registry Number	3724653
EC Number	208-545-8
PubChem Substance ID	24856469
Chemical Name Translation	碱性橙2
Merck Number	13,2279
Wiswesser Line Notation	ZR CZ DNUNR &GH

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

酸碱指示剂

安全信息

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H318 Causes serious eye damage 严重伤害眼睛
H302 Harmful if swallowed 吞食有害

GHS Symbol

WGK Germany2

Precautionary statements

P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P501 Dispose of contents/container to..… 处理内容物/容器.....

RTECSST3380000

Signal word Danger

Personal Protective Equipment Gloves

Hazard Codes 9

Safety Statements

S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R38 Irritating to skin 刺激皮肤
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R50/53
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险

UN Number 3077 UN 3077 9/PG 3

Packing GroupIII

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 93600 mg/kg/56W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Liver - tumors
REFERENCE :
   LANCAO Lancet.  (7 Adam St., London WC2N 6AD, UK)  V.1-    1823-
   Volume(issue)/page/year: 1,564,1982

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 94 gm/kg/57W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
REFERENCE :
   XPHPAW U.S. Public Health Service Publication.  (U.S. Government Printing
   Office, Supt. of Documents, Washington, DC 20402)  No.1-    1950-
   Volume(issue)/page/year: 149,365,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6670 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
   Behavioral - muscle weakness
   Gastrointestinal - nausea or vomiting
REFERENCE :
   TLSMA6 Trudy Leningradskogo Sanitarno-Gigienicheskogo Meditsinskogo
   Instituta.  (Leningrad, Russia) V.1-145, 1949-82.  Discontinued.
   Volume(issue)/page/year: 105,42,1974

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 100 ug/L
REFERENCE :
   VINIT* Vsesoyuznyi Institut Nauchnoi i Tekhnicheskoi Informatsii (VINITI).
   All-Union Institute of Scientific and Technical Information.  (Moscow, USSR)
    Use information broker to obtain publications. Volume(issue)/page/year:
   #428-84

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 9(Suppl
   9),1,1987

TYPE OF TEST            : Phage inhibition capacity
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   MDMIAZ Medycyna Doswiadczalna i Mikrobiologia.  For English translation, see
   EXMMAV.  (Ars Polona, POB 1001, 00-068 Warsaw 1, Poland)  V.1-    1949-
   Volume(issue)/page/year: 31,11,1979

其他信息

Acros Organics:橘红/柯衣定/碱性橙II Chrysoidin, pure(532-82-1)
上游原料:亚硝酸钠 --> 间苯二胺 --> 碘化钾淀粉试纸
方法一:以苯胺和间苯二胺为主要原料，首先将苯胺重氮化，然后与间苯二胺偶合，经结晶、过滤、干燥得成品。。。在重氮锅中加水 200L、盐酸 (31%) 317kg 和苯胺 70kg，搅拌冷却至 0-5℃，于 45min 之内加入 20%-30%亚硝酸钠溶液，加完继续反应 20-30min，用碘化钾淀粉试纸确定反应终点。于偶合锅内加入水 250L、间苯二胺 88.25kg，搅拌，升温至 65℃，至间苯二胺全部溶解，然后降温至 -4℃，并以盐酸调节 pH 值达 6-7。开始缓慢加入冷至 -4℃的重氮液，维持反应温度不大于 -2℃，加完继续反应至重氮盐消失。随后加入物料量一半量的水，升温至 95℃，加入 5kg 盐酸，搅拌均匀，静置，结晶，过滤，于 60℃干燥，得产品约 200kg。
图谱信息:碱性橙 2(532-82-1)红外图谱(IR2) 碱性橙 2(532-82-1)红外图谱(IR1)
下游产品:酸性黄 23 --> 尼扎替丁 --> 耐晒猩红RC --> 艾地苯醌 --> 叶酸 --> 猪去氧胆酸 --> 镉红 --> 2-氨基-4-硝基苯甲醚 --> 2,4-二硝基苯甲醚 --> 葡萄糖氧化酶 --> 甲基胺草磷 --> 磷钼酸 --> 5,7-二氯-8-羟基喹啉
溶于水呈黄光橙色。溶于酒精和溶纤素，微溶于丙酮，不溶于苯、二甲苯和醚；遇浓硫酸呈黄色，稀释后呈橙色；遇硝酸呈橙色。溶解度:55g/L水 (15°C)，4.75% 无水乙醇，6.0% 乙二醇乙醚（溶纤素），9.5% 无水乙二醇。
Sigma Aldrich:532-82-1(sigmaaldrich)
用途四:酸碱指示剂
方法二:将苯胺重氮化，然后与间苯二胺偶合，再经溶解、结晶、干燥即得成品。原料消耗(kg/t)间苯二胺（100%） 440苯胺 365亚硝酸钠 280盐酸（31%） 1320
碱性橙 2价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xw040003 柯衣定;桔黄; 菊橙; 黄叱精Y; 碱性菊橙; 盐酸柯衣定; 黄叱精盐酸盐 10g 180元 2010/06/21 200740500 碱性橙 2 Chrysoidin , pure 50 GR 475元
用途二:碱性橙用于腈纶纤维的染色和织物的直接印花，也用于蚕丝，羊毛和棉纤维的染色，染色坚牢度较差。还用于皮革、纸张、羽毛、草、木、竹等制品的染色。
MOL 文件:532-82-1.mol
用途三:可用于棉、腈纶、皮革、纸张、羽毛、革、木、竹等制品和蚕丝的染色。
用途一:主要用于涂料、塑料、油墨、合成树脂、陶瓷的坯体着色、平面着色