Borane Trimethylamine Complex 硼烷三甲胺络合物

CAS 75-22-9 MFCD00012420

化学结构图

75-22-9
SMILES: [BH3-][N+](C)(C)C

化学属性

Mol. Formula(CH3)3N
Mol. Weight73
Density0.81
Flash Point64°(147°F)
TSCAYes
Melting Point92-94
Boiling Point172
Solubility分解

别名和识别编码

Chemical NameBorane Trimethylamine Complex
Synonym BORANE-TRIMETHYLAMINE BORANE-TRIMETHYLAMINE COMPLEX BORON HYDRIDE TRIMETHYLAMINE Borane complex with trimethylamine (1:1) Borane trimethylamine complex Borane-trimethylamine (1:1) Methanamine, N,N-dimethyl-, compd. with borane (1:1) TMAB Trihydro(trimethylamine)boron Trihydro(trimethylamine)​boron Trimethylamine, compd. with borane (1:1) Trimethylamine-borane (1:1) Trimethylamine-borane(3)-complex(1:1) Trimethylamineborane borane,compd.withtrimethylamine(1:1) n,n-dimethyl-methanamincompd.withborane(1:1) trimethylamine,compd.withborane(1:1) trimethylamine--borane (1:1) trimethylamineborane,tmab
CAS Number75-22-9
EC Number200-850-4
Beilstein Registry Number3905060
MDL NumberMFCD00012420
PubChem Substance ID87576964
Chemical Name Translation硼烷三甲胺络合物
Reaxys-RN3905060
LabNetwork Molecule IDLN01323950
InChIKeyKQVSXUGMDCAISO-UHFFFAOYSA-N
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分类

  • {SNA} Boranes, Chemical Synthesis, Molecular Biology, Protein Modification, Protein Structural Analysis, Proteomics, Reagents for reduction of proteins, Reduction, Reduction and Oxidation, Synthetic Reagents
  • {SNA} Boranes, Chemical Synthesis, Protein Modification, Protein Structural Analysis, Reagents for reduction of proteins, Reduction,
  • {SNA} Boranes, Chemical Synthesis, Protein Modification, Reagents for reduction of proteins, Reduction, Reduction and Oxidation, Synthetic Reagents, 分子生物学, 蛋白质组学, 蛋白质

相关文献及参考

  • Short: III/35C4
  • Selective reducing agent. Reactivity in carbonyl reductions is promoted by protic or Lewis acids: J. Am. Chem. Soc., 86, 3882 (1964). In the presence of HCl, indoles are reduced to indolines: Synthesis, 508 (1974). For a review of amine boranes, see: Org. Prep. Proced. Int., 16, 335 (1984).
  • {
  • Short: III/35A

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
RTECSPA0525000
Packing GroupII
UN Number 1325 UN1325
Storage condition Moisture Sensitive 0-10 0-10°C Refrigerator
Hazard statements
  • H228 Flammable solid 易燃固体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes 4.1 F,Xn F;Xi
Hazard Class4.1

其他信息

  • 类别:有毒物质
  • 毒性分级:高毒
  • 海关编码:29420000
  • 储运特性:库房通风低温干燥, 与氧化剂, 酸类分开存放
  • 可燃性危险特性:热分解排出有毒氮氧化物气体
  • 图谱信息:硼烷-三甲胺络合物(75-22-9)红外图谱(IR1) 硼烷-三甲胺络合物(75-22-9)红外图谱(IR2) 硼烷-三甲胺络合物(75-22-9)核磁图( 13 CNMR) 硼烷-三甲胺络合物(75-22-9)质谱(MS) 硼烷-三甲胺络合物(75-22-9)核磁图( 1 HNMR)
  • 灭火剂:水,干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 急性毒性:腹腔-大鼠 LD50: 175 毫克/公斤; 腹腔-小鼠 LD50:740 毫克/公斤
  • Sigma Aldrich:75-22-9(sigmaaldrich)
  • Alfa Aesar:三甲氨基硼烷,98% Borane-trimethylamine complex, 98%(75-22-9)
  • F:10-21
  • MSDS 信息:Borane-trimethylamine complex(75-22-9).msds
  • TCI Shanghai:三甲胺硼烷 Trimethylamine Borane,>;95.0%(T)(75-22-9)
  • Acros Organics:三甲胺硼烷 Borane-trimethylaminecomplex,98%(75-22-9)
  • 敏感性:Moisture Sensitive
  • MOL 文件:75-22-9.mol
  • 硼烷-三甲胺络合物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1181 三甲胺硼烷 Trimethylamine Borane 25G 663元 2010/06/21 402741000 硼烷-三甲胺络合物 Borane-trimethylamine complex 98% 100 GR 2788元 2010/06/21 402740250 硼烷-三甲胺络合物 Borane-trimethylamine complex 98% 25 GR 733元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Aluminum Hydrides - Reduction
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Boranes - Reduction
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Boranes - Reduction
  1. Life Science 生命科学
  2. Proteomics 蛋白质组学
  3. Protein Structural Analysis - Proteomics
  4. Protein Modification - Protein Structural Analysis
  5. Reduction and Oxidation - Protein Modification
  6. Reagents for reduction of proteins - Reduction and Oxidation
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boranes
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Proteomics
  4. Protein Structural Analysis
  5. Protein Modification
  6. Reduction and Oxidation

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