2,2':5',2''-Terthiophene 2,5-二(2-噻吩基)噻吩

CAS 1081-34-1 MFCD00012167

化学结构图

1081-34-1
SMILES: c1csc(-c2ccc(-c3cccs3)s2)c1

化学属性

Mol. FormulaC12H8S3
Mol. Weight248.39
Density1.318
Melting Point93-95°C
TSCANo
Boiling Point361.3°C at 760 mmHg
Flash Point160°C/0.1mm

别名和识别编码

Chemical Name2,2':5',2''-Terthiophene
Synonym 2,2':5',2''-Terthiophene {LY} 2,2':5',2''-Terthiophene 2,2,5,2''-terthiophene alpha-terthienyl alpha-terthiophene terthiophene {} {LY} 2,2':5',2''-Terthiophene {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {} {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {} {} {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {} {} {} {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {} {} {} {} {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {} {} {} {} {} {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2':5',2''-Terthiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00012167
CAS Number1081-34-1
EC Number000-000-0
Beilstein Registry Number178604
Merck Number9174
PubChem Substance ID65067
Chemical Name Translation2,5-二(2-噻吩基)噻吩
Reaxys-RN178604
LabNetwork Molecule IDLN00186858
InChIInChI=1S/C12H8S3/c1-3-9(13-7-1)11-5-6-12(15-11)10-4-2-8-14-10/h1-8H
Canonical SMILESC1(C2=CC=C(C3=CC=CS3)S2)=CC=CS1
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分类

  • {uni_hamburg} no charge; sulfur heterocycle; aromatic; 5ring; sulfide; 1fragment
  • {SNA} Building Blocks, C10 to C20+, Chemical Synthesis, Heterocyclic Building Blocks, Organic and Printed Electronics, Synthetic Tools and Reagents, Thiophene Monomers and Building Blocks, Thiophenes, 材料科学
  • {SNA} Building Blocks, C10 to C20+, Chemical Synthesis, Heterocyclic Building Blocks, Materials Science, Organic and Printed Electronics, Synthetic Tools and Reagents, Thiophene Monomers and Building Blocks, Thiophenes

相关文献及参考

  • Short: II/3
  • Short: LC
  • Merck:14,9174 Beilstein: 19,V,9,226
  • Short: IV/7c
  • Merck:14,9174

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSWZ9717750
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。

其他信息

  • Acros Organics:alpha-Terthienyl, 99+%(1081-34-1)
  • alpha-三联噻吩价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1196 2,2':5',2''-三噻吩(=α-三联噻吩) 2,2':5',2''-Terthiophene (=alpha-Terthienyl) 5G 3140元 2014/06/02 T1196 2,2':5',2''-三噻吩(=α-三联噻吩) 2,2':5',2''-Terthiophene (=alpha-Terthienyl) 1G 1010元 2010/06/21 255372500 alpha-三联噻吩 alpha-Terthienyl 99+% 250 MG 544元
  • Sigma Aldrich:1081-34-1(sigmaaldrich)
  • Alfa Aesar:2,2':5',2''-三噻吩,99% 2,2':5',2''-Terthiophene, 99%(1081-34-1)
  • alpha-三联噻吩价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 T1196 2,2':5',2''-三噻吩(=α-三联噻吩) 2,2':5',2''-Terthiophene (=alpha-Terthienyl) 5G 5280元 2011/04/16 T1196 2,2':5',2''-三噻吩(=α-三联噻吩) 2,2':5',2''-Terthiophene (=alpha-Terthienyl) 1G 1510元 2010/06/21 255372500 alpha-三联噻吩 alpha-Terthienyl 99+% 250 MG 544元
  • 存储注意事项:氮气保护
  • 图谱信息:alpha-三联噻吩(1081-34-1)核磁图( 1 HNMR) alpha-三联噻吩(1081-34-1)质谱(MS) alpha-三联噻吩(1081-34-1)核磁图( 13 CNMR)
  • F:8-10
  • 上游原料:乙醚 --> 镁 --> 2-溴噻吩 --> 2,5-二溴噻吩
  • 检测方法:HPLC,NMR
  • MOL 文件:1081-34-1.mol
  • TCI Shanghai:alpha-三联噻吩 2,2':5',2''-Terthiophene (=alpha-Terthienyl),>;98.0%(GC)(1081-34-1)

系列性分类


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