N-Methyl-N-Methylenemethanaminium Chloride N,N-二甲基氯烯亚胺
CAS 30354-18-8 MFCD00011809
化学结构图
SMILES: [Cl-].C[N+](C)=C
化学属性
| Mol. Formula | CH2=N+(CH3)2Cl- |
|---|---|
| Mol. Weight | 93.56 |
| Melting Point | 146-148 °C(lit.) |
别名和识别编码
| Chemical Name | N-Methyl-N-Methylenemethanaminium Chloride |
|---|---|
| Synonym | Böhme's salt Dimethylformiminium chloride Eschenmoser 盐 Methylenedimethylammonium chloride N,N-二甲基氯烯亚胺 Böhme's salt Methylenedimethylammonium chloride Dimethylformiminium chloride Eschenmoser 盐 |
| CAS Number | 30354-18-8 |
| PubChem Substance ID | 24871926 |
| EC Number | 250-142-4 |
| Beilstein Registry Number | 505955 |
| MDL Number | MFCD00011809 |
| Chemical Name Translation | N,N-二甲基氯烯亚胺 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Others, Synthetic Reagents
- Building Blocks, Chemical Synthesis, Imines/Amidines, Nitrogen Compounds, Organic Building Blocks
- {SNA} C-C Bond Formation, Chemical Synthesis, Other Synthetic Reagents for C-C Bond Formation, Synthetic Reagents
相关文献及参考
- 1. Johnson, T. W.; et al. J. Med. Chem. 54 , 3393, (2011)
- 2. Percivalle, C.; et al. J. Org. Chem. 76 , 3096, (2011)
- 3. Huber, K.; et al. Synthesis , 3849, (2010)
- 4. Trzupek, J. D.; et al. J. Am. Chem. Soc. 132 , 8506, (2010)
- 5. Liedtke, A. J.; et al. J. Med. Chem. 52 , 4968, (2009)
- 6. Li, C.; et al. Angew. Chem. Int. Ed. Engl. 46 , 1448, (2007)
- Beil. 4 ,IV,153
- FT-NMR 1 (1), 1324:C
安全信息
GHS Symbol
WGK Germany3
Hazard statements
- H228 Flammable solid 易燃固体
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes
Xi
Precautionary statements
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
Signal word
Warning
Safety Statements
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
