Allyltriphenylphosphonium Bromide 烯丙基三苯基溴化鏻
CAS 1560-54-9 MFCD00011808
化学结构图
SMILES:
化学属性
| Mol. Formula | (CH2=CHCH2)(C6H5)3PBr |
|---|---|
| Mol. Weight | 383 |
| Melting Point | 222-225 °C(lit.) |
| TSCA | No |
| Solubility | 分解 |
| Stability | 易潮湿 |
别名和识别编码
| Chemical Name | Allyltriphenylphosphonium Bromide |
|---|---|
| Synonym | Triphenylallylphosphonium bromide 2-Propenyltriphenylphosphonium bromide Phosphonium, triphenyl-2-propenyl-, bromide NSC 59815 Triphenyl-prop-2-enylphosphanium bromide allyltriphenyl-phosphoniubromide ALLYLTRIPHENYLPHOSPHONIUM BROMIDE (TAL) ALLYLTRIPHENYLPHOSPHONIUM BROMIDE Triphenyl(2-propenyl)phosphonium bromide Allyltriphenylphosphoniumbromide,99% 2-Propenyltriphenylphosphonium bromide NSC 110609 NSC 59815 NSC 110609 Allyltriphenylphosphonium bromide 烯丙基三苯基溴化膦 allyltriphenylphosphonium TAL 烯丙基三苯基溴(氯)化膦 烯丙基三苯基溴化磷 烯丙基三苯基溴化鏻 |
| MDL Number | MFCD00011808 |
| PubChem Substance ID | 87562500 |
| CAS Number | 1560-54-9 |
| EC Number | 216-332-6 |
| Reaxys-RN | 3579053 |
| Beilstein Registry Number | 3579053 |
| Chemical Name Translation | 烯丙基三苯基溴化鏻 |
| InChIKey | FWYKRJUVEOBFGH-UHFFFAOYSA-M |
| Wiswesser Line Notation | 1U2PR&R&R &E |
| LabNetwork Molecule ID | LN00192641 |
| InChI | InChI=1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- Michael addition of the phosphorane to ɑß-unsaturated ketones, followed by intramolecular Wittig reaction, gives cyclohexa-1,3-dienes: Tetrahedron Lett., 4425 (1973). Further lithiation of the phosphorane in the presence of TMEDA, followed by reaction of the ylide anion with an aldehyde, provides a route to (E,E)-ß-hydroxy-1,3-dienes: Tetrahedron Lett., 32, 4353 (1991).
- Michael addition of the phosphorane to ɑß-unsaturated ketones, followed by intramolecular Wittig reaction, gives cyclohexa-1,3-dienes: Tetrahedron Lett., 4425 (1973). Further lithiation of the phosphor
- Wittig reaction (see Appendix 1) with aldehydes, using K2CO3 in toluene, gives dienes: Synth. Commun., 22, 1421 (1992). The derived phosphorane also reacts with ß-chloroacrylates to give conjugated phosphoranes, convertible to trienes: Tetrahedron Lett., 1359 (1975):
- Wittig reaction (see Appendix 1) with aldehydes, using K2CO3 in toluene, gives dienes: Synth. Commun., 22, 1421 (1992). The derived phosphorane also reacts with ß-chloroacrylates to give conjugated phosphoranes, convertible to trienes: Tetrahedron Lett., 1359 (1975):
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P332+P313+P362+P364
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 22 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01708
其他信息
- Acros Organics:烯丙基三苯基溴化磷 Allyltriphenylphosphonium bromide, 99%(1560-54-9)
- 海关编码:29310095
- Alfa Aesar:烯丙基三苯基溴化膦,99% Allyltriphenylphosphonium bromide, 99%(1560-54-9)
- 烯丙基三苯基溴化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1007 烯丙基三苯基溴化膦 Allyltriphenylphosphonium Bromide 25G 292元 2010/06/21 103041000 烯丙基三苯基溴化膦 Allyltriphenylphosphonium bromide 99% 100 GR 943元 2010/06/21 103040050 烯丙基三苯基溴化膦 Allyltriphenylphosphonium bromide 99% 5 GR 111元
- MSDS 信息:Allyltriphenylphosphonium bromide(1560-54-9).msds
- MOL 文件:1560-54-9.mol
- Sigma Aldrich:1560-54-9(sigmaaldrich)
- 敏感性:Hygroscopic
- TCI Shanghai:烯丙基三苯基溴化膦 Allyltriphenylphosphonium Bromide,>;98.0%(T)(1560-54-9)
