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• Building Blocks, Chemical Synthesis, Dendrimers, Materials Science, Nanomaterials, Organic Building Blocks, Phosphorous Dendrimers, Phosphorus Compounds, Phosphorus Halides
• {Chemicalbook} 无机化工产品: 无机盐: Cm磷化合物及磷酸盐
• {SNA} Building Blocks, Chemical Synthesis, Dendrimers, Nanomaterials, Organic Building Blocks, Phosphorous Dendrimers, Phosphorus Compounds, Phosphorus Halides, 材料科学
• {uni_hamburg} no charge; 1fragment
• {SNA} Building Blocks, Chemical Synthesis, Dendrimers, Materials Science, Nanomaterials, Organic Building Blocks, Phosphorous Dendrimers,

相关文献及参考

• Merck 14 ,7356
• Fieser 15 ,308
• Aldrich MSDS 1 , 1705:C / Corp MSDS 1 (2), 3337:A / FT-IR 2 (3), 4713:C / FT-IR 1 (2), 1230:A / IR-Spectra (3), 555:D / RegBook 1 (3), 3205:A / Sax 6 , 2574 / Structure Index 1 , 509:C:5 / Vapor Phase 3 , 1691:D
• Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
• Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 660 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 31(12),53,1987

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 31(12),53,1987

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 520 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 31(12),53,1987

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 400 mg/m3
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
REFERENCE :
   GTPZAB Gigiena Truda i Professiona

其他信息

• 用途三:三氯硫磷主要作为有机磷农药生产中广泛应用的原料，用于合成重要的含磷中间体“氯化物”和“二氯化物”，进而可得到一大批硫代磷酸酯类农药(如对硫磷、辛硫磷、二嗪磷、毒死蜱等)和硫代磷酰胺类农药(如水胺硫磷、甲基异柳磷、胺草磷等)；此外也用作有机合成磷化合物的原料。
• 毒性:三氯硫磷挥发出来的气体有毒，有刺激性和腐蚀性，对肺、黏膜和眼睛都有刺激。应防止泄漏，造成中毒事故。本品腐蚀性较强，如不慎触及皮肤容易灼伤，应立即用大量温水冲洗干净。 生产搬运人员应穿工作服，佩戴口罩、橡皮手套、橡皮围裙，穿长统胶鞋；操作应在上风头进行。
• F:21
• 外观性质:无色或浅黄色油状液体，有刺激性气味。
• 硫代磷酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 208351000 硫代磷酰氯 Thiophosphoryl chloride 98% 100 ML 614元 2010/06/21 208352500 硫代磷酰氯 Thiophosphoryl chloride 98% 250 ML 1132元 2010/06/21 208350010 硫代磷酰氯 Thiophosphoryl
• 灭火剂:砂土、二氧化碳
• 毒性分级:中毒
• 类别:腐蚀物品
• 储运特性:库房通风低温干燥; 与碱类、氧化剂、食品填加剂分开存放
• MOL 文件:3982-91-0.mol
• 下游产品:糠醇 --> 二乙基硫代磷酰氯 --> 甲胺磷 --> 喹硫磷 --> 甲基对硫磷 --> 辛硫磷 --> 杀螟松 --> 丙溴磷 --> 地虫磷 --> 水胺硫磷 --> 水胺硫磷乳油 --> 不对称有机磷农药的含磷中间体 --> 二甲基硫代磷酰氯 --> 二甲基硫代磷酰氯 --> 噻唑磷 --> 硫丙磷 --> 异柳磷 --> 毒鼠磷 --> O-甲基硫代磷酰二氯 --> O,O-二烷基硫代磷酰氯(简称氯化物) --> 吡唑硫磷 --> 蔬果磷,水杨硫磷 --> 异丙氧磷 --> 哒嗪硫磷 --> S-丙基二硫代磷酰二氯 --> O,O-二烷基硫(醇)代磷酸盐 --> O,O-(二-对氯苯基)硫代磷酰氯 --> 硫代氯磷酸二对溴苯酯 --> O-乙基硫代磷酰二氯 --> 内吸磷 --> 苯硫磷酯
• Acros Organics:硫代磷酰氯 Thiophosphoryl chloride, 98%(3982-91-0)
• 方法一:其制备方法是通过三氯化磷与硫磺在催化剂三氯化铝存在下加热反应而制得。 即在反应器中先加入适量的催化剂，然后将加热到140℃的熔融硫磺加入反应器中，将反应器加热到液相温度为140～160℃、气相温度为125～130℃时，按硫：三氯化磷质量比为1∶4.3加入三氯化磷，反应生成三氯硫磷，再经回流冷凝、分离，得到三氯硫磷成品。此外，也可由五硫化二磷与五氯化磷作用得到三氯硫磷。
• 上游原料:硫磺 --> 三氯化磷 --> 五氯化磷 --> 五硫化二磷 --> 红磷 --> 硫磺 --> 黄磷
• 用途二:主要用作生产有机磷农药如甲基对硫磷、二甲基硫代磷酰氯、二乙基硫代磷酰氯和甲胺磷、倍硫磷、禾螟松等高效低毒有机磷农药的原料，也用作有机合成磷化合物的原料。
• 参考质量标准:参考标准 指标名称 指标 外观 无色透明液体 三氯硫磷(PSC13)/%≥ 98 水洗减量/% 2 游离硫黄 测定水洗减量的试样中不应析出硫黄
• 方法二:合成法在反应器中先加入适量的催化剂，然后将加热到140℃的熔融硫黄加人反应器中，将反应器加热至液相温度为140～160℃、气相温度为125～130℃时，按投料比(质量比值)S：PCI3=1：4.3向反应器加入适量的三氯化磷，进行反应生成三氯硫磷，由反应器连续蒸出，经回流冷凝、分离，制得三氯硫磷
• MSDS 信息:硫代磷酰氯(3982-91-0).msds
• 用途一:主要用于生产甲基对硫磷、二甲基硫代磷酰氯、甲胺磷、倍硫磷、禾螟松等农药以及有机磷化合物
• Sigma Aldrich:3982-91-0(sigmaaldrich)