CAS 7664-41-7 MFCD00011418-Ammonia 氨 TAO{mole} - 淘摩尔专家级采购助手

Ammonia 氨

CAS 7664-41-7 MFCD00011418

化学结构图

SMILES: N

化学属性

Mol. Formula	NH3
Mol. Weight	17.03
Density	1.023
TSCA	Yes
Autoignition Point	1203 °F
Vapor Density	0.6 (vs air)
Boiling Point	-33 °C(lit.)
Vapor Pressure	8.75 atm ( 21 °C)
Melting Point	-78
Flash Point	6°C(lit.)
Solubility	可溶
Appearance	1.5640，溶于苯、甲苯等溶剂，不溶于水。 D 对氯苯甲醛是白色固体，m.p.46～47℃，b.p.213～214℃，n 20
pH	:A

别名和识别编码

Chemical Name	Ammonia
Synonym	4-氯苯甲醛 AM-Fol AMMONIA 10 ION CHROMATOGRAPHY STANDARD AMMONIA 10K ION CHROMATOGRAPHY STANDARD AMMONIA 1K ION CHROMATOGRAPHY STANDARD AMMONIA MONITOR REAGENT 1 AMMONIA MONITOR REAGENT 2 AMMONIA MONITOR SECOND REAGENT AMMONIA SOLUTION, STRONG AMMONIA, FREE REAGENT Ammonia Ammonia anhydrous Ammonium hydroxide H₃N (ammonia) Hydrogennitrid Nitro-Sil R 717 Refrigerent R717 am-fol, ammonia(anhydrous), ammoniaanhydrous ammonia ammonia, anhydrous 氨氨溶液氨水水质氨（水剂）标样
MDL Number	MFCD00011418
EC Number	231-635-3
CAS Number	7664-41-7
Merck Number	492
Beilstein Registry Number	3587154
PubChem Substance ID	222
Reaxys-RN	3587154
Chemical Name Translation	氨
Wiswesser Line Notation	ZH
LabNetwork Molecule ID	LN00163871
InChI	InChI=1S/H3N/h1H3

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安全信息

RTECSBO0875000

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

UN Number 1165 1219 1992 3286 UN 1219 3/PG 2 UN2672

Risk Statements

R11 Highly flammable 非常易燃
R19 May form explosive peroxides 可能生成易爆的过氧化物质
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R34 Causes burns 会导致灼伤
R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R50 Very toxic to aquatic organisms 对水生生物极毒
R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂

Signal word Danger

GHS Symbol

WGK Germany2

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241+P242+P243
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P301+P310
P301+P330+P331
P302+P352+P332+P313+P362+P364
P303+P361+P353
P304+P312
P304+P340
P304+P340+P312
P305+P351+P338
P305+P351+P338+P310
P305+P351+P338+P337+P313
P308+P311
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. 漏气着火：切勿灭火，除非漏气能够被安全地制止。
P381 Eliminate all ignition sources if safe to do so. 如果安全的话，消除所有点火源。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403 Store in a well-ventilated place. 储存在通风良好的地方。
P403+P233
P405 Store locked up. 上锁保管。
P410+P403
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H221 Flammable gas 易燃气体。
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H280 Contains gas under pressure; may explode if heated 内含高压气体，遇热可能爆炸。
H301 Toxic if swallowed 吞食有毒
H302 Harmful if swallowed 吞食有害
H311 Toxic in contact with skin 皮肤接触中毒
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H319 Causes serious eye irritation 严重刺激眼睛
H331 Toxic if inhaled 吸入中毒
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌
H370 Causes damage to organs 导致器官损伤
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

Packing GroupII

Storage condition 0-10 0-6°C 0-10°C Hygroscopic

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Faceshields, Gloves, Goggles, half-mask respirator (US), multi-purpose combination respirator cartridge (US)

Hazard Codes 3 8 F,C,N,Xn F,T T,N

Hazard Class3/6.1

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1680 mg/kg/24W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Gastrointestinal - tumors
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   65,15,1992

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 20 ppm
TOXIC EFFECTS :

TYPE OF TEST            : TDLo - Lowe

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 15 uL/kg
TOXIC EFFECTS :
   Gastrointestinal - changes in structure or function of esophagus
REFERENCE :
   AJEMEN American Journal of Emergency Medicine.  (WB Saunders, Philadelphia,
   PA)  V.1-    1983-  Volume(issue)/page/year: 3,320,1985

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 5000 ppm/5M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TABIA2 Tabulae Biologicae.  (The Hague, Netherlands)  V.1-22, 1925-63.
   Discontinued.  Volume(issue)/page/year: 3,231,1933

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 7 gm/m3/1H
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Behavioral - excitement
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 26,29,1944

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Che

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TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 19800 ug/m3/16W
REFERENCE :
   BZARAZ Biologicheskii Zhurnal Armenii.  Biological Journal of Armenia. (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.19-    1966-
   Volume(issue)/page/year: 27(6),102,1974

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 1500 ppm/3H
REFERENCE :
   AMNTA4 American Naturalist.  (Univ. of Chicago Press, Journals Div., POB
   37005, Chicago, IL 60637) V.1-    1867-  Volume(issue)/page/year:
   85,119,1951

Restrict 危险品

其他信息

4-氯苯甲醛价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 C150441000 4-氯苯甲醛;对氯苯甲醛 100g 242元 2011/08/23 A11221602 4-氯苯甲醛;对氯苯甲醛 250g 527元 2011/08/23 K2349101 4-氯苯甲醛;对氯苯甲醛
急性毒性:吸入- 大鼠 LC50:2000 PPM/4小时; 吸入- 小鼠 LC50:4230 PPM/1小时
{Chem
{
用途一:主要用于制造镇静药芬那露、氨苯酪酸等医药原料及中间体，在农药上用以制造氯肉桂醛，除草杀敌散等
外观性质:无色、有刺激性恶臭的气体。
Alfa Aesar:4-氯苯甲醛,98% 4-Chlorobenzaldehyde, 98%(104-88-1)
下游产品:2,4-二硝基苯胺 --> (+)-1-苯基-2-(对甲基苯基)乙胺 --> 丙酰胺 --> 氮化硼 --> 4-氯-3-硝基苯甲醛 --> 虫螨腈 --> 十二烷基伯胺 --> 酒石酸铵 --> 盐酸氯苯胍 --> 双硫腙 --> N-乙酰-L-谷氨酰胺 --> 2,5-二甲氧基-2,5-二氢呋喃 --> 非氨酯 --> 3,4-亚甲二氧苯乙胺 --> 烯效唑 --> 钛酸四丁酯 --> 酸性蓝 83 --> 卡特缩合剂 --> N-(4-氯苄基)-N-甲胺 --> 巴氯芬 --> 合成加脂剂 --> 2-对氯苯基肌氨酸 --> 2-氨基-2-苯基乙酸 --> 新铜铁灵 --> O,O-二异丙基硫代磷酸铵 --> 环丙氨嗪 --> 4-氯苄基频那酮 --> N-苯基甘氨酸 --> 芬那露 --> 4-苯氧基-2,6-二异丙基苯硫代异氰酸酯 --> 4-氯肉桂酸 --> 1-氨基蒽醌-2-羧酸 --> 烯效唑 --> 烯效唑可湿性粉剂 --> 2,2'-二羟基-3,5,3',5',4''-五氯三苯基甲烷-2''-磺酸钠 --> 奥卡西平 --> 3-(乙磺酰基)-2-吡啶磺酰胺
上游原料:乙酸 --> 氢氧化铵 --> 氮 -->
对氯苯甲醛:对氯苯甲醛又名4-氯苯甲醛。无色片状结晶至淡黄色粉末。分子量140.57。熔点47.5℃。沸点213～214℃。相对密度1.196 (61/4℃)。折射率1.5552 (61℃)。闪点87℃。不溶于水，易溶于乙醇、乙醚、苯，溶于水、丙酮。能随水蒸气挥发。用作医药、染料中间体，用于制造芬那露、氨苯氨酪酸等。由对氯甲苯氯化水解而得。也可由对氯甲苯二氧化锰氧化而得。还能由对氯甲苯用空气氧化制取。制备植物生长调节剂多效唑：以对氯苯甲醛和2，2-二甲基-3-丁酮为原料，在氢氧化钠和叔丁醇溶液中反应，生成1-(2，2-二甲基-3-酮-4-戊烯)对氯苯，在乙酸乙酯溶液中，以镍为催化剂，高温下加氢，生成1-(2，2-二甲基-3-戊酮)对氯苯，在四氯化碳溶液中，加溴，生成1-(2，2-二甲基-4-溴-3-戊酮)对氯苯，进一步在丙酮溶液中与1，2，4-三唑反应，最后在硼氢化钠的甲醇溶液中，生成多效唑。巴氯芬用作脊椎的骨骼肌松弛剂和镇痉剂。由对氯苯甲醛与乙酰乙酸乙酯缩合生成对氯代苯亚甲基-双-乙酰乙酸乙酯。加热水解得对氯代苯基戊二酸。用乙酐脱水环合生成对氯代苯基戊二酸酐。再用浓氨水胺化生成对氯代苯基戊二酸亚酰胺，最后开环、降解而得。
用途五:主要用于大规模集成电路减压或等离子体CVD，以生长二氧化硅膜
{Chemica
TCI Shanghai:氨(约4%的甲醇溶液,约2.0mol/L) Ammonia (ca. 4% in Methanol, ca. 2.0mol/L)(7664-41-7)
Alfa Aesar:氨水,2M甲醇溶液 Amm
用途三:用于制造镇静药芬那露、染料酸性艳蓝6B等
用途九:用作致冷剂及制取铵盐和氮肥。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。
用途二:用于化工、食品、医药等行业
检测方法:GC,NMR
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可燃性危险特性:在空气中明火可燃; 遇水产生有腐蚀性的氨水; 燃烧产生有毒氮氧化物和氨气体
{Chemicalbo