Iodine Monobromide 一溴化碘
CAS 7789-33-5 MFCD00011353
化学结构图
SMILES: BrI
化学属性
| Mol. Formula | I Br |
|---|---|
| Mol. Weight | 206.81 |
| Density | 4.41 |
| Flash Point | None |
| TSCA | Yes |
| Boiling Point | |
| Melting Point | No Data Available |
| Stability | 对光和潮气和空气敏感 |
| Solubility | 溶于水。 |
别名和识别编码
| Chemical Name | Iodine Monobromide |
|---|---|
| MDL Number | MFCD00011353 |
| Synonym | BROMINE IODIDE Bromine iodide Bromoiodine HANUS SOL FOR THE DET. OF IODINE VALUE IBr IODINE 0,1 MOL IBR/L, VOLUMETRIC SOLUTIO N ACCORDING TO HANUS IODINE BROMIDE Iodine Monobromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
| EC Number | 232-159-9 |
| CAS Number | 7789-33-5 |
| Merck Number | 14,5016 |
| Beilstein Registry Number | 3902973 |
| PubChem Substance ID | 82238 |
| Chemical Name Translation | 一溴化碘 |
| LabNetwork Molecule ID | LN02127159 |
| InChI | InChI=1S/BrI/c1-2 |
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分类
- {SNA} Analytical Reagents, Analytical/Chromatography, C-X Bond Formation (Halogen), Chemical Synthesis, G - M, Halogenated Solutions, Iodine and Iodide solutions, Most common compounds for volumetric titration, Others, Salt Solutions, Synthetic Reagents, Titration,
- {SNA} C-X Bond Formation (Halogen),
相关文献及参考
- Reagent for mild, selective deprotection of TBDMS ethers in carbohydrates and nucleosides: Synlett, 311 (1999).
- Merck: 14,5016
- Also found to give higher diastereoselectivity than iodine in the cyclization of certain homoallylic carbonates: Tetrahedron Lett., 33, 6439 (1992).
- Selective brominating agent, considered to be intermediate in electrophilic power between bromine and iodine: J. Chem. Soc., 1509 (1939); J. Am. Chem. Soc., 60, 256 (1938); Chem. Commun., 849 (1968).
- Short: II/24A
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R10 Flammable 易燃
- R34 Causes burns 会导致灼伤
- R35 Causes severe burns 会导致严重灼伤
- R37 Irritating to respiratory system 刺激呼吸道
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H351 Suspected of causing cancer 怀疑致癌
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H226 Flammable liquid and vapour 易燃液体和蒸气
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
其他信息
- 用途一:用于有机合成
- MSDS 信息:溴化碘(7789-33-5).msds
- MOL 文件:7789-33-5.mol
- F:1-8
- Sigma Aldrich:7789-33-5(sigmaaldrich)
- 溶于水，溶于乙醇、乙醚、二硫化碳和冰醋酸。
- 敏感性:Moisture & Light Sensitive
- 一溴化碘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A22484701 一溴化碘 50g 727元 2010/06/21 208842500 一溴化碘 Iodine monobromide 98% 250 GR 2533元 2010/06/21 208840500 一溴化碘 Iodine monobromide 98% 50 GR 695元
- 外观性质:黑褐色晶体。
- Acros Organics:一溴化碘 Iodine monobromide, 98%(7789-33-5)
- Alfa Aesar:单溴化碘,99%min Iodine monobromide, 98% min(7789-33-5)
