Decaborane 癸硼烷

CAS 17702-41-9 MFCD00011314

化学结构图

17702-41-9
SMILES: [B][B][B][B][B][B][B][B][B][B]

化学属性

Mol. Weight122.24
Density0.94
Mol. FormulaB10H14
Boiling Point213°C
Vapor Pressure0.15 mmHg ( 20 °C)
Melting Point99-103°C
SolubilitySlightly soluble in cold water. Hydrolyzes in hot water. Soluble in ethyl acetate, 1-Bromopropane, ethyl silicate, benzene, alcohol, and carbon tetrachloride
TSCAYes
Flash Point213°C

别名和识别编码

Synonym nido-B10H14 nido-Decaborane(14) B10H14 Boron hydride Boron hydride (B10H14) DECABORANE DECABORANE(14) DECABORANE(14) TECH. DECABORANE(14) WHITE Decaboran(14) Decaboran-14 Decaborane Decaborane (B10H14) Decaborane (non-isotopic, high purity) Decaborane(14) Decaborane(14), white,98% Decaborane(B10H14) Decaborane,min.97% Decaboron tetradecahydride Tetradecahydrodecaborane boronhydride(b10h14) decaborane (14) decaboron tetradecahydride decaborontetradecahydride nido-B10H14 nido-Decaborane(14) 十硼氢 十硼烷 癸硼烷 癸硼烷; 十硼烷
EC Number241-711-8
MDL NumberMFCD00011314
CAS Number17702-41-9
Merck Number14,2845
Chemical NameDecaborane(14)
InChIKeySXQKYQKNQZAWBF-UHFFFAOYSA-N
Chemical Name Translation癸硼烷
Wiswesser Line NotationH2 B10-H12
Beilstein Registry Number
PubChem Substance ID6328162
InChIInChI=1S/B10/c1-3-5-7-9-10-8-6-4-2
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分类

  • {uni_hamburg} no charge; other heterocycle; alicycle; large ring; fused rings; 3ring; 4ring; 5ring; 6ring; 7ring; 8ring; 9ring; 10ring; 11ring; 12ring; 13ring; 14ring; spiro; 1fragment
  • {SNA} Boranes, Chemical Synthesis, Reduction, Synthetic Reagents

产品应用

  • In rocket propellants, and as a catalyst in olefin polymerization
  • Boron source for ion-implantation processes.

相关文献及参考

  • Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25A Year: 1998 Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules ISBN: 3-540-61713-2 ISBN: 978-3-540-61713-6 Internet Resource: DOI:10.1007/b59072 RefComment: VII, 359 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cu Author: Chi

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H330 Fatal if inhaled 吸入致命
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H228 Flammable solid 易燃固体
  • H301+H311
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges
RTECSHD1400000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301 IF SWALLOWED: 如果吞下去
  • P305 IF IN EYES: 如果进入眼睛
Signal word Danger
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Packing GroupII
UN Number 1868 UN1868
Risk Statements
  • R11 Highly flammable 非常易燃
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R26 Very toxic by inhalation 吸入极毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R5 Heating may cause an explosion 加热会引起爆炸
Hazard Codes F,T+
Storage condition Flammables area
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 33 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 11,132,1955

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 71 mg/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (i

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 28 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 8,335,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 740 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 11,132,1955

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inh

其他信息

  • MOL 文件:17702-41-9.mol
  • 癸硼烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 211020010 癸硼烷 Decaborane(14), white 98% 1 GR 760元 2010/06/21 211020050 癸硼烷 Decaborane(14), white 98% 5 GR 2895元
  • 外观性质:无色结晶。
  • HazardClass:4.1
  • PackingGroup:II
  • RTECS号:HD1400000

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Aluminum Hydrides - Reduction
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Boranes - Reduction

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