CAS 1345-04-6 MFCD00011217-Lymphoscan 硫化锑 TAO{mole}

Lymphoscan 硫化锑

CAS 1345-04-6 MFCD00011217

化学结构图

SMILES: S=[Sb]S[Sb]=S

化学属性

Mol. Formula	Sb2S3
Mol. Weight	340
TSCA	Yes
Melting Point	550 °C (lit.)
Solubility	Insoluble in water. Soluble in HCl with H2S evolution
Density	4.64 g/mL at 25 °C(lit.)
Boiling Point	1150 °C
Appearance	powder
Refractive index	3.194
Stability	对湿度敏感

别名和识别编码

Chemical Name	Antimony(III) sulfide
Synonym	ANTIMONY (II) SULFIDE ANTIMONY OXYSULFIDE ANTIMONY RED ANTIMONY SULFIDE, OXY ANTIMONY SULFIDE, TRI ANTIMONY TRISULFIDE-RED ANTIMONY(+3)SULFIDE Antimonite Antimontrisulfid Antimony sulfide Antimony sulfide (Sb4S6) Antimony trisulfide colloid Antimony(3+) sulfide C.I. 77060 Diantimony Trisulphide Diantimony trisulfide IMMU-LL2-Fab LymphoSCAN MAb LL2 (EPB2) STIBNITE antimony (III) sulphide antimony trisulfide antimonyorange antimonysesquisulfide bectumomab monoclonal antibody IMMU-LL2-Fab stibnite {} {C {} {} {C {} {} {} {Che {} {} {} {} {Chemical {} {} {} {} {} {} { {} {} {} {} {} {} {Chemicalboo {} {} {} {
MDL Number	MFCD00011217
CAS Number	1345-04-6
EC Number	215-713-4
Merck Number	14,713
PubChem Substance ID	16685273
Chemical Name Translation	硫化锑
Wiswesser Line Notation	SB2 S3
InChI	InChI=1S/3S.2Sb

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产品应用

橡胶硫化剂。焰火、玻璃、炸药、油漆颜料的制造。

安全信息

Safety Statements

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Packing GroupIII

UN Number UN1549 UN 1549 6.1/PG 3

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
R51/53

WGK Germany2

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P317
P304+P340
P305+P351+P338
P317
P319
P330 Rinse mouth. 漱口
P337+P317
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning

Hazard statements

H302 Harmful if swallowed 吞食有害
H302+H332
H332 Harmful if inhaled 吸入有害
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。

GHS Symbol

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes Xn,N Xn

Hazard Class6.1

RTECSCC9450000

Storage condition 密封保存。

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1390 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   INMEAF Industrial Medicine.  (Chicago, IL)  V.1-18, 1932-49.  For publisher
   information, see IOHSA5.  Volume(issue)/page/year: 10,15,1941

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : >139 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 8(7),25,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 209 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,23,1982

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 580 ug/m3/35W
TOXIC EFFECTS :
   Cardiac - EKG changes not diagnostic of specified effects
   Vascular - BP elevation not characterized in autonomic section
   Gastrointestinal - ulceration or bleeding from st

其他信息

上游原料:硫酸 --> 三氧化二锑 --> 锑
{Chem
储运特性:库房通风低温干燥; 与酸类, 食品分开储运
灭火剂:水, 砂土
露置空气中逐渐氧化。亦溶于不挥发氢氧化碱溶液中，溶于浓盐酸并放出硫化氢，不溶于水。纯三硫化二锑为黄红色无定形粉末，不溶于水和醋酸，溶于浓盐酸、醇、硫化铵和硫化钾溶液。烟花爆竹行业所用硫化锑为辉锑矿矿石粉加工而成，为黑色或灰黑色粉末，有金属光泽，不溶于水，具强还原性。有毒，最小致死量(大鼠，腹腔)1000mg/kg。
毒性:三价锑化合物具有强的刺激作用。急性中毒表现对呼吸道和消化道及皮肤的刺激作用。最高容许浓度硫化锑(换算成Sb)规定为1 mg/m 3 。工作人员要佩戴防毒口罩等劳保防护用具。
Sigma Aldrich:1345-04-6(sigmaaldrich)
MOL 文件:1345-04-6.mol
图谱信息:
类别:有毒物品
硫化锑价格(试剂级):更新日期产品编号产品名称包装价格 2010/06/21 223591000 硫化锑 Antimony(III) sulfide 98% 100 GR 293元 2010/06/21 223595000 硫化锑 Antimony(III) sulfide 98% 500 GR 1059元 2010/05/25 12521 硫化锑, 98% (metals basis) Antimony(III) sulfide, 98% (metals basis) 250g 496元
Alfa Aesar:天然辉锑矿,approximately0.06-0.19in Stibnite, naturally occuring mineral, approximatel
职业标准:TWA 0.5 毫克 (锑)/立方米; STEL 2.5 毫克 (锑)/立方米
Acros Organics:硫化锑 Antimony(III) sulfide, 98%(1345-04-6)
参考质量标准:国家标准GB 5236—85 品号牌号化学成分/% 锑总量化合硫杂质，≤ 王水不溶物游离硫三硫化二砷外观为深灰色的针状晶体，不应含有肉眼可见的夹杂物零号三硫化二锑 Sb2S3-0 71.00～72.50 25.50～28.00 0.20 0.05 0.20 一号三硫化二锑 Sb2S3-1 70.00～73.00 25.00～28.30 0.30 0.07 0.30 二号三硫化二锑 Sb2S3-2 69.00～73.00 25.00～28.30 0.50 0.10 0.30
外观性质:红色粉末。
方法一:制备方法有三种：天然太后加工法、锑白转化法和直接化合法。天然矿加工法。天然辉锑矿经筛选、粉碎等加工而制得硫化锑成品。锑白转化法。反应方程式： Sb2O3+4Na2S+Ca(OH)2+3H2O→Sb2S3+8NaOH+CaS 操作方法：将Sb2O3 1.80kg、Ca(OH)2 0.6kg、H2O 6kg混合后，在80℃加热1h。将2.41kg 60%Na2S溶解在3L水中配成Na2S溶液，在搅拌下，于80℃下，在30min内将此Na2S溶液加入上述混合物中，再维持搅拌30min。然后用30%的HCl在3h内酸化至pH为0.4。升温至95℃，再搅拌3h，降温、过滤、洗涤、干燥，制得Sb2S3颜料。直接化合法。反应方程式： 3S+2Sb→Sb2S3 操作方法：将金属锑高温熔化后，向其中通入硫蒸气，直接化合生成三硫化二锑。硫的用量为化学计量的103%～115%，搅拌反应0.3～1h，反应温度维持在650～850℃。
下游产品:三氧化二锑
用途三:主要用于制造火柴和烟火，各种锑盐和有色玻璃。橡胶工业用作硫化剂及军工用等。
用途一:主要用于生产安全火柴、鞭炮、军火和在橡胶工业中作为硬化剂或颜料
用途四:橡胶硫化剂
急性毒性:腹注-大鼠 LD50: 1390 毫克/公斤; 腹注-小鼠 LD50: 209 毫克/公斤