CAS 7773-01-5 MFCD00011114-Manganese(II) chloride 无水二氯化锰 TAO{mole}

Manganese(II) chloride 无水二氯化锰

CAS 7773-01-5 MFCD00011114

化学结构图

SMILES: [Cl-].[Cl-].[Mn+2]

化学属性

Mol. Formula	MnCl2
Mol. Weight	125.84
Density	1.01 g/mL at 20 °C
Melting Point	652 °C(lit.)
TSCA	Yes
Boiling Point	1190°C
Solubility	Very soluble in water, alcohol. Insoluble in ether
Flash Point	1190°C
Appearance	flakes
Stability	易吸潮

别名和识别编码

Chemical Name	Manganese(II) chloride
Synonym	Manganese (chloride) {LY} Manganese (chloride) {} {LY} Manganese (chloride) {} {} {LY} Manganese (chloride) {} {} {} {LY} Manganese (chloride) {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number	7773-01-5
PubChem Substance ID	10313134
EC Number	231-791-2
MDL Number	MFCD00011114
Merck Number	14,5728
Chemical Name Translation	无水二氯化锰
LabNetwork Molecule ID	LN00222920
InChI	InChI=1S/2ClH.Mn/h2*1H;/q;;+2/p-2
Canonical SMILES	Cl[Mn]Cl

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产品应用

通过 MnCl2 氧化及同时进行的 NaOMe 促进型聚集来合成一种新型高自旋六核 Mn(III) 原子簇化合物 [NaMn6(OMe)12(dbm)6]+。该原子簇化合物具有全新的环状结构，在基态时具有 24 个不成对电子。1还用于形成可用于自由基环化反应的活性 Mn(0) 物质。

安全信息

GHS Symbol

WGK Germany1

Hazard Codes Xn

Hazard statements

H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H318 Causes serious eye damage 严重伤害眼睛
H302 Harmful if swallowed 吞食有害
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
H319 Causes serious eye irritation 严重刺激眼睛
H301 Toxic if swallowed 吞食有毒

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Faceshields, Gloves

RTECSOO9625000

Precautionary statements

P273 Avoid release to the environment. 避免释放到环境中。
P305+P351+P338+P310
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P337+P313
P305+P351+P338
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P301+P312+P330

Signal word Danger Warning

Safety Statements

S22 Do not breathe dust 不要吸入粉尘；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R52 Harmful to aquatic organisms 对水生生物有害
R48/22
R25 Toxic if swallowed 吞咽有毒

Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Hygroscopic {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture

UN Number UN3288 UN 3288 6.1/PG 3

Packing GroupIII

其他信息

Alfa Aesar:无水氯化锰(II),anhydrous,97% Manganese(II) chloride, anhydrous, 97%(7773-01-5)
职业标准:TWA 0.2 毫克(锰)/立方米
图谱信息:氯化锰(7773-01-5)红外图谱(IR1)
储运特性:库房低温, 通风, 干燥; 与食品原料分开存放
灭火剂:水, 二氧化碳, 干粉, 砂土
水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 63.4g/0℃;68.1g/10℃;73.9g/20℃;80.8g/30℃;88.5g/40℃ 109g/60℃;113g/80℃;114g/90℃;115g/100℃
用途二:营养增补剂(锰强化剂)。
外观性质:玫瑰色立方形晶体，微有潮解性。
敏感性:Hygroscopic
有很强吸湿性，650℃熔融，650℃以上升华，在空气中加热即释放出氯化氢气体并生成四氧化三锰。溶于水、醇，不溶于醚。
方法一:将菱锰矿与盐酸反应，经中和并除去铁、钙等杂质而得。将软锰矿与盐酸反应，经除杂而得。
类别:有毒物质
用途三:用作有机物氯化催化剂，油漆催干剂和汽油抗震剂原料。用于饲料辅助剂、分析试剂、染料和颜料制造。镁合金、铝合金冶炼，棕黑色砖瓦生产以及制药和干电池制造。在农业上还用作微量元素肥料。
可燃性危险特性:可燃, 火场排出含锰辛辣刺激烟雾
Acros Organics:氯化锰 Manganese(II) chloride, anhydrous, 80 mesh, 99+%(7773-01-5)
上游原料:二氧化锰 --> 碳酸锰 --> 锰
用途一:用于铝合金冶炼、有机氯化物触媒、染料和颜料的制造，以及用于制药和干电池等
Sigma Aldrich:7773-01-5(sigmaaldrich)
氯化锰价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 20026118 氯化锰 500g 26元 2010/06/21 223610500 氯化锰 Manganese(II) chloride 99+%, anhydrous, 80 mesh 50 GR 1342元 2010/06/21 223610100 氯化锰 Manganese(II) chloride 99+%, anhydrous, 80 mesh 10 GR 431元
毒性分级:高毒
下游产品:钛 --> 2-苯基苄胺
MOL 文件:7773-01-5.mol
急性毒性:口服- 大鼠 LD50 250 毫克/ 公斤; 口服- 小鼠 LD50: 1031 毫克/公斤
MSDS 信息:氯化锰(7773-01-5).msds