1,2-Bis(Trimethylsilyloxy)Cyclobutene 1,2-双(三甲基硅氧基)环丁烯

CAS 17082-61-0 MFCD00010798

化学结构图

17082-61-0
SMILES: C[Si](C)(C)OC1CCC=1O[Si](C)(C)C

化学属性

Mol. FormulaC10H22O2Si2
Mol. Weight230.45
Refractive index1.4320 to 1.4370
Boiling Point58-59 °C at 2 mmHg
Density0.897 g/mL at 25 °C(lit.)
Flash Point61°C(lit.)

别名和识别编码

Chemical Name1,2-Bis(Trimethylsilyloxy)Cyclobutene
CAS Number17082-61-0
PubChem Substance ID87564663
Beilstein Registry Number1367530
MDL NumberMFCD00010798
Reaxys-RN1367530
Synonym 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclob
Chemical Name Translation1,2-双(三甲基硅氧基)环丁烯
Canonical SMILESC[Si](C)(C)OC1=C(CC1)O[Si](C)(C)C
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • J. Am. Chem. Soc. 106 , 1759, (1984)
  • Org. Synth. 7 , 112, (1990)
  • Corp MSDS 1 (1), 459:D / FT-IR 2 (3), 4381:D / FT-NMR 1 (3), 671:B / RegBook 1 (2), 2975:C / Structure Index 1 , 471:D:1 / Vapor Phase 3 , 1649:A

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P332+P313
  • P370+P378
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P352+P332+
Signal word Warning {} {} {} {} {TCI}
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Siloxanes - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Enol Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Enol Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Amino Alcohols
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Simple 4-Membered Ring Compounds

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