4-((Tert-Butyldimethylsilyl)Oxy)Pent-3-En-2-One 4-叔-丁基二甲基甲硅烷氧基-3-戊烯-2-酮

CAS 69404-97-3 MFCD00010655

化学结构图

69404-97-3
SMILES: C/C(=C\C(C)=O)/O[Si](C)(C)C(C)(C)C

化学属性

Mol. FormulaC11H22O2Si
Mol. Weight214
Density0.907 g/mL at 20 °C(lit.)
Boiling Point48-50 °C/0.2 mmHg
Refractive indexn20/D 1.462
Flash Point73°(163°F)
TSCANo

别名和识别编码

Chemical Name4-((Tert-Butyldimethylsilyl)Oxy)Pent-3-En-2-One
Synonym 4-叔丁基二甲基硅氧基-3-戊烯-2-酮
MDL NumberMFCD00010655
Beilstein Registry Number4661590
CAS Number69404-97-3
Chemical Name Translation4-叔-丁基二甲基甲硅烷氧基-3-戊烯-2-酮
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • 1. T. Veysoglu, L.A. Mitscher Tetrahedron Lett. 22 , 1299, (1981)
  • 2. T. Matsumoto et al. Chem. Pharm. Bull. 34 , 4613, (1986) 摘要

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Moisture Sensitive

系列性分类


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