((4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (4S,5S)-(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(二苯基甲醇)

CAS 93379-49-8 MFCD00010079

化学结构图

93379-49-8
SMILES: CC1(C)O[C@@H]([C@H](O1)C(O)(C1C=CC=CC=1)C1C=CC=CC=1)C(O)(C1C=CC=CC=1)C1C=CC=CC=1 |&1:4,5|

化学属性

Mol. FormulaC31H30O4
Mol. Weight466.58
Melting Point193-196
Appearance white to light yellow pwdr.

别名和识别编码

Chemical Name((4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol)
Synonym (+)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-D-threitol, (+)-trans-,-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (+)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-D-threitol, (+)-trans-α,α′-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (+)-2,3-O-异亚丙基-1,1,4,4-四苯基-D-苏糖醇 (+)-2,3-O-异亚丙基-1,1,4,4-四苯基-D-苏糖醇 (+)-反式-α,α′-(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(二苯基甲醇) (4S,5S)-4,5-双(二苯基羟甲基)-2,2-二甲基二氧戊环 (+)-反式-α,α′-(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(二苯基甲醇) (4S,5S)-4,5-双(二苯基羟甲基)-2,2-二甲基二氧戊环
MDL NumberMFCD00010079
PubChem Substance ID87564922
Beilstein Registry Number4724097
CAS Number93379-49-8
Reaxys-RN4724096
Chemical Name Translation(4S,5S)-(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(二苯基甲醇)
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分类

  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, TADDOLs
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, TADDOLs
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, TADDOLs

相关文献及参考

  • 1. Quinkert, G. et al. Tetrahedron Lett. 33 , 3617, (1992)
  • 2. Hafner, A. et al. J. Am. Chem. Soc. 114 , 2321, (1992)
  • 3. Bernardi, A. et al. Tetrahedron Lett. 36 , 1363, (1995)
  • FT-NMR 1 (2), 377:A / RegBook 1 (1), 1337:F / Structure Index 1 , 206:C:3
  • Fieser 17 ,322

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Symbol

系列性分类


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