Benzene-Chromium(0) Tricarbonyl 苯三羰基铬
CAS 12082-08-5 MFCD00009955
化学结构图
SMILES: [Cr].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH][CH]1 |^1:7,8,9,10,11,12|
化学属性
| Mol. Formula | C6H6Cr(CO)3 |
|---|---|
| Mol. Weight | 214 |
| Melting Point | 163-166 °C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | Benzene-Chromium(0) Tricarbonyl |
|---|---|
| Synonym | {uni_hamburg} Tricarbonylbenzene chromium Benzentrikarbonylchromium Benzenechromotricarbonyl Chromium, (eta(sup 6)-benzene)tricarbonyl- Benzene-chromium tricarbonyl 苯三羰基铬 Benchrotrene Tricarbonyl(benzene)chromium(0) Benzene-chromium-tricarbonyl (Benzene)tricarbonylchromium (η6-benzene)tricarbonylchromium eta(sup 6)-Benzenetricarbonylchromium Benzenechromiumtricarbonyl Benzolchromtricarbonyl Chromium, (η6-benzene)tricarbonyl- Benzenetricarbonylchromium Chromium, (η(6)-benzene)tricarbonyl- pi-Benzenetricarbonylchromium (η6-benzene)tricarbonylchromium pi-Benzenechromium tricarbonyl Tricarbonylchrom-Benzol Benchrotrene 苯三羰基铬(0) Benzene chromium tricarbonyl Benzenetricarbonyl chromium(0) |
| MDL Number | MFCD00009955 |
| PubChem Substance ID | 24847392 |
| Beilstein Registry Number | 3571699 |
| EC Number | 235-146-6 |
| CAS Number | 12082-08-5 |
| Chemical Name Translation | 苯三羰基铬 |
| Wiswesser Line Notation | L60J 0-CR-CO&CO&CO |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Chromium
- {uni_hamburg} no charge; metal-organic; other heterocycle; carbocycle; aromatic; large ring; fused rings; 3ring; 4ring; 5ring; 6ring; 7ring; metal carbonyl; 1fragment
相关文献及参考
- Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
- Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules Author: Demaison, J.; Hübner, H.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24C Year: 2002 Keyword: Atoms; Molecules and Cluster;
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- H332 Harmful if inhaled 吸入有害
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R25 Toxic if swallowed 吞咽有毒
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 10 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04751
