4-Chlorophenylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&Kseal; 4-氯苯基溴化镁

CAS 873-77-8 MFCD00009926

化学结构图

873-77-8
SMILES: Clc1ccc([Mg]Br)cc1

化学属性

Mol. FormulaC6H4BrClMg
Mol. Weight215.76
Density0.85
TSCANo
Stability对湿度,空气,热和光线敏感
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical Name4-Chlorophenylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&Kseal;
CAS Number873-77-8
EC Number250-023-7
Beilstein Registry Number2384789
MDL NumberMFCD00009926
PubChem Substance ID101888
Synonym 4-氯苯基溴化镁 溶液 4-氯苯基溴化镁
Chemical Name Translation4-氯苯基溴化镁
InChIKeyCDEMHJCJMMOFMB-UHFFFAOYSA-M
LabNetwork Molecule IDLN01322714
InChIInChI=1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q-1;;+2/p-1
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分类

  • {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

相关文献及参考

  • Beilstein: 16,937

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S8 Keep container dry 保持容器干燥;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P316
  • P317
  • P301+P330+P331
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P302+P361+P354
  • P403+P235
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P405 Store locked up. 上锁保管。
  • P303+P361+P353
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P354+P338
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340
  • P370+P378
  • P264+P265
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number 2924
Storage condition 储存温度2-8℃; 充氩保存 Air & Moisture Sensitive 密封2-8°C保存
Hazard Codes 3
Restrict -

其他信息

  • 和水剧烈反应。

系列性分类


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