(Trimethylsilyl)methylmagnesium chloride (三甲基硅基)甲基氯化镁

CAS 13170-43-9 MFCD00009916

化学结构图

13170-43-9
SMILES: C[Si](C)(C)C[Mg]Cl

化学属性

Mol. Formula(CH3)3SiCH2MgCl
Mol. Weight147
Density1.04
Flash Point-40 ºC
TSCANo
Boiling PointAG7160N\/A

别名和识别编码

Chemical Name(Trimethylsilyl)methylmagnesium chloride
MDL NumberMFCD00009916
CAS Number13170-43-9
Beilstein Registry Number3587255
PubChem Substance ID125308026
Synonym Trimethylsiylmethylmagnesium chloride (三甲基硅基)甲基氯化镁 溶液 (Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF (TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE , 1.0M SOLUTION IN DIETHYL ETHER (trimethylsilyl)methylmagnesium chl. sol (Trimethylsilyl)methylmagnesium chloride1.3M solution in THFAcroSeal§3 Trimethylsilylmethylchloromagnesium (Trimethylsilyl)methylmagnesium chloride, 1,3m solution in THF Trimethylsilylmethylmagnesium chloride (20% in ethyl ether (TRIMETHYLSILYL)METHYLMAGNESIUM CHL. SOL , 1 M IN DIETH.ETHER [(Trimethylsilyl)methyl]magnesium Chloride 1.0 M In Diethyl Ether TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE (三甲基硅基)甲基氯化镁 [(Trimethylsilyl)methyl]magnesium Chloride, 1.0 M In Tetrahydrofuran (Trimethylsilylmethyl)chloromagnesium Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L) (Trimethylsilyl)methylmagnesium chloride solution （三甲基硅烷）甲基氯化镁
EC Number250-023-7
Reaxys-RN3535708
Chemical Name Translation(三甲基硅基)甲基氯化镁
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分类

  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

安全信息

GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P311
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P335+P334
  • P370+P378
  • P402+P404
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
WGK Germany3
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Danger
Hazard Codes 4.3 F+,C F+;C F,C
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R12 Extremely flammable 极端易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
UN Number 3399
Packing GroupI
Storage condition Flammables + water-Freezer (-20°C)e area Air & Moisture Sensitive
Hazard Class4.3/3

其他信息

  • Acros Organics:(三甲基硅基)甲基氯化镁 (Trimethylsilyl)methylmagnesium chloride, 1.3M solution in THF, AcroSeal?(13170-43-9)
  • Sigma Aldrich:13170-43-9(sigmaaldrich)
  • MOL 文件:13170-43-9.mol
  • TSCA:No
  • F:10
  • (三甲基硅基)甲基氯化镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1451 三甲基硅基甲基氯化镁(20%的乙醚溶液,约1mol/L) Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L) 100ML 550元 2010/06/21 377461000 (三甲基硅基)甲基氯化镁 (Trimethylsilyl)methylmagnesium chloride , 1.3M solution in THF, AcroSeal® 100 ML 1241元 2010/06/21 377468000 (三甲基硅基)甲基氯化镁 (Trimethylsilyl)methylmagnesium chloride , 1.3M solution in THF, AcroSeal® 800 ML 8560元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Grignard Reagents & Alkyl Metals
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkenyl

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