4-((Trimethylsilyl)Oxy)Pent-3-En-2-One 4-((三甲基硅烷基)氧基)戊-3-烯-2-酮
CAS 13257-81-3 MFCD00009853
化学结构图
SMILES: C/C(=C\C(C)=O)/O[Si](C)(C)C
化学属性
| Mol. Formula | C8H16O2Si |
|---|---|
| Mol. Weight | 172.30 |
| Refractive index | 1.4490 to 1.4520 |
| Boiling Point | 58°C/4mmHg(lit.) |
| Density | 0.912 g/mL at 25 °C(lit.) |
| Flash Point | 35°C(lit.) |
别名和识别编码
| Chemical Name | 4-((Trimethylsilyl)Oxy)Pent-3-En-2-One |
|---|---|
| Synonym | 4-(三甲基硅氧基)-3-戊烯-2-酮 乙酰丙酮烯醇三甲基硅烷酯 TMS acac 乙酰丙酮烯醇三甲基硅烷酯 TMS acac |
| CAS Number | 13257-81-3 |
| PubChem Substance ID | 87577331 |
| EC Number | 236-252-5 |
| Beilstein Registry Number | 4(4)4003 |
| MDL Number | MFCD00009853 |
| Reaxys-RN | 1759078 |
| Chemical Name Translation | 4-((三甲基硅烷基)氧基)戊-3-烯-2-酮 |
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分类
- {SA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Reagents for Silylation, Silylation Reagents
- {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds
相关文献及参考
- Beil. 4 ,IV,4003
- Aldrich MSDS 1 , 1801:A / Corp MSDS 1 (2), 3501:C / FT-IR 2 (3), 4397:D / FT-IR 1 (2), 1114:A / FT-NMR 1 (3), 682:B / RegBook 1 (2), 2983:B / Structure Index 1 , 472:E:5 / Vapor Phase 3 , 1657:C
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+P242+P243
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R10 Flammable 易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
