N-(tert-butyldimethylsilyl)-2,2,2-trifluoro-N-methylacetamide N-(叔丁基二甲基甲硅烷基)-2,2,2-三氟-N-甲基乙酰胺
CAS 77377-52-7 MFCD00009671
化学结构图
SMILES: CC(C)(C)[Si](C)(C)N(C)C(=O)C(F)(F)F
化学属性
| Mol. Formula | C9H18F3NOSi |
|---|---|
| Mol. Weight | 241 |
| Boiling Point | 170 |
| Refractive index | 1.4000 to 1.4050 |
| Density | 1.036 |
| Flash Point | 52°C(lit.) |
| TSCA | No |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | N-(tert-butyldimethylsilyl)-2,2,2-trifluoro-N-methylacetamide |
|---|---|
| CAS Number | 77377-52-7 |
| Alfabeta Name | BUTYLDIMETHYLSILYLMETHYLTRIFLUOROACETAMIDE NTN()----- |
| MDL Number | MFCD00009671 |
| Synonym | MBDSTFA MTBSTFA AND TBDMCS N-(TER N-(TERT-BUTYLDIMETHYLSILYL)-N-METHYL-TRI FLUOROACETAMIDE, 97+% N-METHYL-N-(T-BUTYLDIMETHYLSILYL)TRIFLUOROACETAMIDE N-METHYL-N-TERT-BUTYLDIMETHYLSILYLTRIFLUOROACETAMIDE N-METHYL-N-[TERT-BUTYLDIMETHYL-SILYL]TRIFLUOROACETAMIDE AND TERT-BUTYLDIMETHYLCHLOROSILANE N-Methyl-N-(tert-butyldimethylsilyl)trifluoroacetamide N-TERT-BUTYLDIME.SILYL-N-ME.TRIFLUOROACE N-TERT-BUTYLDIME.SILYL-N-ME.TRIFLUOROACE TAMIDE + 1% TBDMSCL N-[(1,1-Dimethylethyl)dimethylsilyl]-2,2,2-trifluoro-N-methylacetamide N-叔丁基二甲基甲硅烷基-N-甲基三氟乙酰胺 N-甲基-N-叔丁基二甲基甲硅烷基三氟乙酰胺 SILYLATING MIXTURE FLUKA VI 甲硅烷基化混合物 Fluka VI |
| PubChem Substance ID | 87564091 |
| Beilstein Registry Number | 3606546 |
| Reaxys-RN | 3606546 |
| EC Number | 000-000-0 |
| Chemical Name Translation | N-(叔丁基二甲基甲硅烷基)-2,2,2-三氟-N-甲基乙酰胺 |
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分类
- Amides, Analytical Reagents, Analytical/Chromatography, Biochemicals and Reagents, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents GC, Fluorescence/Luminescence Spectroscopy, GC Derivatization Reagents, by Application, Luminescent Compounds/Detection, Protecting and Derivatizing Reagents,
产品应用
- 高效的硅烷化试剂，据报道对湿度的敏感性比其他硅烷化试剂低，用于 GLC 衍生化反应。
相关文献及参考
- Pleasance, S. et al.: Biomed. Env. Mass Spec., 19, 420 (1990); Paik, M. et al.: BMB Rep., 41, 23 (2008);
- Reactive silylating agent effective in acetonitrile for introduction of the TBDMS group with alcohols, thiols, amines, amides, carboxylic acids, as well as conversion of enolizable carbonyl groups to silyl enol ethers: J. Org. Chem., 47, 3336 (1982). See Appendix 4.
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P305+P351+P338
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P370+P378
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R10 Flammable 易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S37 Wear suitable gloves 戴适当手套；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S7 Keep container tightly closed 保存在严格密闭容器中；
其他信息
- Sigma Aldrich:77377-52-7(sigmaaldrich)
