n-Butyl vinyl ether 乙烯基正丁醚
CAS 111-34-2 MFCD00009454
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分类
- {SNA} Monomers, Polymer Science, Vinyl Ethers, 材料科学
- {SNA} Materials Science, Monomers, Polymer Science, Vinyl Ethers
- {SNA} A-B, A-C, Additional Standards, Alpha Sort, Analytical Standards, Chromatography, Environmental Standards, Organic Pollutant Standards, Volatile & Semivolatile Standards, Volatiles/ Semivolatiles, 分析/色谱
- Materials Science, Monomers, Polymer Science,
- {SNA} A-B, Alpha Sort, Analytical Standards, Chromatography, Environmental Standards, Volatiles/ Semivolatiles, 分析/色谱
相关文献及参考
- Beil. 1 ,IV,2052
- Aldrich MSDS 1 , 333:C / Corp MSDS 1 (1), 651:A / FT-IR 2 (1), 316:B / FT-IR 1 (1), 213:D / FT-NMR 1 (1), 332:B / IR-Spectra (3), 128:E / IR-Spectra (2), 117:F / NMR-Reference 2 (1), 182:D / RegBook 1 (1), 219:C / Sax 6 , 2727 / Structure Index 1 , 30:D:3 / Vapor Phase 3 , 278:B
- Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
- Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength de
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R11 Highly flammable 非常易燃
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S14 Keep away from ... (incompatible materials to be indicated by the manufacturer) 远离(生产厂家指定的不相容物质)保存;
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S33 Take precautionary measures against static discharges 对静电采取预防措施;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37 Wear suitable gloves 戴适当手套;
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
TYPE OF TEST : LC50 - Lethal
TYPE OF TEST : LC50 - Lethal conc
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 62 gm/m3/2H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,119,1982
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 10 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 6/28/1972
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 16000 ppm/4H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 6/28/1972
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Mammal - species unspecified DOSE/DURATION : 60 gm/m3 TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publi
其他信息
- 乙烯基正丁醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0746 丁基乙烯醚(含稳定剂氢氧化钾) Butyl Vinyl Ether (stabilized with KOH) 25ML 137元 2014/06/02 B0746 丁基乙烯醚(含稳定剂氢氧化钾) Butyl Vinyl Ether (stabilized with KOH) 500ML 461元 2010/06/21 149705000 乙烯基正丁醚 n-Butyl vinyl ether 98%, stabilized 500 ML 420元
- 毒性分级:低毒
- 用途二:有机合成原料,用来聚合共产主义战士聚生产聚乙烯基醚,用于涂料、胶粘剂、助剂、增塑剂等。
- 灭火剂:干粉、干砂、干石粉、二氧化碳、泡沫
- 职业标准:STEL 20 毫克/ 立方米
- 上游原料:氯化钯 --> 1,1-二乙氧基乙烷 --> 乙烯醚
- 类别:易燃液体
- 图谱信息:乙烯基正丁醚(111-34-2)红外图谱(IR2) 乙烯基正丁醚(111-34-2)质谱(MS) 乙烯基正丁醚(111-34-2)核磁图( 13 CNMR) 乙烯基正丁醚(111-34-2)Raman光谱 乙烯基正丁醚(111-34-2)红外图谱(IR1) 乙烯基正丁醚(111-34-2)核磁图( 1 HNMR)
- 急性毒性:口服-大鼠 LD50:10000 毫克/公斤; 吸入-小鼠 LC50: 62 克/立方米/2小时
- MSDS 信息:乙烯基正丁基醚(111-34-2).msds
- 用途一:用于有机合成,可用于聚合和共聚生产聚乙烯基醚,也用于涂料、胶粘剂、助剂、增塑剂等
- 刺激数据:皮肤- 兔子 500 毫克 轻度; 眼睛- 兔子 500 毫克/ 24小时 轻度
- 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生刺激烟雾
- MOL 文件:111-34-2.mol
- 下游产品:2-肼基-4-三氟甲基嘧啶 --> 2-氯-4-三氟甲基嘧啶 --> 1-甲基-3-三氟甲基-1H-吡唑 --> 3-氯-5-氟苯胺 --> 2-羟基-6-三氟甲基烟酸 --> 4-(4-三氟甲基嘧啶-2-基)哌嗪-1-甲酸叔丁酯 --> 2-羟基-4-三氟甲基嘧啶 --> 4-三氟甲基-2-溴嘧啶 --> 3-(三氟甲基)吡唑
- 危险类别:第三类易燃液体
- 蒸气密度:3.5 (vs air)
- 包装贮存:贮存在玻璃的、钢的或铁的容器内。可与空气接触,只要没有水分即可。
- Sigma Aldrich:111-34-2(sigmaaldrich)
- TCI Shanghai:丁基乙烯醚(含稳定剂氢氧化钾) Butyl Vinyl Ether (stabilized with KOH),>;98.0%(GC)(111-34-2)
- 方法一:(1)由乙炔与丁醇反应而得。此法所需设备少,选择性高。(2)由乙醛与正丁醇反应而得。这种由缩醛裂解的方法也是乙烯基醚通用的工艺。另一种较新的方法是由醇、乙烯和氧在氯化钯-氯化铜催化剂存在下反应,也可以获得乙烯基醚。
- Acros Organics:正丁基乙烯醚 n-Butyl vinyl ether, stabilized, 98%(111-34-2)
- 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
- Alfa Aesar:正丁基乙烯基醚,98%,stab.with0.01%KOH n-Butyl vinyl ether, 98%, stab. with 0.01% KOH(111-34-2)
- 蒸气压:42 mm Hg ( 20 °C)
- 外观性质:无色液体。