CAS 56-35-9 MFCD00009418-Bis(Tributyltin) Oxide 三丁基氧化锡 TAO{mole}

Bis(Tributyltin) Oxide 三丁基氧化锡

CAS 56-35-9 MFCD00009418

化学结构图

SMILES:

化学属性

Mol. Formula	C24H54OSn2
Mol. Weight	596
Refractive index	1.486
Boiling Point	180
Density	1.17
Flash Point	168°(334°F)
TSCA	Yes
Melting Point	-45°
Vapor Pressure	<;0.01 mmHg ( 25 °C)
Solubility	不溶
Stability	对空气和湿度敏感
Appearance	微黄色液体。不溶于水，可与有机溶剂混溶。

别名和识别编码

Chemical Name	Bis(Tributyltin) Oxide
Synonym	BIS(TRIBUTYLTIN) OXIDE Bis-(tributylzinn)-oxid Kyslicnik tri-n-butylcinicity {Chem { Bis(tri-n-butyltin)oxide Oxybis[tributyltin] MT 1E Bis-(tri-n-butylcin)oxid Tin, oxybis(tributyl- Bis(tributylstannyl)oxide Bis(tri-n-butylzinn)oxid Lastanox F Biomet TBTO Aceto T Bis(tributyloxide) of tin Stannicide A Oxybis(tributyltin) Bis(tributylzinn)-oxid 双(三正丁基锡)氧化物,97% ZK 21995 {uni_ha 双[三正丁基锡(IV)]氧化物 Stannane, tri-N-butyl-, oxide BTO Bis(tr Oxybis-(tributylzinn) HEXABUTYLDISTANNOXANE {uni_hamburg {SNA} Hexabutyldistanniox 1,1,1,3 双(三正丁基锡)氧化物
CAS Number	56-35-9
PubChem Substance ID	24891834
EC Number	200-268-0
Beilstein Registry Number	745057
MDL Number	MFCD00009418
Chemical Name Translation	三丁基氧化锡
Wiswesser Line Notation	4-SN-4&4&O-SN-4&4&4
LabNetwork Molecule ID	LN01264936

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安全信息

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H301 Toxic if swallowed 吞食有毒
H312 Harmful in contact with skin 皮肤接触有害
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H319 Causes serious eye irritation 严重刺激眼睛
H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes T,N

RTECSJN8750000

Precautionary statements

P273 Avoid release to the environment. 避免释放到环境中。
P301+P310
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P501 Dispose of contents/container to..… 处理内容物/容器.....
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服

Signal word

UN Number UN 2788 6.1/PG 2 UN2788

Risk Statements

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；

Storage condition Air & Moisture Sensitive +4°C 2-8℃

Packing GroupII

Hazard Class6.1

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 36500 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Endocrine - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0571285

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 37100 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Endocrine - tumors
   Endocrine - thyroid tumors
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   28,179,1990

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOS

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 55 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 41(5),10,1976

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 200 mg/m3
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - aggression
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   EJTXAZ European Journal of Toxicology and Environmental Hygiene.  (Paris,
   France)  V.7-9, 1974-76. For publisher information, see TOERD9.
   Volume(issue)/page/year: 9,339,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 87 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1255,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
   Gastrointestinal - alteration in gastric secretion
   Nutritional and Gross Metabolic - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Spr

TYPE OF TEST

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 56200 ppb
REFERENCE :
   AEMIDF Applied and Environmental Microbiology.  (American Soc. for
   Microbiology, 1913 I St., NW, Washington, DC 20006)  V.31-    1976-
   Volume(issue)/page/year: 45,48,1983

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 56200 ppb
REFERENCE :
   AEMIDF Applied and Environmental Microbiology.  (American Soc. for
   Microbiology, 1913 I St., NW, Washington, DC 20006)  V.31-    1976-
   Volume(issue)/page/year: 45,48,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterda

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 60 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 188,65,1987

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 100 ug/disk
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 280,195

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 15 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 300,5,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 150 mg/kg
SEX/DURATION            : female 6-20 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   97,113,1989

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 400 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 50,257,1990

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 50 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 50,257,1990

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERV

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent -

其他信息

Sigma Aldrich:56-35-9(sigmaaldrich)
海关编码:29310095
用途一:用作消毒杀菌剂、防霉剂等
方法一:锡和氯气反应合成四氯化锡，再与氯丁烷和金属镁反应生成三丁基氯化锡。然后用氢氧化钠处理制得氧化双三丁基锡。工业产品含量93-95%。原料消耗定额：锡800kg/t、镁500kg/t、丁醇800kg/t。
急性毒性:口服- 大鼠 LD50: 87 毫克/ 公斤; 口服- 小鼠 LD50: 55 毫克/ 公斤
三丁基氧化锡价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xw010253 三丁基氧化锡 100g 200元 2010/06/21 106510050 三丁基氧化锡 Bis(tri-n-butyltin) oxide 96%, stabilized 5 ML 316元 2010/06/21 106511000 三丁基氧化锡 Bis(tri-n-butyltin) oxide 96%, stabilized 100 ML 392元
灭火剂:干粉、泡沫、砂土
Alfa Aesar:双(三正丁基锡)氧化物,97% Bis(tri-n-butyltin) oxide, 97%(56-35-9)
Acros Organics:双(三正丁基锡)氧化物 Bis(tri-n-butyltin) oxide, stabilized, 96%(56-35-9)
蒸气压:<;0.01 mm Hg ( 25 °C)
下游产品:4-硝基苯基-D-吡喃葡糖苷 --> 2-氯-4-硝基苯-alpha-L-岩藻糖苷
不溶于水。
可燃性危险特性:受热分解排放含锡化物辛辣刺激气体
MOL 文件:56-35-9.mol
用途二:用来合成有机锡高分子树脂，制取用于船舶漆的防污剂、熏蒸剂、杀菌剂、杀藻剂。
敏感性:Air & Moisture Sensitive
TSCA:Yes
储运特性:库房通风低温干燥; 与食品原料分开储运
类别:农药
上游原料:镁 --> 1-氯丁烷 --> 三丁基氯化锡
职业标准:TWA 0.1 毫克 (锡)/ 立方米; STEL 0.2 毫克 (锡)/ 立方米
毒性分级:高毒
刺激数据:眼睛- 兔子 0.05 毫克/ 24小时重度
MSDS 信息:Hexabutyldistannoxane(56-35-9).msds
图谱信息:三丁基氧化锡(56-35-9)红外图谱(IR1) 三丁基氧化锡(56-35-9)核磁图( 1 HNMR) 三丁基氧化锡(56-35-9)质谱(MS)