Ethyl 2-(diethoxyphosphoryl)propanoate ethyl 2-(diethoxyphosphoryl)propanoate
CAS 3699-66-9 MFCD00009159
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资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents
产品应用
- Wittig-Horner试剂,广泛用于醛酮进行的反应,形成丙烯酸。
相关文献及参考
- Beilstein:4(1)573
- Wadsworth-Emmons precursor of methacrylic esters (see Triethyl phosphonoacetate, A14120 and Appendix 1). Lithiation followed by acylation with perfluoroalkanoic anhydrides gives a perfluoroacyl intermediate which, with an organolithium reagent, leads stereoselectively to a trifluoroalkylated ɑß-unsaturated ester: J. Fluorine Chem., 89, 141 (1998):
安全信息
GHS Symbol
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37 Wear suitable gloves 戴适当手套;
- S39 Wear eye/face protection 戴眼睛/面孔保护装置;
- R36 Irritating to eyes 刺激眼睛
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R37 Irritating to respiratory system 刺激呼吸道
- R38 Irritating to skin 刺激皮肤
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P304+P340
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- Sigma Aldrich:3699-66-9(sigmaaldrich)
- 三乙基2-膦酰基丙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T2135 2-膦酰丙酸三乙酯 Triethyl 2-Phosphonopropionate 25G 620元 2010/06/21 174360500 三乙基2-膦酰基丙酯 Triethyl 2-phosphonopropionate 98% 50 GR 1287元 2010/06/21 174360100 三乙基2-膦酰基丙酯 Triethyl 2-phosphonopropionate 98% 10 GR 415元
- Hazard Note:Irritant
- 用途一:Wittig-Horner试剂,广泛用于醛酮进行的反应,形成丙烯酸。
- Acros Organics:2-磷酰丙酸三乙酯 Triethyl 2-phosphonopropionate, 98%(3699-66-9)
- F:10
- Alfa Aesar:2-膦酰丙酸三乙脂,98% Triethyl 2-phosphonopropionate, 98%(3699-66-9)
- MOL 文件:3699-66-9.mol