Thallium(I) Ethoxide 乙醇铊(I)

CAS 20398-06-5 MFCD00009072

化学结构图

20398-06-5
SMILES: CCO[Tl]

化学属性

Mol. FormulaTlOC2H5
Mol. Weight249.44
Refractive indexn20/D 1.676(lit.)
Density3.522 g/mL at 25 °C(lit.)
Flash Point>110°(230°F)
TSCAYes
Boiling Point130° dec.
Melting Point-3°
Appearance cloudy, dense liq.
Stabilitymoisture sensitive, store cold

别名和识别编码

Chemical NameThallium(I) Ethoxide
Synonym Ethanol thallium salt Ethyl alcohol thallium(I) salt Thallium monoethoxide 乙氧基亚铊 乙醇铊(I) Ethyl alcohol, thallium (I)
CAS Number20398-06-5
PubChem Substance ID24848978
EC Number243-786-2
MDL NumberMFCD00009072
Chemical Name Translation乙醇铊(I)
Wiswesser Line Notation2O-TL-
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Solution Deposition Precursors, Thallium, 材料科学
  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Thallium
  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Thallium

相关文献及参考

  • Chan, T. H.; Li, C. J.; Wei, Z. Y., J. Chem. Soc., Chem. Commun. , 505, (1990)
  • Andrews, P. C.; Peatt, A. C.; Raston, C. L. Tetrahedron Lett. 43 , 7541, (2002)
  • Jian, H.; Tour, J. M. J. Org. Chem. 68 , 5091, (2003) 摘要
  • Fieser 2 ,407 / Fieser 4 ,501 / Fieser 5 ,656 / Fieser 6 ,577 / Fieser 7 ,362 / Fieser 10 ,395
  • Aldrich MSDS 1 , 1694:B / Corp MSDS 1 (2), 3317:D / FT-IR 2 (3), 4488:B / FT-IR 1 (2), 1139:C / IR-Spectra (3), 1556:C / IR-Spectra (2), 1330:B / NMR-Reference 2 (2), 981:B / RegBook 1 (2), 3053:J / Sax 6 , 1304 / Sigma FT-IR 1 (2), 1050:A / Structure Index 1 , 484:C:3

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T+,N
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H300 Fatal if swallowed 吞食致命
  • H300+H330
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P301+P310+P330
  • P304+P340+P310
  • P403+P233
Signal word Danger
RTECSKM2940000
UN Number UN2810
Risk Statements
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R51/53
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
Storage condition Moisture Sensitive
Packing GroupII
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,43,1953

系列性分类


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