CAS 100-99-2 MFCD00008929-Triisobutylaluminium 三异丁基铝 TAO{mole}

Triisobutylaluminium 三异丁基铝

CAS 100-99-2 MFCD00008929

化学结构图

SMILES: CC(C)C[Al](CC(C)C)CC(C)C

化学属性

Mol. Formula	C12H27Al
Mol. Weight	198.37
Density	0.695
Refractive index	1.4494
Boiling Point	68-69
Melting Point	4-6°C
TSCA	Yes
Flash Point	-18 ºC
Solubility	溶于苯。
Stability	对空气和湿度敏感
Appearance	colorless liq.

别名和识别编码

Chemical Name	Triisobutylaluminium
CAS Number	100-99-2
EC Number	202-906-3
Beilstein Registry Number	3587328
MDL Number	MFCD00008929
Synonym	ALUMINUM TRIISOBUTYL Aluminium triisobutyl Aluminiumtriisobutyl Aluminiumtris-(2-methylpropanid) Aluminum, tris(2-methylpropyl)- TIBA TIBA 三(2-甲基丙基)铝 TIBAL TIBAL cpd TRIISOBUTYLALUMINIUM TRIISOBUTYLALUMINUM Tri(isobutyl)aluminum Tri-i-butylaluminum Tri-iso-butylaluminum Triisobutylalane Triisobutylaluminummincolorlessliq Tris(2-methylpropyl)aluminium Tris(2-methylpropyl)aluminum Tris(isobutyl)aluminum triisobutyl alane triisobutyl-aluminu triisobutylalane triisobutylaluminum tris(2-methylpropyl)-Aluminum tris(isobutyl)aluminum 三异丁基铝三异丁基铝, 25% W/W IN HEXANE 三異丁基鋁
PubChem Substance ID	16682931
Chemical Name Translation	三异丁基铝
Merck Number	326
LabNetwork Molecule ID	LN00162753
InChI	InChI=1S/3C4H9.Al/c31-4(2)3;/h34H,1H2,2-3H3;

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

用于有机合成及作聚合烯烃的催化剂。

安全信息

Signal word

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
S30 Never add water to this product 切勿将水加入该产品中；
S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
S8 Keep container dry 保持容器干燥；

Risk Statements

R11 Highly flammable 非常易燃
R48/20
R14 Reacts violently with water 遇水会猛烈反应
R17 Spontaneously flammable in air 在空气中能够自燃
R34 Causes burns 会导致灼伤
R62 Possible risk of impaired fertility 有削弱生殖能力的危险
R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
R51/53
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P222 Do not allow contact with air. 不要与空气接触。
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
P231+P232
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P302+P334
P303+P361+P353
P304+P340
P305+P351+P338
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P335+P334
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P402+P404
P405 Store locked up. 上锁保管。
P422 Store contents under… 存储目录在…之下。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H318 Causes serious eye damage 严重伤害眼睛

Hazard Codes F,C

UN Number UN 3394 4.2/PG 1 UN3399 UN3394

Storage condition 密封保存 Air & Moisture Sensitive 充氩保存 0-6°C

Packing GroupI

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Class4.3

RTECSBD2203500

Warnings 危化品目录(2015)

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4 gm/kg
TOXIC EFFECTS :
   Gastrointestinal - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555398

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8000 ppm/1H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555398

Restrict 危险品

其他信息

外观性质:无色澄清液体，具有强烈的霉烂气味。
毒性分级:中毒
上游原料:异丁烯 --> 铝 --> 合成纤维
F:10
用途一:用作顺丁橡胶聚合催化剂，也是其他定向聚合橡胶、合成树脂和合成纤维常用聚合催化剂
类别:自燃物品
三异丁基铝价格(试剂级):更新日期产品编号产品名称包装价格 2011/04/16 T0784 三异丁基铝(15%的己烷溶液,约0.50mol/L) Triisobutylaluminum (15% in Hexane, ca. 0.50mol/L) 100ML 500元 2011/04/16 T1330 三异丁基铝(15%的庚烷溶液,约0.53mol/L) Triisobutylaluminum (15% in Heptane, ca. 0.53mol/L) 100ML 920元 2010/06/21 185428000 三异丁基铝 Triisobutylaluminium , 1.1M solution in toluene, AcroSeal® 800 ML 2589元
用途二:顺丁橡胶聚合剂合用催化剂，也用作其他定向聚合剂、合成树脂和合成纤维的常用聚合催化剂之一。
MSDS 信息:三异丁基铝(100-99-2).msds
储运特性:库房通风低温干燥; 包装充氮; 与氧化剂分开存放
职业标准:TLV-TWA 2 毫克 (AL) / 立方米 (美国)
急性毒性:参考值吸入- 大鼠 LC50: 10000 毫克/ 立方米/ 15分
Sigma Aldrich:100-99-2(sigmaaldrich)
敏感性:Air & Moisture Sensitive
灭火剂:干砂、干粉
TSCA:Yes
可燃性危险特性:遇空气、氯气、氧化剂、高温、水能自燃; 燃烧产生有毒铝化物烟雾
用途三:用于有机合成及作聚合烯烃的催化剂。
具有强烈的霉烂气味。和水反应，和饱和脂肪烃及芳香烃混溶。
方法一:铝粉经球磨活化，异丁烯经干燥，两者与氢一起在三异丁基铝引发下一步直接合成。原料消耗(kg/t)原料名称规格消耗铝粉（标准态下），粒度50-120目，含量 ≥99% 82立方米氧含量≤20ppm 水含量≤20ppm异丁烯含量≥ 98% 1700 水分<20ppm 氧<20ppm产品加工成无色或微黄色催化剂，也用作其他定向聚合橡胶、合成树立脂和合成纤维的常用聚合催化剂之一。
下游产品:香茅醇 --> 聚苯(IV)
MOL 文件:100-99-2.mol
Acros Organics:三异丁基铝 Triisobutylaluminium, 1.1M solution in toluene, AcroSeal?(100-99-2)
Alfa Aesar:Triisobutylaluminum, 25% w/w in hexane(100-99-2)