Isobutane 异丁烷
CAS 75-28-5 MFCD00008926
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分类
- {Chemicalbook} 食品添加剂: 充气剂和各种气体
- {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chemical Synthesis, M, META - METH, Specialty Gases, Synthetic Reagents
- {uni_hamburg} no charge; 1fragment
相关文献及参考
- {uni_
- Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
- Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
安全信息
GHS Symbol
- H220 Extremely flammable gas 极易燃气体。
- H280 Contains gas under pressure; may explode if heated 内含高压气体,遇热可能爆炸。
- P410+P403
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- R12 Extremely flammable 极端易燃
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1041 gm/m3/2H TOXIC EFFECTS : Behavioral - excitement REFERENCE : JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 58,74,1936
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 57 pph/15M TOXIC EFFECTS : Behavioral - tremor Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - respiratory depression REFERENCE : HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 1,239,1982
其他信息
- 蒸气密度:2.01 (21 °C, vs air)
- 毒性分级:低毒
- 用途二:主要用作石化企业分析、检测仪器的标准气
- 用途四:主要用于与异丁烯经烃化生产异辛烷,用作汽油辛烷值改进剂。经裂解可制异丁烯与丙烯。与异丁烯、丙烯进行烷基化可制烷基化汽油。可制备甲基丙烯酸、丙酮和甲醇等。还可作冷冻剂。
- 蒸气压:72.2 psi ( 37.7 °C)
- 用途三:气溶胶;充气剂。
- 下游产品:环氧丙烷 --> 异丁烯 --> 2-甲基丙烯酸 --> 1R,3R-二溴菊酸 --> 正丁烷 --> 正丁烯 --> 1R-顺式菊酸 --> 氯醚菊酯 --> 2,2,4-三甲基戊烷
- 使用限量:GMP(FDA,§184.1165,2000)。
- 储运特性:库房通风低温干燥; 轻装轻卸; 与氧气、空气等助燃气体钢瓶分开存放
- MOL 文件:75-28-5.mol
- 上游原料:压凝汽油 --> C4烃类混合物
- 异丁烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80022780 异丁烷(*)¤ net140g 772.2元
- 参考质量标准:FCC,1996 含量/% ≥95.0 残渣酸度 正常 高沸点残渣/(mg/kg) ≤5 含硫化合物 正常 水分/(mg/kg) ≤10
- 毒性:GRAS(FDA,§184.:1165,2000)。
- 类别:有害气体
- 急性毒性:吸入-大鼠LC50:57000PPM/15分;吸入-小鼠LCL0:1041000毫克/立方米/2小时
- 用途一:主要用于与异丁烯经烃化而制异辛烷,作为汽油辛烷值的改进剂,也可用作冷冻剂
- 灭火剂:雾状水、二氧化碳
- 外观性质:无色、稍有气味的气体。
- 职业标准:TWA 1430 毫克/ 立方米; STEL 1800 毫克/ 立方米
- F:4.5-31
- TCI Shanghai:异丁烷(置于无阀气瓶中) Isobutane (in cylinder without valve) [To use this product charged in cylinder, a valve is required which is sold separately (Product Code:V0030)],>;95.0%(GC)(75-28-5)
- 爆炸物危险特性:与空气混合明火、受热可爆
- Sigma Aldrich:75-28-5(sigmaaldrich)
- 方法一:由天然气分馏后用表面活性剂吸附或冷冻而得。
- 可燃性危险特性:明火、受热可燃; 燃烧产生刺激烟雾
- MSDS 信息:异丁烷(75-28-5).msds
- 方法二:存在于石油气、天然气和裂化气中。由石油裂化过程中产生的碳四馏分,经分离而得。