CAS 110-05-4 MFCD00008803-二叔丁基过氧化物二叔丁基过氧化物 TAO{mole}

二叔丁基过氧化物二叔丁基过氧化物

CAS 110-05-4 MFCD00008803

化学结构图

SMILES: CC(C)(C)OOC(C)(C)C

化学属性

Mol. Formula	(CH3)3COOC(CH3)3
Mol. Weight	146.23
Refractive index	n20/D 1.3891(lit.)
Boiling Point	109-110
Density	0.796
Vapor Pressure	40 mmHg ( 20 °C)
Flash Point	12°C(lit.)
Melting Point	-40
Solubility	不溶于水，溶于酮、烃类。
Stability	对热敏感

别名和识别编码

Chemical Name	二叔丁基过氧化物
Synonym	Interox DTB 叔丁基过氧化物 (Luperox® DI) 过氧化二叔丁基醚二(1,1-二甲基乙基)过氧化物 Di-tert-butyl peroxyde 過氧化二(三級丁基) 过氧化二叔丁基 tert-Butyl Peroxide Di-tert.-butylperoxid 过氧化二特丁烷 Bis(1,1-dimethylethyl)peroxide Bis(1,1-dimethylethyl) peroxide tert-Butyl peroxide; DTBP DTBP Di-t-butyl peroxide bis(1,1-dimethylethyl)-peroxid DI-TERT-BUTYL PEROXIDE 过氧化二叔丁烷 BIS(1,1-DIMETHYLETHYL)PEROXIDE Peroxyde de butyle tertiaire (tributyl)peroxide Kayabutyl D 2-tert-Butylperoxy-2-methyl-propane Trigonox B 双(1,1-二甲基乙基)过氧化物
CAS Number	110-05-4
PubChem Substance ID	24850244
EC Number	203-733-6
Beilstein Registry Number	1735581
MDL Number	MFCD00008803
Reaxys-RN	1735581
Merck Number	3461
Chemical Name Translation	二叔丁基过氧化物
Wiswesser Line Notation	1X1&1&OOX1&1&1
LabNetwork Molecule ID	LN01245304

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品牌质保精细包装现货库存一流品牌服务

产品应用

用作不饱和聚酯和硅橡胶的交联剂，还用作聚合引发剂。

安全信息

GHS Symbol

WGK Germany1

Hazard statements

H242 Heating may cause a fire 加热可能会引起火灾
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes O,F

RTECSER2450000

Precautionary statements

P410 Protect from sunlight. 防止阳光照射。
P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
P420 Store away from other materials. 远离其他材料。
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P411+P235
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P332+P313
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P303+P361+P353
P305+P351+P338+P337+P313

Signal word

UN Number

Storage condition 易燃产品，密封阴凉保存储存温度2-8℃ <;0 <0°C 储存温度-20°C 2-8°C

Safety Statements

S14 Keep away from ... (incompatible materials to be indicated by the manufacturer) 远离（生产厂家指定的不相容物质）保存；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处；

Risk Statements

R11 Highly flammable 非常易燃
R52/53
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
R7 May cause fire 会导致起火

Packing GroupⅡ

Hazard Class5.2

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 585 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   RARSAM Radiation Research, Supplement.  (New York, NY)  No.1-7, 1959-67.
   Discontinued.  Volume(issue)/page/year: 3,193,1963

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >25 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARCOC* ARCO Chemical Company Report.  (3801 West Chester Pike, Newton
   Square, PA 19073)  Volume(issue)/page/year: JUN1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3210 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Behavioral - ataxia
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,205,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4572 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,43,1982

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >4100 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARCOC* ARCO Chemical Company Report.  (3801 West Chester Pike, Newton
   Square, PA 19073)  Volume(issue)/page/year: JUN1982

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >4103

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 226 mg/m3/4H
SEX/DURATION            : female 1-19 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(12),46,1976

Restrict 危险品

其他信息

类别:氧化剂
灭火剂:泡沫、二氧化碳、干粉
毒性分级:中毒
刺激数据:皮肤-兔 500 毫克中度; 眼- 兔 500 毫克/24小时轻度
储运特性:库房通风低温; 轻装轻卸; 与有机物、还原剂、硫、磷易燃物分开存放
用途二:用作不饱和聚酯和硅橡胶的交联剂，还用作聚合引发剂。理论活性氧量10.94％，活化能146.9kJ/mol，半衰期218h(100℃)、34h(115℃)、0.15h(130℃)。本品与还原剂接触或受冲击会爆炸。闪点18℃，易燃，其蒸气和空气混合形成爆炸混合物。能刺激眼睛、皮肤和呼吸道。
二叔丁基过氧化物价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80044527 过氧化二叔丁基（*） 250ml 60.8元 2011/04/16 D3411 二叔丁基过氧化物 Di-tert-butyl Peroxide 100ML 284元 2010/06/21 349932500 二叔丁基过氧化物 Di-tert-butyl peroxide 99% 250 GR 557元
急性毒性:吸入- 大鼠 LC50: 4100 PPM/ 4小时; 口服- 小鼠 LD50: 4572 毫克/ 公斤
下游产品:(4-甲氧基吡啶-2-基)甲醇 --> 4-甲氧基吡啶-2-醛
Acros Organics:二-叔丁基过氧化物 Di-tert-butyl peroxide, 99%(110-05-4)
MSDS 信息:过氧化二叔丁基(110-05-4).msds
TCI Shanghai:二叔丁基过氧化物 Di-tert-butyl Peroxide,>;94.0%(GC)(110-05-4)
爆炸物危险特性:与还原剂、硫、磷等混合可爆; 干燥时摩擦、光照、受热、撞击可爆
用途一:广泛用作不饱和聚酯和硅橡胶的交联剂、单体的聚合引发剂、聚丙烯改性剂、橡胶硫化剂等
能与苯、石油醚等大多数有机溶剂混溶,不溶于水,有强氧化性。
上游原料:过氧化氢 --> 叔丁醇 --> 叔丁基过氧化氢
外观性质:水白色透明液体。
可燃性危险特性:遇有机物、还原剂、硫、磷等易燃物及明火、摩擦、撞击可燃; 燃烧产生刺激烟雾
MOL 文件:110-05-4.mol
用途四:用作不饱和聚酯和硅橡胶的交联剂，还用作聚合引发剂。
Sigma Aldrich:110-05-4(sigmaaldrich)
蒸气压:40 mm Hg ( 20 °C)
方法一:由叔丁醇在浓硫酸中与过氧化氢反应而得。将222g(3mol)叔丁醇和140g(1mol)70％的硫酸混合冷却至-2～-8℃。在激烈搅拌下，于90min内滴加入126g(1mol)27％过氧化氢和400g(4mol)浓硫酸，加完后继续搅拌3h。分出油层，用60ml水洗，再用30％氢氧化钠溶液洗除叔丁基过氧化氢，最后用水洗。加硫酸镁干燥，过滤得成品。
用途三:用作不饱和聚酯和硅橡胶的交联剂，还用作聚合引发剂。理论活性氧量10.94%，活化能35.4200J/mol，半衰期218h（100℃）、34h（115℃）、0.15h（130℃）。该品与还原剂接触或受冲击会爆炸。闪点18℃，易燃，其蒸气和空气形成爆炸混合物。能刺激眼睛、皮肤和呼吸道。