Diacetone acrylamide 双丙酮丙烯酰胺

CAS 2873-97-4 MFCD00008788

化学结构图

2873-97-4
SMILES: C=CC(=O)NC(C)(C)CC(C)=O

化学属性

Mol. FormulaC9H15NO2
Mol. Weight169.22
Melting Point53-57°C
Flash Point139.4°C
TSCAYes
Boiling Point325.9°C at 760 mmHg
Solubility可溶
Appearance 白色或稍带黄色的片状结晶。熔融时无色。熔点57-58℃，沸点120℃（1.07kPa），93-100℃（13.3-40Pa），相对密度0.998（60/4℃）。溶于水、甲醇、乙醇、丙酮、四氢呋喃、乙酸乙酯、氯甲烷、苯、乙腈、苯乙烯、正己醇等，不溶于石油醚（30-60℃）。
Density0.965
Stability易吸潮,对光线敏感

别名和识别编码

Chemical NameDiacetone acrylamide
Synonym N-(2-Methyl-4-oxopentan-2-yl)acrylamide {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-yl)acrylamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(2-Methyl-4-oxopentan-2-y
CAS Number2873-97-4
PubChem Substance ID87566810
EC Number220-713-2
Beilstein Registry Number1928444
MDL NumberMFCD00008788
Reaxys-RN1928444
Merck Number2963
Chemical Name Translation双丙酮丙烯酰胺
Wiswesser Line Notation1V1X1&1&MV1U1
LabNetwork Molecule IDLN00225852
Canonical SMILESC=CC(NC(C)(CC(C)=O)C)=O
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分类

  • {SNA} Amides, Building Blocks, C8 to C20+, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
  • Acrylamide and Methacrylamide, Acrylic Monomers, Materials Science, Monomers, Polymer Science
  • {SNA} Acrylamide and Methacrylamide, Acrylic Monomers, Monomers, Polymer Science, 材料科学

相关文献及参考

  • Merck: 14,2963

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
RTECSAS3475000
Signal word
Precautionary statements
  • P301+P312+P330
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1770 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,113,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,113,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1303 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   47,179,1981

其他信息

  • 溶于水，也溶于甲醇、氯仿等大部分有机溶剂；极易与多种单体共聚，形成均聚物，聚合物具有强吸水性。
  • 双丙酮丙烯酰胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D0062 双丙酮丙烯酰胺(含稳定剂MEHQ + TBC) Diacetone Acrylamide (stabilized with MEHQ) 500G 1090元 2011/04/16 D0062 双丙酮丙烯酰胺(含稳定剂MEHQ + TBC) Diacetone Acrylamide (stabilized with MEHQ) 25G 184元 2010/06/21 352320050 双丙酮丙烯酰胺 Diacetone acrylamide 99% 5 GR 256元
  • MOL 文件:2873-97-4.mol
  • 用途一:主要作为均聚物使用，广泛用于涂料、耐湿性好的烫发用树脂及喷雾定型剂、感光树脂及其添加剂等
  • 上游原料:四氯化碳
  • F:3
  • Acros Organics:双丙酮丙烯酰胺 Diacetone acrylamide, 99%(2873-97-4)
  • MSDS 信息:N-(1,1-Dimethyl-3-oxobutyl)acrylamide(2873-97-4).msds
  • 双丙酮丙烯酰胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0062 双丙酮丙烯酰胺(含稳定剂MEHQ + TBC) Diacetone Acrylamide (stabilized with MEHQ) 500G 702元 2014/06/02 D0062 双丙酮丙烯酰胺(含稳定剂MEHQ + TBC) Diacetone Acrylamide (stabilized with MEHQ) 25G 123元 2010/06/21 352320050 双丙酮丙烯酰胺 Diacetone acrylamide 99% 5 GR 256元
  • 敏感性:Hygroscopic
  • Sigma Aldrich:2873-97-4(sigmaaldrich)
  • TCI Shanghai:N-(1,1-二甲基-3-氧代丁基)烯丙酰胺(含稳定剂甲氧基氢醌和叔丁基邻苯二酚) Diacetone Acrylamide (stabilized with MEHQ + TBC),>;98.0%(T)(2873-97-4)
  • 方法一:由丙烯腈和丙酮在浓硫酸中反应而得。
  • Alfa Aesar:二丙酮丙烯酰基酰胺,99% Diacetone acrylamide, 99%(2873-97-4)
  • 用途二:重要的乙烯基单体。聚合生成的均聚物不溶于水，但有“水呼吸性”。吸水率可达树脂自重的20-25%，而当环境湿度低于60%时，聚合物所吸收的水分又释放出来，水分对聚合物来说，起着一种增塑剂的作用。利用这种奇特的性质，可发展多种用途。（1）耐湿润性好的烫发用树脂 日本将其用于耐湿气的烫发用树脂，发型保持时间长，雨淋、冲洗不变形。（2）感光树脂将该品用作感光树脂原料的一部分，可有以下特点：感光速度快；曝光后非影像部分容易除去可以得到清晰的影像；能获得强度好、耐溶剂、耐水性好的版面。此外，还可用作不饱和聚酯树脂的交联剂，邻苯二甲酸二烯丙酯的交联剂，环氧树脂的固化剂，如用于“水呼吸性”树脂（接触眼镜、防止玻璃起雾、船底涂料等）、压敏胶粘剂、胶粘改良剂、无纺织物粘合剂、吸水性薄膜、皮革涂饰剂和改良剂、纸力增强剂、防静电聚合物、油墨等。
  • 图谱信息:双丙酮丙烯酰胺(2873-97-4)红外图谱(IR1) 双丙酮丙烯酰胺(2873-97-4)核磁图( 1 HNMR) 双丙酮丙烯酰胺(2873-97-4)核磁图( 13 CNMR) 双丙酮丙烯酰胺(2873-97-4)质谱(MS) 双丙酮丙烯酰胺(2873-97-4)红外图谱(IR2)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Amides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Amides - Carbonyl Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Acrylic Monomers - Monomers
  5. Acrylamide and Methacrylamide - Acrylic Monomers

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