CAS 591-87-7 MFCD00008721-Allyl acetate 乙酸烯丙酯 TAO{mole}

Allyl acetate 乙酸烯丙酯

CAS 591-87-7 MFCD00008721

化学结构图

SMILES: C=CCOC(C)=O

化学属性

Mol. Formula	C5H8O2
Mol. Weight	100.12
Refractive index	n20/D 1.404(lit.)
Boiling Point
Density	0.928
Melting Point	No Data Available
TSCA	Yes
Autoignition Point	705 °F
Flash Point	6.67°C
Solubility	微溶于水，可混溶于乙醇、乙醚等。

别名和识别编码

Chemical Name	Allyl acetate
CAS Number	591-87-7
PubChem Substance ID	11584
EC Number	209-734-8
Beilstein Registry Number	1742050
MDL Number	MFCD00008721
Synonym	Allyl Acetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Reaxys-RN	1742050
Merck Number	285
Chemical Name Translation	乙酸烯丙酯
Wiswesser Line Notation	1VO2U1
LabNetwork Molecule ID	LN00222042
InChI	InChI=1S/C5H8O2/c1-3-4-7-5(2)6/h3H,1,4H2,2H3
Canonical SMILES	C=CCOC(C)=O

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

生产甘油的中间体。用于有机合成。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H301 Toxic if swallowed 吞食有毒
H312 Harmful in contact with skin 皮肤接触有害
H319 Causes serious eye irritation 严重刺激眼睛
H330 Fatal if inhaled 吸入致命

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 3 F,T F;T

RTECSAF1750000

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P241+P242+P243
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P301+P310
P301+P310+P330
P301+P316
P301+P330+P331
P302+P352
P302+P352+P312+P362+P364
P302+P361+P354
P303+P361+P353
P304+P340
P304+P340+P311
P305+P351+P338
P305+P351+P338+P337+P313
P305+P354+P338
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P316
P317
P319
P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P332+P317
P337+P313
P337+P317
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P361+P364
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P403+P233
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

UN Number 2333 UN 2333 3/PG 2 UN2333

Risk Statements

R11 Highly flammable 非常易燃
R21 Harmful in contact with skin 与皮肤接触有害
R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
R25 Toxic if swallowed 吞咽有毒
R36 Irritating to eyes 刺激眼睛
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Packing GroupII

Hazard Class3/6.1

Storage condition +4°C 2-8°C 4 4℃ Refrigerator (+4°C) + Flammables area {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {

Warnings 危化品目录(2015)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 130 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,60,1949

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1021 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,60,1949

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 170 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 2,327,1964

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1000 ppm/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 21,28,1960

Restrict 危险品

其他信息

食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称允许使用该种添加剂的食品中文名称添加剂功能最大允许使用量（g/kg）最大允许残留量（g/kg）乙酸烯丙酯食品食品用香料用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
储运特性:库房通风低温干燥; 与氧化剂分开存放; 不宜久储, 以防聚合
Alfa Aesar:乙酸烯丙酯,99% Allyl acetate, 99%(591-87-7)
急性毒性:口服- 大鼠 LD50: 130 毫克/ 公斤
灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
爆炸物危险特性:与空气混合可爆
用途一:用作有机中间体
易溶于醇和醚，能溶于丙酮，微溶于水。
方法一:由丙烯、乙酸和氧在在水蒸气存在下反应，以乙酸钯为催化剂，于50-250℃进行气相反应。当反应温度在160℃时乙酸烯丙酯的空时收率为217g/L催化剂·h，乙酸转化率达99%，乙酸烯丙酯选取择性以丙烯计为94%。此反应亦可在二氧化碳存在下，以钯作催化剂（乙酸钯、乙酸镉和乙酸钾）于190℃、0.78MPa下，由丙烯、乙酸和氧制得，收率为91%。
类别:易燃液体
下游产品:丙烯醇
MSDS 信息:乙酸烯丙酯(591-87-7).msds
Sigma Aldrich:591-87-7(sigmaaldrich)
TCI Shanghai:乙酸-2-丙烯基酯 Allyl Acetate,>;98.0%(GC)(591-87-7)
海关编码:29153990
可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生刺激烟雾
Acros Organics:醋酸烯丙酯 Allyl acetate, 99%(591-87-7)
职业标准:STEL 2 毫克/ 立方米
上游原料:醋酸钯 --> 乙酸钾
乙酸烯丙酯价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 A0020 乙酸烯丙酯 Allyl Acetate 25ML 264元 2014/06/02 A0020 乙酸烯丙酯 Allyl Acetate 500ML 775元 2010/06/21 180651000 乙酸烯丙酯 Allyl acetate 99% 100 ML 362元
图谱信息:乙酸烯丙酯(591-87-7)质谱(MS) 乙酸烯丙酯(591-87-7)红外图谱(IR1) 乙酸烯丙酯(591-87-7)Raman光谱乙酸烯丙酯(591-87-7)核磁图( 13 CNMR) 乙酸烯丙酯(591-87-7)核磁图( 1 HNMR) 乙酸烯丙酯(591-87-7)红外图谱(IR2)
毒性分级:高毒
刺激数据:皮肤- 兔子 10 毫克/ 24小时轻度; 眼睛- 兔子 100 毫克/ 24 小时中度
MOL 文件:591-87-7.mol
外观性质:无色液体。
用途二:生产甘油的中间体。用于有机合成。