Dibutylstannanediyl diacetate 二乙酸二丁基锡
CAS 1067-33-0 MFCD00008697
化学结构图
SMILES: CCCC[Sn](CCCC)(OC(C)=O)OC(C)=O
化学属性
| Mol. Formula | C12H24O4Sn |
|---|---|
| Mol. Weight | 351.03 |
| Density | 1.32 |
| Refractive index | 1.4680 to 1.4710 |
| Vapor Density | 12 (vs air) |
| Boiling Point | 145°C/10mmHg(lit.) |
| Vapor Pressure | 1.3 mmHg ( 25 °C) |
| Melting Point | 7-10 |
| Flash Point | 143°C(lit.) |
| Solubility | Soluble in water and most organic solvents |
| TSCA | Yes |
别名和识别编码
| Chemical Name | Dibutylstannanediyl diacetate |
|---|---|
| Synonym | dibutylstanniumdiacetate Bis(acetyloxy)dibutylzinn DIACETOXYDIBUTYLSTANNANE Tin, dibutyl-, diacetate Dibutylzinndiacetat DIACETOXYDIBUTYLTIN Ba 2726 bis(acetyloxy)dibutyl-stannan 二乙酸二丁基锡; 二醋酸二丁基锡 NCI-C02028 fomrezsul-3 二乙酸二丁基锡 Tin, bis(acetato)dibutyl- Diacetoxybutyltin Fomrez sul-3 Bis(acetyloxy)dibutylstannane dibutyltin di(acetate) Fascat 4200 二醋酸二丁基锡 Dibutyltin diacetate 二正丁基二乙酸锡 Tegokat 233 二乙酸二丁基锡烷 Diacetoxydi-n-butyltin Fomrez SUL 3 Metacure T 1 Diacetoxydibutyltin U 200 (tin compound) |
| CAS Number | 1067-33-0 |
| EC Number | 213-928-8 |
| Beilstein Registry Number | 4136035 |
| MDL Number | MFCD00008697 |
| PubChem Substance ID | 87566997 |
| Reaxys-RN | 4136035 |
| Chemical Name Translation | 二乙酸二丁基锡 |
| Wiswesser Line Notation | 1VO-SN-4&4&OV1 |
| LabNetwork Molecule ID | LN00225933 |
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分类
- {uni_hamburg} no charge; metal-organic; ester; 1fragment
- {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotins
相关文献及参考
- Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- R48/25
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R50/53
- R60 May impair fertility 可能降低生殖能力
- R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
- R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
- R34 Causes burns 会导致灼伤
- R25 Toxic if swallowed 吞咽有毒
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P332+P313
- P302+P350
- P337+P313
- P308+P313
- P302+P352+P332+P313+P362+P364
- P273 Avoid release to the environment. 避免释放到环境中。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P305+P351+P338+P310
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P304+P340+P310
- P301+P310
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P308 IF exposed or concerned: 如果接触或涉及
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
- H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
- H370 Causes damage to organs 导致器官损伤
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- H300 Fatal if swallowed 吞食致命
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 32 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NCILB* Progress Report for Contract No. NIH-NCI-E-C-72-3252, Submitted to the National Cancer Institute by Litton Bionetics, Inc. (Bethesda, MD) Volume(issue)/page/year: NCI-E-C-72-3252,1973
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 18 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02348
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 2318 mg/kg TOXIC EFFECTS : Skin and Appendages - dermatitis, other (after systemic exposure) REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570735
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 46 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NCILB* Progress Report for Contract No. NIH-NCI-E-C-72-3252, Submitted to the National Cancer Institute by Litton Bionetics, Inc. (Bethesda, MD) Volume(issue)/page/year: NCI-E-C-72-3252,1973
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 110 mg/kg SEX/DURATION : female 7-17 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - fetal death Reproductive - Specific Developmental Abnormalities - Central Nervous System Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue) REFERENCE : AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 23,216,1992
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 15200 ug/kg SEX/DURATION : female 8 day(s) after conception TOXIC EFFECTS : Reproductive - Specific Developmental Abnormalities - musculoskeletal system REFERENCE : BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 49,715,1992
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 18700 ug/kg SEX/DURATION : female 7-17 day(s) after conception TOXIC EFFECTS : Reproductive - Maternal Effects - other effects REFERENCE : JJTHEC Japanese Journal of Toxicology and Environmental Health. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) V.38- 1992- Volume(issue)/page/year: 39,219,1993
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE
其他信息
- 二乙酸二丁基锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0302 二乙酸二丁基锡 Dibutyltin Diacetate 500G 1630元 2014/06/02 D0302 二乙酸二丁基锡 Dibutyltin Diacetate 25G 195元 2010/05/25 18595 二正丁基二乙酸锡, 95% Di-n-butyltin diacetate, 95% 250g 885元
- 用途一:用于油漆工业
- 海关编码:29310095
- 外观:浅黄色或无色透明带有醋酸气味的液体，10℃以下呈固体后半固体。 贮存时要保持干燥，温度在10℃以上为宜。低于10℃析出晶体，加热熔化后不影响使用效果
- 用途三:1067-33-0（二乙酸二丁基锡）主要用作室温硅橡胶固化催化剂，尤其是适用于脱醋酸型的有机硅制品。其特点是催化速度要比二月硅酸二丁基锡快。为了降低它的醋酸气味可以与二月硅酸二丁基锡配合使用，通常采用二醋酸二丁基锡；二月硅酸二丁基锡为1：9或2：8。本品用后应立即盖紧，它暴露在空气中容易水解，瓶口析出固体，它还可用作聚氨酯涂料催化剂。
- Acros Organics:二乙酸二丁基锡 Dibutyltin diacetate, pract.(1067-33-0)
- 蒸气压:1.3 mm Hg ( 25 °C)
- 用途二:为多用途的催化剂，用于酯交换反应、硅醇缩合反应及聚氨酯交联反应，供胶粘剂和填缝剂用
- 产品类别:有机硅酮胶固化催化剂
- Sigma Aldrich:1067-33-0(sigmaaldrich)
- 蒸气密度:12 (vs air)
- Alfa Aesar:二正丁基二乙酸锡,95% Di-n-butyltin diacetate, 95%(1067-33-0)
- MSDS 信息:Dibutyltin diacetate(1067-33-0).msds
- TCI Shanghai:二乙酸二丁基锡 Dibutyltin Diacetate,>;95.0%(W)(1067-33-0)
- MOL 文件:1067-33-0.mol
- 图谱信息:二乙酸二丁基锡(1067-33-0)核磁图( 13 CNMR) 二乙酸二丁基锡(1067-33-0)红外图谱(IR1) 二乙酸二丁基锡(1067-33-0)质谱(MS)
- TSCA:Yes
