CAS 592-88-1 MFCD00008658-Diallyl sulfide 二烯丙基硫醚 TAO{mole}

Diallyl sulfide 二烯丙基硫醚

CAS 592-88-1 MFCD00008658

化学结构图

SMILES: C=CCSCC=C

化学属性

Mol. Formula	(CH2=CHCH2)2S
Mol. Weight	114
Refractive index	1.4880 to 1.4920
Boiling Point	138
Density	0.89
Melting Point	-83
Flash Point	46°C(lit.)
TSCA	Yes
Vapor Density	3.9 (vs air)
Vapor Pressure	7 mmHg ( 20 °C)
Solubility	不溶于水，可混溶于乙醇、乙醚、氯仿、四氯化碳。
pH	:A

别名和识别编码

Chemical Name	Diallyl sulfide
Synonym	1-propene, 3,3'-thiobis- 2-PROPENYL SULPHIDE 2-Propenylsulfid 3,3'-thiobis-1-propene 3,3'-Thiobis-1-propene Diallyl sulfide NSC 20947 二烯丙基硫醚 ALLYL SULFIDE Allyl sulfide DIALLYL SULPHIDE Di(2-propenyl) sulfide Diallyl monosulfide Diallyl sulfide Diallyl thioather Diallyl thioether Diallylsulfid FEMA 2042 NSC 20947 Oil garlic THIOALLYL ETHER Thioallyl ether Thioallylether allyl sulfide allyl sulphide allylmonosulfide diallyl sulfide diallyl sulphide diallylsulfane diallylsulfide garlic oil {} {} {} {} {} {Chemicalboo {} {} {} {} {} {} {SNA {} {} {} {} {} {} {} {Chemicalbook} {} {} {} {} {} {} {
CAS Number	592-88-1
PubChem Substance ID	11617
EC Number	209-775-1
Beilstein Registry Number	1736016
MDL Number	MFCD00008658
Reaxys-RN	1736016
Merck Number	297
Chemical Name Translation	二烯丙基硫醚
Wiswesser Line Notation	1U2S2U1
LabNetwork Molecule ID	LN00164457
InChI	InChI=1S/C6H10S/c1-3-5-7-6-4-2/h3-4H,1-2,5-6H2

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安全信息

GHS Symbol

WGK Germany2

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 3

RTECSBC4900000

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P303+P361+P353
P305+P351+P338
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P370+P378
P403+P235
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S37 Wear suitable gloves 戴适当手套；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；

Risk Statements

R10 Flammable 易燃
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

UN Number 1993

Packing GroupIII

Hazard Class3

Storage condition 2-8°C

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2980 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   26,299,1988

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 330 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle contraction or spasticity
   Lungs, Thorax, or Respiration - other changes
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   BIJOAK Biochemical Journal.  (Biochemical Soc. Book Depot, POB 32, Commerce
   Way, Colchester, Essex CO2 8HP, UK)  V.1-    1906- Volume(issue)/page/year:
   4,107,1909

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   26,299,1988

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 600 mg/L
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   35,379,1997

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 200 mg/L
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   35,379,1997

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 300 mg/L
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   35,379,1997

其他信息

Alfa Aesar:二烯丙基硫醚,98% Diallyl sulfide, 98%(592-88-1)
毒性分级:中毒
二烯丙基硫醚价格(试剂级):更新日期产品编号产品名称包装价格 2010/06/21 103021000 二烯丙基硫醚 Allyl sulfide 97% 100 ML 1080元 2010/06/21 103020250 二烯丙基硫醚 Allyl sulfide 97% 25 ML 330元 2010/05/25 L10971 二烯丙基硫醚, 98% Diallyl sulfide, 98% 25g 260元
TCI Shanghai:二烯丙基硫醚 Allyl Sulfide,>;98.0%(GC)(592-88-1)
FEMA:2042
参考质量标准:FAO/WHO，1999 折射率(n D 20 ) 1.488～1.492 相对密度(d 25 25 ) 0.887～0.892
灭火剂:泡沫、干粉、二氧化碳、砂土
类别:有毒物品
急性毒性:口服-大鼠 LD50: 2980 毫克/ 公斤
海关编码:29309070
方法一:GB 2760--2002规定为允许使用的食品用香料。主要用于配制洋葱、大蒜、辣椒、小萝卜、芥菜等香精。
蒸气密度:3.9 (vs air)
储运特性:库房通风低温干燥; 与食品、氧化剂、酸类、含水物分开储运
使用限量:FEMA(mg/kg)：饮料0.04；冷饮0.06；糖果，0.07；焙烤制品0.05；调味品13；肉类3.7。 FDA，§172．515：适量为限。
Acros Organics:单硫化二丙烯 Allyl sulfide, 97%(592-88-1)
用途一:用作日用、食用香精
毒性:GRAS(FEMA)。
图谱信息:二烯丙基硫醚(592-88-1)质谱(MS) 二烯丙基硫醚(592-88-1)核磁图( 1 HNMR) 二烯丙基硫醚(592-88-1)核磁图( 13 CNMR) 二烯丙基硫醚(592-88-1)红外图谱(IR1)
外观性质:无色油状液体, 有蒜臭味。
上游原料:硫化钠 --> 九水硫化钠 --> 辣椒 --> 大蒜
Sigma Aldrich:592-88-1(sigmaaldrich)
蒸气压:7 mm Hg ( 20 °C)
爆炸物危险特性:与N-溴代丁二酰胺起爆炸反应
MOL 文件:592-88-1.mol
MSDS 信息:二烯丙基硫醚(592-88-1).msds
食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称允许使用该种添加剂的食品中文名称添加剂功能最大允许使用量（g/kg）最大允许残留量（g/kg）二烯丙基硫醚食品食品用香料用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
可燃性危险特性:明火可燃; 燃烧放出有毒硫氧化物烟雾; 遇热或遇水蒸气放出有毒硫化氢蒸气
下游产品:氯哌噻吨