CAS 124-02-7 MFCD00008642-Diallylamine 二烯丙基胺 TAO{mole}

Diallylamine 二烯丙基胺

CAS 124-02-7 MFCD00008642

化学结构图

SMILES: C=CCNCC=C

化学属性

Mol. Formula	C6H11N
Mol. Weight	97.16
Density	0.787
Refractive index	1.4390 to 1.4420
Vapor Density	3.35 (vs air)
Boiling Point	111-112
Vapor Pressure	18 mmHg ( 20 °C)
Melting Point	-88
Flash Point	14°C(lit.)
TSCA	Yes
Solubility	8.6 G/100ML

别名和识别编码

Chemical Name	Diallylamine
Synonym	Diallylamine {LY} Diallylamine Diallylamine,99% Diallymine N,N-Di(2-propenyl)amine N,N-Diallylamine N,N-二烯丙[基]胺 N-2-Propenyl-2-propen-1-amine N-2-丙烯基-2-丙烯-1-胺 N-Allyl-2-propen-1-amine N-Nitroso-N-2-propenyl-2-propen-1-amine N-prop-2-enylprop-2-en-1-amine diallyamine diallyl-amin diallyl-amine diallylamine n-2-propenyl-2-propen-1-amin {} {LY} Diallylamine {} {} {LY} Diallylamine {} {} {} {LY} Diallylamine {} {} {} {} {LY} Diallylamine {} {} {} {} {} {LY} Diallylamine {} {} {} {} {} {} {LY} Diallylamine {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Diallylamine {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} Diallylamine {} {} {} {} {} {} {} {} {} {LY} Diallylamine {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {}
CAS Number	124-02-7
EC Number	204-671-2
Beilstein Registry Number	773718
MDL Number	MFCD00008642
Merck Number	2971
PubChem Substance ID	31279
Reaxys-RN	773718
Chemical Name Translation	二烯丙基胺
Wiswesser Line Notation	1U2M2U1
LabNetwork Molecule ID	LN00238649
InChI	InChI=1S/C6H11N/c1-3-5-7-6-4-2/h3-4,7H,1-2,5-6H2
Canonical SMILES	C=CCNCC=C

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品牌质保精细包装现货库存一流品牌服务

产品应用

有机中间体。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R11 Highly flammable 非常易燃
R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
R24 Toxic in contact with skin 与皮肤接触有毒
R34 Causes burns 会导致灼伤
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P241+P242+P243
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P301+P330+P331
P301+P330+P331+P310
P302+P352
P303+P361+P353
P303+P361+P353+P310+P363
P304+P312
P304+P340
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P337+P313
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P403+P233
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

RTECSUC6650000

Packing GroupII

UN Number 2359

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Codes 3 F,T F;T

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H302 Harmful if swallowed 吞食有害
H311 Toxic in contact with skin 皮肤接触中毒
H311+H331
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H331 Toxic if inhaled 吸入中毒
H332 Harmful if inhaled 吸入有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Class3/6.1, 8

Warnings 危化品目录(2015)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 355 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,43,1982

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 5 ppm/5M
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Lungs, Thorax, or Respiration - structural or functional change in trachea
   or bronchi
REFERENCE :
   AEHLAU Archives of Environmental Health.  (Heldref Pub., 4000 Albemarle St.,
   NW, Washington, DC 20016)  V.1-    1960-  Volume(issue)/page/year:
   1,343,1960

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 795 ppm/8H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Sense Organs and Special Senses (Eye) - lacrimation
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   AEHLAU Archives of Environmental Health.  (Heldref

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 578 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - other changes
REFERENCE :
   AEHLAU Archives of Environmental Health.  (Heldref Pub., 4000 Albemarle St.,
   NW, Washington, DC 20016)  V.1-    1960-  Volume(issue)/page/year:
   1,343,1960

Restrict 危险品

其他信息

Acros Organics:二烯丙胺 Diallylamine, 97%(124-02-7)
Alfa Aesar:二烯丙基胺,98% Diallylamine, 98%(124-02-7)
检测方法:GC
Sigma Aldrich:124-02-7(sigmaaldrich)
方法一:由二烯丙基氰胺水解而得。水解反应在硫酸介质中进行，缓和回流6h。产率80-88%。
溶于水、醇、醚、苯，有氨臭。水中溶解度：90 g/l。
灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
急性毒性:口服- 大鼠 LD50: 578 毫克/ 公斤; 口服- 小鼠 LD50: 355 毫克/ 公斤
二烯丙基胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xw010100 二烯丙基胺 100ml 160元 2011/04/16 D0069 二烯丙基胺 Diallylamine 500ML 575元 2011/04/16 D0069 二烯丙基胺 Diallylamine 25ML 153元
TCI Shanghai:二烯丙基胺 Diallylamine,>;98.0%(GC)(124-02-7)
图谱信息:二烯丙基胺(124-02-7)质谱(MS) 二烯丙基胺(124-02-7)红外图谱(IR1)
类别:易燃液体
MSDS 信息:二烯丙胺(124-02-7).msds
用途三:二烯丙基胺{124-02-7}应用于制做交联型无醛固色剂（二烯丙基胺与二甲基二烯丙基氯化铵共聚）、交联剂、制药中间体、以及农用化学品、染料和涂料、有机合成和树脂改良剂等的中间体。还可以用于制备两性高分子聚合物等。国内生产厂家较少，只有山东的铭兴化工和鲁岳在批量生产，国外生产的有德国洋樱集团生产的和美国利田化学的。
上游原料:烯丙基腈
用途二:有机中间体。
职业标准:STEL 1 毫克/ 立方米
可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
刺激数据:皮肤- 兔子 100 微克/ 24小时; 眼睛- 兔子 50 毫克/ 20秒重度
蒸气压:18 mm Hg ( 20 °C)
蒸气密度:3.35 (vs air)
MOL 文件:124-02-7.mol
F:2-10
毒性分级:高毒
敏感性:Air Sensitive
用途一:用作有机合成原料、离子净水剂、聚合物单体、制药中间体等
储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
外观性质:无色液体。