Trimethyl((1-phenylvinyl)oxy)silane 1-苯基-1-三甲硅氧基乙烯
CAS 13735-81-4 MFCD00008582
化学结构图
SMILES: C[Si](C)(C)OC(=C)C1C=CC=CC=1
化学属性
| Mol. Formula | C11H16OSi |
|---|---|
| Mol. Weight | 192.33 |
| Density | 0.938 |
| Refractive index | 1.5000 to 1.5040 |
| Boiling Point | 94°C/15mmHg(lit.) |
| Flash Point | 78°C(lit.) |
| TSCA | Yes |
| Vapor Density | >;1 (vs air) |
别名和识别编码
| Chemical Name | Trimethyl((1-phenylvinyl)oxy)silane |
|---|---|
| Synonym | α-(三甲基硅氧基)苯乙烯 α-(三甲基硅氧基)苯乙烯 1-苯基-1-三甲硅氧基乙烯 1-苯基-1-三甲基硅氧乙烯 alpha-(Trimethylsiloxy)styrene 1-苯基-1-三甲硅氧基乙烯 |
| CAS Number | 13735-81-4 |
| EC Number | 237-308-1 |
| Beilstein Registry Number | 1306914 |
| MDL Number | MFCD00008582 |
| Reaxys-RN | 1306914 |
| PubChem Substance ID | 87575374 |
| Chemical Name Translation | 1-苯基-1-三甲硅氧基乙烯 |
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分类
- {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds
相关文献及参考
- For a review of the synthetic applications of silyl enol ethers, see: Synthesis, 91 (1977).
- The TiCl4 promoted crossed aldol condensation with acetone illustrates the reaction of silyl enol ethers with aldehydes and ketones: Org. Synth. Coll., 8, 323 (1993). For a further example and reaction scheme, see 1-(Trimethylsiloxy)cyclohexene, A16099. For an alternative catalyst for this type of reaction, see Tetra-n-butylammonium fluoride, A10588.
- ɑ-Arylation with diazonium fluoroborates to give ɑ-arylacetophenones (deoxybenzoins) occurs in pyridine, and also in other solvents in the presence of a Pd catalyst: J. Chem. Soc. Perkin 1, 283 (1994).
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H227 Combustible liquid 可燃液体
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P332+P313
- P370+P378
- P305+P351+P338+P337+P313
- P302+P350
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P302+P352+P332+P313+P362+P364
- P403+P235
- P302+P352+P332+
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
