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• 试剂商城
• 直接询价

分类

• {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfides/Disulfides, Sulfur Compounds
• {Chemicalbook} 食品添加剂: 食用香料（增香剂）: 天然等同香料和人造香
• {SA} Alphabetical Listings, Flavors and Fragrances, M-N
• {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; sulfide; 1fragment

产品应用

• 高效启动剂，用于酸催化裂解N-Z, O-benzyl 和 O-methyl保护基团。

相关文献及参考

• Beilstein:6,297
• Short: II/24C
• Cation scavenger in the acidic deprotection of peptides; see, e.g.: Int. J. Pept. Prot. Res., 36, 255 (1990). See Appendix 6. The combination of the soft nucleophile thioanisole and the hard acid triflic acid has been used for the cleavage of methyl ethers, e.g. O-methyltyrosine, resistant to other methods: J. Chem. Soc., Chem. Commun., 971 (1979). The same conditions have been used for the cleavage of Cbz, Boc, benzyl and 4-methoxybenzyl protecting groups in peptide synthesis: Chem. Pharm. Bull., 28, 1214 (1980); 29, 600 (1981); J. Chem. Soc., Chem. Commun., 101 (1980); see also: Angew. Chem. Int. Ed., 33, 1729 (1994).
• Short: II/24B
• Monolithiation is thought to occur initially on the ring, but rearrangement then gives the more stable phenylthiomethyllithium: J. Org. Chem., 31, 4097 (1966); Tetrahedron Lett., 1961 (1977). Further metallation occurs at the ortho-position. See, e.g.: Tetrahedron, 46, 861 (1990). Demetallation and acylation is the basis of a route to 3-substituted benzo[b]thiophenes: Synthesis, 888 (1988):

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00184

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 891 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCBPBS Pesticide Biochemistry and Physiology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1971-  Volume(issue)/page/year:
   1,356,1971

其他信息

• 下游产品:2-乙酰-3-甲基苯并[B]噻吩 --> 4，4-二甲基-6-乙酰基硫代苯并二氢吡喃 --> 3-甲基苯并[B]噻吩-2-羰醛 --> 2-溴-1-(4-甲磺酰基)苯乙酮 --> 3-甲基苯噻吩 --> 醋酸奥曲肽 --> 2-甲基-4-苯基硫基-2-丁醇
• Alfa Aesar:硫代苯甲醚,99% Thioanisole, 99%(100-68-5)
• 敏感性:Stench
• 图谱信息:甲基苯基硫醚(100-68-5)核磁图( 1 HNMR) 甲基苯基硫醚(100-68-5)红外图谱(IR1) 甲基苯基硫醚(100-68-5)质谱(MS) 甲基苯基硫醚(100-68-5)核磁图( 13 CNMR)
• 用途一:用作农药、医药、染料中间体
• 检测方法:GC,NMR
• 用途二:高效启动剂，用于酸催化裂解N-Z, O-benzyl 和 O-methyl保护基团。
• 参考质量标准:FAO/WHO，1999 含量(GT-10-4) ≥98% 折射率(n D 20 ) 1.532～1.551 相对密度(d 25 25 ) 0.958～0.968
• 甲基苯基硫醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 T0191 甲基苯基硫醚 Thioanisole 25ML 239元 2011/04/16 T0191 甲基苯基硫醚 Thioanisole 500ML 1430元 2010/06/21 138675000 甲基苯基硫醚 Thioanisole 99% 500 GR 1449元
• 海关编码:29309070
• 不溶于水，溶于大多数有机溶剂。
• Hazard Note:Harmful/Stench
• TCI Shanghai:甲基苯基硫醚 Thioanisole,>;99.0%(GC)(100-68-5)
• MSDS 信息:Methyl phenyl sulfide(100-68-5).msds
• 毒性:GRAS(FEMA)。
• Sigma Aldrich:100-68-5(sigmaaldrich)
• FEMA:3873
• Acros Organics:苯甲硫醚 Thioanisole, 99%(100-68-5)
• MOL 文件:100-68-5.mol
• 使用限量:FEMA(mg/kg)：焙烤制品0.06～1.0；无醇饮料0.2～2.0；油脂0.01～0.04；明胶、布丁、调味汁，0.1～1.0；肉类制品0.4～4.0；调味香料0.5～1.0。
• 甲基苯基硫醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0191 甲基苯基硫醚 Thioanisole 25ML 227元 2014/06/02 T0191 甲基苯基硫醚 Thioanisole 500ML 1360元 2010/06/21 138675000 甲基苯基硫醚 Thioanisole 99% 500 GR 1449元
• F:13