Methyldiphenylphosphine 二苯基甲基膦

CAS 1486-28-8 MFCD00008508

化学结构图

1486-28-8
SMILES: CP(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC13H13P
Mol. Weight200.22
Density1.076
Boiling Point186°C/50mmHg(lit.)
Refractive index1.6230 to 1.6260
Flash Point>110°(230°F)
TSCANo
Stability对空气敏感
Appearance colorless liq.
Melting Point117-118 °C

别名和识别编码

Chemical NameMethyldiphenylphosphine
CAS Number1486-28-8
EC Number216-065-5
Beilstein Registry Number16(2)371
MDL NumberMFCD00008508
Synonym Methyldiphenylphosphine {LY} Methyldiphenylphosphine {} {LY} Methyldiphenylphosphine {} {} {LY} Methyldiphenylphosphine {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID73879
Reaxys-RN743075
Chemical Name Translation二苯基甲基膦
InChIKeyUJNZOIKQAUQOCN-UHFFFAOYSA-N
LabNetwork Molecule IDLN00201887
InChIInChI=1S/C13H13P/c1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
Canonical SMILESCP(C1=CC=CC=C1)C2=CC=CC=C2
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands

相关文献及参考

  • Beilstein:16(2)371

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S17 Keep away from combustible material 远离可燃物料;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from lig
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Hazard Codes Xn
Restrict 危险品

其他信息

  • 图谱信息:二苯基甲氧基膦(1486-28-8)红外图谱(IR1) 二苯基甲氧基膦(1486-28-8)核磁图( 13 CNMR) 二苯基甲氧基膦(1486-28-8)核磁图( 1 HNMR) 二苯基甲氧基膦(1486-28-8)质谱(MS)
  • TCI Shanghai:二苯基甲基膦 Methyldiphenylphosphine,>;97.0%(GC)(1486-28-8)
  • 敏感性:Air Sensitive
  • Sigma Aldrich:1486-28-8(sigmaaldrich)
  • Acros Organics:二苯基甲基膦 Methyldiphenylphosphine, 99%(1486-28-8)
  • F:1-10
  • 二苯基甲氧基膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1318 二苯基甲基膦 Methyldiphenylphosphine 5G 714元 2014/06/02 M1318 二苯基甲基膦 Methyldiphenylphosphine 1G 240元 2010/06/21 408970050 二苯基甲氧基膦 Methyldiphenylphosphine 99% 5 GR 681元
  • Alfa Aesar:甲基联苯膦,99% Methyldiphenylphosphine, 99%(1486-28-8)
  • MOL 文件:1486-28-8.mol

系列性分类


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