CAS 60-11-7 MFCD00008308-N,N-dimethyl-4-(phenyldiazenyl)aniline 甲基黄 TAO{mole}

N,N-dimethyl-4-(phenyldiazenyl)aniline 甲基黄

CAS 60-11-7 MFCD00008308

化学结构图

SMILES: CN(C)c1ccc(N=Nc2ccccc2)cc1

化学属性

Mol. Formula	C14H15N3
Mol. Weight	225.29
Density	1.422
Melting Point	111°C
TSCA	Yes
Solubility	Insoluble in water. Soluble in alcohol.
Stability	对湿度敏感
Boiling Point	371.0±25.0 °C at 760 mmHg
Flash Point	178.2±23.2 °C

别名和识别编码

Chemical Name	N,N-dimethyl-4-(phenyldiazenyl)aniline
Synonym	Methyl yellow {LY} Methyl yellow {} {LY} Methyl yellow {} {} {LY} Methyl yellow {} {} {} {LY} Methyl yellow {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {} {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl yellow {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl yellow
CAS Number	60-11-7
EC Number	200-455-7
Beilstein Registry Number	16,312
MDL Number	MFCD00008308
PubChem Substance ID	6053
Merck Number	3229
Reaxys-RN	746017
Chemical Name Translation	甲基黄
Wiswesser Line Notation	1N1&R DNUNR
LabNetwork Molecule ID	LN00221233
InChI	InChI=1S/C14H15N3/c1-17(2)14-10-8-13(9-11-14)16-15-12-6-4-3-5-7-12/h3-11H,1-2H3
Canonical SMILES	CN(C)C1=CC=C(/N=N/C2=CC=CC=C2)C=C1

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产品应用

酸碱指示剂，pH2.9(红)～4.0(黄)，测定胃液中的游离盐酸，过氧化脂肪的点滴试验。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R25 Toxic if swallowed 吞咽有毒
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P310
P302+P350
P302+P352+P332+P313+P362+P364
P304+P340
P305+P351+P338
P308+P313
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P403+P233
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H301 Toxic if swallowed 吞食有毒
H351 Suspected of causing cancer 怀疑致癌

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

RTECSBX7350000

Packing GroupIII

UN Number 2811 3143 UN 2811 6.1/PG 3 UN2811

Hazard Codes 6.1 T

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Store at RT. {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, prote

Hazard Class6.1

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2331 mg/kg/7W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
REFERENCE :
   KTUNAA K'at'ollik Taehak Uihakpu Nonmunjip.  Journal of Catholic Medical
   College.  (Catholic Medical College, Graduate School, Seoul 135, S. Korea)
   V.1-    1957-  Volume(issue)/page/year: 32,229,1979

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1920 mg/kg/14W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   5,235,1945

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 13 gm/kg/53W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
REFERENCE :
   MEXPAG Medicina Experimentalis.  (Basel, Switzerland)  V.1-11, 1959-64;
   V.18-19, 1968-69.  For publisher information, see JNMDBO.
   Volume(issue)/page/year: 4,1,1961

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1440 mg/kg/90W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   26,2406,1966

TYPE OF TEST            : TD - Toxic dose

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 230 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   34,2274,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GANNA2 Gann.  Japanese Journal of Cancer Research.  (Tokyo, Japan)  V.1-75,
   1907-84.  For publisher information, see JJCREP.  Volume(issue)/page/year:
   54,455,1963

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ZEKBAI Zeitschrift fuer Krebsforschung.  (Berlin, Fed. Rep. Ger.)  V.1-75,
   1903-71.  For publisher information, see JCROD7.  Volume(issue)/page/year:
   69,103,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 230 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   34,2274,1974

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 5 mg/L
REFERENCE :
   PMRSDJ Progress in Mutation Research.  (Elsevier Science Pub. Co., Inc., 52
   Vanderbilt Ave., New York, NY 10017)  V.1-    1981- Volume(issue)/page/year:
   1,491,1981

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 1 umol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   46,1654,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 33 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 9(Suppl
   9),1,1987

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 100 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume

TYPE OF TEST            : Body fluid assay
TEST SYSTEM             : Rodent - rat Bacteria - Salmonella typhimurium
DOSE/DURATION           : 600 mg/kg
REFERENCE :
   NATUAS Nature.  (Nature Subscription Dept., POB 1018, Manasguan, NJ 08736)
   V.1-    1869-  Volume(issue)/page/year: 249,850,1974

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Kidney
DOSE/DURATION           : 25 mg/L
REFERENCE :
   PMRSDJ Progress in Mutation Research.  (Elsevier Science Pub. Co., Inc., 52
   Vanderbilt Ave., New York, NY 10017)  V.1-    1981- Volume(issue)/page/year:
   1,638,1981

TYPE OF TES

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 3 gm/kg
SEX/DURATION            : male 5 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
REFERENCE :
   PMRSDJ Progress in Mutation Research.  (Elsevier Science Pub. Co., Inc., 52
   Vanderbilt Ave., New York, NY 10017)  V.1-    1981- Volume(issue)/page/year:
   1,712,1981

其他信息

Alfa Aesar:甲基黄,98% Methyl Yellow, 98%(60-11-7)
溶剂黄 2价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 71013954 二甲基黄;甲基黄; 对二甲氨基偶氮苯; 奶油黄 25g 23.2元 2011/04/16 D0231 甲基黄 Methyl Yellow 25G 277元 2010/06/21 151401000 溶剂黄 2 Methyl Yellow , pure, indicator grade 100 GR 678元
MOL 文件:60-11-7.mol
海关编码:29270000
外观性质:桔黄色叶状晶体。
Acros Organics:甲基黄/(4-二甲基氨基偶氮苯) Methyl Yellow, indicator grade, pure(60-11-7)
用途一:该品为酸碱指示剂。pH2.9（红）-4.0（黄）。非水溶液滴定用指示剂及胃液中游离盐酸的测定。
用途二:酸碱指示剂，pH2.9(红)～4.0(黄)，测定胃液中的游离盐酸，过氧化脂肪的点滴试验。
上游原料:无水醋酸钠 --> 二甲苯胺
Sigma Aldrich:60-11-7(sigmaaldrich)
TCI Shanghai:甲基黄 Methyl Yellow(60-11-7)
色指数:11020
方法一:由苯胺与亚硝酸钠重氮化，再与二甲苯胺偶合而得。将苯胺慢慢加入有碎冰的浓盐酸中，在0-5℃加亚硝酸钠溶液进行重氮化反应。再将二甲苯胺加入重氮盐中，控制温度在5℃以下，边搅拌边加入工业乙酸钠，搅拌3h后再加少量乙酸钠，过滤出黄色沉淀即得粗品。干燥后用甲苯重结晶，再用乙醇重结晶即得成品二甲基黄。
MSDS 信息:对二甲基氨基偶氮苯(60-11-7).msds
能醇于醇、苯、氯仿、醚、石油醚和矿酸，不溶于水。
图谱信息:溶剂黄 2(60-11-7)核磁图( 13 CNMR) 溶剂黄 2(60-11-7)质谱(MS) 溶剂黄 2(60-11-7)红外图谱(IR1) 溶剂黄 2(60-11-7)核磁图( 1 HNMR) 溶剂黄 2(60-11-7)红外图谱(IR2)