CAS 103-67-3 MFCD00008289-N-Benzylmethylamine N-甲基苄胺 TAO{mole}

N-Benzylmethylamine N-甲基苄胺

CAS 103-67-3 MFCD00008289

化学结构图

SMILES: CNCc1ccccc1

化学属性

Mol. Formula	C8H11N
Mol. Weight	121.18
Density	0.939
Refractive index	1.5210 to 1.5240
Flash Point	75°C
TSCA	Yes
Boiling Point	180.5°C at 760 mmHg
Melting Point	-24°C
Solubility	65 G/L (20 ºC)
Stability	对空气敏感
Appearance	无色至浅黄色液体。沸点184-186℃，相对密度0.9360（20/4℃），折光率1.5210。闪点77℃，易溶于有机溶剂。有苄胺臭味。
pH	:A

别名和识别编码

Chemical Name	N-Benzylmethylamine
MDL Number	MFCD00008289
CAS Number	103-67-3
EC Number	203-133-4
Beilstein Registry Number	606221
Synonym	N-Methylbenzylamine {uni_hamburg} N-Methy-N-benzylamine N-Methyl Benylamine N-Methyl(phenyl)methanamine N-Methyl-N-(phenylmethyl)amine N-Methyl-N-benzylamine {} {JNK} N-Benzylmethylamine; ω-Methylaminotoluene {} {} {Chemblink} N-Benzylmethylamine; N-Benzyl-N-methylamine {} {} {} {} {} {} {JNK} N-Benzylmethylamine; -Methylaminotoluene {} {} {} {} {uni_hamburg} N-Benzylmethylamine {} {} {} {} {} { {} {} {} {} {} {Chemicalbook} N-Benzyldimethylamine~98% {} {} {} {} {} {} {uni_hamburg} N-Benzyl-N-methylamine {} {} {} {} {} {} {} {Chemicalbook} N-BENZYLMETHYLAMINE {} {} {} {} {} {} {} {} {Chemicalbook} N-BENZYL-N-METHYLAMINE {} {} {} {} {} {} {} {} {} {uni_hamburg} N-(Phenylmethyl)methylamine {} {} {} {} {} {} {} {} {} {} {Chemicalbook} Benzenemethanamine,N-methyl- {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID	7669
Reaxys-RN	606221
Chemical Name Translation	N-甲基苄胺
InChIKey	RIWRFSMVIUAEBX-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00223583
InChI	InChI=1S/C8H11N/c1-9-7-8-5-3-2-4-6-8/h2-6,9H,7H2,1H3
Canonical SMILES	CNCC1=CC=CC=C1

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产品应用

医药中间体，有机溶剂，也用于染料生产和其他有机合成。

安全信息

Signal word

GHS Symbol

WGK Germany1

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R42/43
R34 Causes burns 会导致灼伤

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P303+P361+P353+P310+P363
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P405 Store locked up. 上锁保管。
P370+P378
P333+P313
P303+P361+P353
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P304+P340+P310
P403+P235
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P305+P351+P338+P310
P301+P330+P331+P310

Packing GroupII

UN Number

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light 对空气敏感，密封保存。

Hazard statements

H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
H227 Combustible liquid 可燃液体

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes C

Hazard Class8

其他信息

Acros Organics:N-甲基苄胺 N-Methylbenzylamine, 97%(103-67-3)
TCI Shanghai:N-甲基苄胺 N-Methylbenzylamine,>;98.0%(GC)(T)(103-67-3)
海关编码:29214980
敏感性:Air Sensitive
用途二:医药中间体，有机溶剂，也用于染料生产和其他有机合成。
MOL 文件:103-67-3.mol
MSDS 信息:N-Methylbenzylamine(103-67-3).msds
Sigma Aldrich:103-67-3(sigmaaldrich)
存储注意事项:氮气保护
方法一:由氯化苄与一甲胺在苯溶剂中反应而得。将一甲胺和苯加入反应锅，于25℃滴加氯化苄，约5-6h加完，升温至45℃反应4h。加入氢氧化钠，再保温1h。静置分层，苯层常压蒸馏至140℃后，再减压蒸馏，收集75-130℃（2.0-6.67kPa），馏分即为苄基甲胺。
N-甲基苄胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 M0164 N-甲基苄胺 N-Methylbenzylamine 500ML 355元 2014/06/02 M0164 N-甲基苄胺 N-Methylbenzylamine 25ML 96元 2010/06/21 106045000 N-甲基苄胺 N-Methylbenzylamine 97% 500 ML 557元
F:2-10
Alfa Aesar:N-苄基基马来甲胺97% N-Benzylmethylamine, 97%(103-67-3)
图谱信息:N-甲基苄胺(103-67-3)Raman光谱 N-甲基苄胺(103-67-3)核磁图( 1 HNMR) N-甲基苄胺(103-67-3)红外图谱(IR1) N-甲基苄胺(103-67-3)质谱(MS) N-甲基苄胺(103-67-3)核磁图( 13 CNMR)
下游产品:N-苄基-6-氯-N-甲基哒嗪-3-胺 --> 1-(3-羟基苯基)-2-[甲基(苯基甲基)氨基]乙酮 --> 优降宁
用途一:用作医药、染料中间体
易溶于有机溶剂，有苄胺臭味,水溶性65g/L(20℃)。