Dimethylphenylsilane 二甲基苯基硅烷
CAS 766-77-8 MFCD00008257
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Others
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Other Organosilicon
产品应用
- F-- 和 H+-催化的酮还原;硅烷化试剂;用于烯醇醚合成的试剂。
相关文献及参考
- Beilstein:16(4)1360
- For a review of silane reductions, see: Org. Prep. Proced. Int., 12, 13 (1980).
- For an example of reduction of a ß-keto amide to a ß-hydroxy amide, see: Org. Synth. Coll., 8, 326 (1993).
- Reagent for the highly diastereoselective reduction of ketones to alcohols, in the presence of TBAF or TFA: J. Am. Chem. Soc., 106, 4629 (1984); J. Org. Chem., 53, 5415 (1988):
- Short: III/35C4
- Short: III/35F
- Silylation of hydroxyl groups gives DMPS ethers under very mild conditions using TBAF catalysis: Tetrahedron Lett., 35, 8413 (1994). See also Chlorodimethylphenylsilane, A15638 and Appendix 4.
安全信息
GHS Symbol
- H318 Causes serious eye damage 严重伤害眼睛
- H226 Flammable liquid and vapour 易燃液体和蒸气
- P403+P235
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P302+P352+P332+P313+P362+P364
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P370+P378
- P305+P351+P338+P337+P313
- P303+P361+P353
- P233 Keep container tightly closed. ?保持容器密闭。
- P337+P313
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P241+P242+P243
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R10 Flammable 易燃
- R36 Irritating to eyes 刺激眼睛
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;