(R)-(-)-2-Phenylglycinol D-苯甘氨醇
CAS 56613-80-0 MFCD00008062
化学结构图
SMILES: N[C@@H](CO)c1ccccc1
化学属性
| Mol. Formula | C8 |
|---|---|
| Mol. Weight | 137 |
| Melting Point | 75-77 |
| TSCA | No |
| Density | 1.104 |
| Stability | 对空气敏感 |
别名和识别编码
| Chemical Name | (R)-(-)-2-Phenylglycinol |
|---|---|
| CAS Number | 56613-80-0 |
| Alfabeta Name | PHENYLGLYCINOL R2(())---- |
| MDL Number | MFCD00008062 |
| Synonym | (R)-(-)-2-Amino-2-phenylethanol (R)-(-)-2-氨基-2-苯基乙醇;(R)-(-)-2-苯基-2-氨基乙醇 (R)-2-Amino-2-phenylethanol, D-(−)-α-Phenylglycinol (R)-2-氨基-2-苯乙醇 D-(-)-α-苯甘氨醇 (R)-2-氨基-2-苯乙醇 D-(-)-α-苯甘氨醇 D-(-)-α-苯甘氨醇 R-苯甘氨醇,右旋苯甘氨醇,2-苯甘氨酸 |
| Beilstein Registry Number | 2935848 |
| PubChem Substance ID | 87575300 |
| EC Number | 260-287-5 |
| Reaxys-RN | 2935848 |
| Chemical Name Translation | D-苯甘氨醇 |
| LabNetwork Molecule ID | LN00009350 |
| InChIKey | IJXJGQCXFSSHNL-UHFFFAOYSA-N |
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分类
- {SNA} Amino Acid Derivatives, Amino Alcohols, Chemical Biology, Chemical Synthesis, Peptide Chemistry
- Catalyst
- {SA} Amino Acid Derivatives, Amino Alcohols, Chemical Biology, Chemical Synthesis, Peptide Chemistry
- Chiral Reagents
- {SNA} Amino Acids & Derivatives, Amino Alcohols, Chemical Biology, Chemical Synthesis, Peptide Chemistry
- Pharmaceuticals
- Amines
- Intermediates & Fine Chemicals
- Aromatics
产品应用
- 作为合成的结构单元使用的手性 β-氨基醇。
- 本氨基醇可用于由三氟丙酮酸乙酯制备手性亚胺或噁唑烷。然后，可将这些中间体用于合成 α-三氟甲基脯氨酸的两种对映体。
相关文献及参考
- Tetrahedron Lett. 45 , 5287, (2004)
- Condensation with glutaraldehyde gives a useful intermediate in asymmetric synthesis of alkaloids: Org. Synth. Coll., 9, 176 (1998):
- Beilstein:13(4)1835
- Condensation with glutaraldehyde gives a useful intermediate in asymmetric synthesis of alkaloids: Org. Synth. Coll., 9, 176 (1998):
- Kristensen, T. E. et al.: Eur. J. Org. Chem., 30, 5185 (2009); Liu, W. et al.: You. Xua., 26, 518 (2006);
- Starting material for the enantioselective synthesis of 2,6-disubstituted piperazines: Synthesis, 833 (1996), and for chiral ɑ-amino phosphonates: Org. Synth., 75, 19 (1997).
- Starting material for the enantioselective synthesis of 2,6-disubstituted piperazines: Synthesis, 833 (1996), and for chiral ɑ-amino phosphonates: Org. Synth., 75, 19 (1997).
安全信息
- H315 Causes skin irritation 会刺激皮肤
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- S22 Do not breathe dust 不要吸入粉尘；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
