4-Methyl-3-Nitroaniline 4-甲基-3-硝基苯胺

CAS 119-32-4 MFCD00007910

化学结构图

119-32-4
SMILES: Cc1ccc(N)cc1[N+](=O)[O-]

化学属性

Mol. FormulaC7H8N2O2
Mol. Weight152
Melting Point74-77
Density1.312
Flash Point175°(347°F)
TSCAYes
Boiling Point169 °C (21 mmHg)
Solubility溶于乙醇、浓硫酸、苯。

别名和识别编码

Chemical Name4-Methyl-3-Nitroaniline
CAS Number119-32-4
Alfabeta NameMETHYLNITROANILINE 43---
MDL NumberMFCD00007910
Synonym 1-AMINO-4-METHYL-2-NITROBENZENE 2-Nitro-4-aminotoluene 2-Nitro-4-toluidine 2-硝基-4-甲苯胺 3-NITRO-4-METHYLANILINE 3-NITRO-P-TOLUIDINE 3-Nitro-4-methylaniline 3-Nitro-p-toluidine 3-硝基-4-甲基苯胺 3-硝基对甲苯胺 4- 4-Amino-1-methyl-2-nitrobenzene, 3-Nitro-p-toluidine 4-Amino-2-nitrotoluene 4-METHYL-3-NITROBENZENAMINE 4-Methyl-3-nitroaniline 4-Methyl-3-nitrobenzenamine 4-氨基-2-硝基甲苯 4-甲基-2-硝基苯胺 4-胺-2-硝甲苯 5-Nitro-4-toluidine m-Nitro-p-toluidine p-Toluidine, 3-nitro- Benzenamine, 4-methyl-3-nitro- FAST RED GL BASE MNPT m-Nitro-p-toluidine {} {} {} {} {Chemicalbook}
PubChem Substance ID87573636
EC Number204-314-0
Beilstein Registry Number638984
Reaxys-RN638984
Chemical Name Translation4-甲基-3-硝基苯胺
Wiswesser Line NotationZR D1 CNW
LabNetwork Molecule IDLN00174013
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分类

  • {SNA} Additional Standards, Alpha Sort, Amines, Analytical Standards, Aromatics, Chemical Class, Chromatography, Environmental Standards, M, Nitro Compounds, Organic Pollutant Standards, Volatiles & Semivolatiles, Volatiles/ Semivolatiles, 分析/色谱
  • Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {SNA} Additional Standards, Alpha Sort, Amines, Analytical Standards, Aromatics, Chemical Class, Chr

相关文献及参考

  • Beil. 12 ,996
  • Aldrich MSDS 1 , 1275:C / Corp MSDS 1 (2), 2389:B / FT-IR 1 (1), 1364:A / FT-IR 2 (2), 2304:D / FT-NMR 1 (2), 741:B / IR-Spectra (3), 824:B / IR-Spectra (2), 722:C / NMR-Reference 2 (1), 1167:B / RegBook 1 (1), 1583:A / Sax 6 , 2065 / Structure Index 1 , 246:A:8
  • Short: III/5a Title: Structure Data of Organic Crystals: C ... C 13 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5a Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-05177-0 Internet Resource: DOI:10.1007/b19970 RefComment: XXI, 736 pages, and VII, 890 pages. Hardcover Abstract: Volume III/5 offers a compitation as complete as possible of the space groups and lattice con-stants of all crystals which have been studied by means of X-rays, neutron and electron diffraction.
  • Short: IV/4 Title: High-Pressure Properties of Matter Author: Beggerow, G. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/4 Year: 1980 ISBN: 3-540-09370-2 ISBN: 978-3-540-09370-1 Internet Resource: DOI:10.1007/b90280 RefComment: 589 figs., VIII, 427 pages. Hardcover Abstract: The main topics are pressure dependences of phase equilibria, compressibility, thermal and caloric properties, transport phenomena, static and magnetic properties, optical phenomena, kinetic phenomena, and systems in the neighbourhood and above the critical area.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Warnings 危化品目录(2015) IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H311+H331
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes 6.1 T,N T,N,Xi
RTECSXU8227000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P302+P350
  • P304+P340+P311
  • P305+P351+P338
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R51/53
UN Number 2660
Packing GroupIII
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6860 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku,"
   Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu
   Praha, Czechoslovakia, 1972  Volume(issue)/page/year: -,133,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04522

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 3200 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   21,315,1972

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 ug/plate
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 13,1,1982

Restrict 危险品

其他信息

  • 灭火剂:二氧化碳、干粉、砂土、雾状水
  • MSDS 信息:间硝基对甲苯胺(119-32-4).msds
  • MOL 文件:119-32-4.mol
  • 图谱信息:4-甲基-3-硝基苯胺(119-32-4)质谱(MS) 4-甲基-3-硝基苯胺(119-32-4)核磁图( 1 HNMR) 4-甲基-3-硝基苯胺(119-32-4)红外图谱(IR3) 4-甲基-3-硝基苯胺(119-32-4)核磁图( 13 CNMR) 4-甲基-3-硝基苯胺(119-32-4)红外图谱(IR2) 4-甲基-3-硝基苯胺(119-32-4)红外图谱(IR1)
  • 类别:有毒物品
  • TCI Shanghai:4-甲基-3-硝基苯胺 4-Methyl-3-nitroaniline,>;98.0%(T)(119-32-4)
  • 毒性分级:中毒
  • 急性毒性:口服-大鼠 LD50: 6860 毫克/公斤; 静脉-小鼠LD50: 180 毫克/公斤
  • 下游产品:碱性红 1 --> 6-甲氧基-3-吲哚甲酸 --> 6-溴吲哚-3-甲醛
  • 可燃性危险特性:遇明火可燃; 燃烧产生氮氧化物烟雾
  • Hazard Note:Irritant
  • 用途一:用作有机合成中间体
  • Alfa Aesar:4-甲基-3-硝基苯胺,98% 4-Methyl-3-nitroaniline, 98%(119-32-4)
  • 外观性质:橙红色针状结晶。
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • Sigma Aldrich:119-32-4(sigmaaldrich)
  • Acros Organics:4-甲基-3-硝基苯胺 4-Methyl-3-nitroaniline, 97%(119-32-4)
  • 4-甲基-3-硝基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0278 4-甲基-3-硝基苯胺 4-Methyl-3-nitroaniline 25G 578元 2010/06/21 127250250 4-甲基-3-硝基苯胺 4-Methyl-3-nitroaniline 97% 25 GR 707元 2010/06/21 127251000 4-甲基-3-硝基苯胺 4-Methyl-3-nitroaniline 97% 100 GR 2307元

系列性分类

  1. C7 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiols/Mercaptans - Sulfur Compounds
  1. C10 to C11 - Amines
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. M - Alphabetic
  5. META - METH - M
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C2 to C6

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