CAS 99-55-8 MFCD00007741-2-Methyl-5-nitroaniline 2-甲基-5-硝基苯胺 TAO{mole}

2-Methyl-5-nitroaniline 2-甲基-5-硝基苯胺

CAS 99-55-8 MFCD00007741

化学结构图

SMILES: Cc1ccc([N+](=O)[O-])cc1N

化学属性

Mol. Formula	C7H8N2O2
Mol. Weight	152.15
Melting Point	103-106°C
Density	1.51
TSCA	Yes
Solubility	<0.1 G/100 ML AT 19 ºC
Stability	对湿度敏感
Appearance	黄色棱形结晶。熔点107℃。溶于醇、醚和丙酮，微溶于水。
Redox	Oxidation
Boiling Point	294.61 °C at 760 mmHg

别名和识别编码

Chemical Name	2-Methyl-5-nitroaniline
CAS Number	99-55-8
Alfabeta Name	METHYLNITROANILINE 25---
MDL Number	MFCD00007741
Synonym	2-Methyl-5-nitrobenzenamine {LY} 2-Methyl-5-nitrobenzenamine {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {} {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {} {} {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-nitrobenzenamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {
Beilstein Registry Number	879021
PubChem Substance ID	7444
EC Number	202-765-8
Reaxys-RN	879021
Chemical Name Translation	2-甲基-5-硝基苯胺
Wiswesser Line Notation	ZR B1 ENW
LabNetwork Molecule ID	LN00150855
InChI	InChI=1S/C7H8N2O2/c1-5-2-3-6(9(10)11)4-7(5)8/h2-4H,8H2,1H3
Canonical SMILES	NC1=C(C)C=CC([N+]([O-])=O)=C1

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

Warnings IRRITANT

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P305+P351+P338
P332+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....
P301+P310
P273 Avoid release to the environment. 避免释放到环境中。
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P304+P340+P311
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P302+P350
P337+P313

WGK Germany3

GHS Symbol

Signal word

Hazard statements

H301+H311+H331
H351 Suspected of causing cancer 怀疑致癌
H331 Toxic if inhaled 吸入中毒
H311 Toxic in contact with skin 皮肤接触中毒
H301 Toxic if swallowed 吞食有毒
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

Hazard Codes T T,Xi

RTECSXU8225000

Safety Statements

S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R52/53
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

UN Number

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Packing GroupIII

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Class6.1

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 150 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Vascular - tumors
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-107,1978

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - mouse Embryo
DOSE/DURATION           : 160 ug/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   12,21,1988

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 33300 ng/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7(Suppl
   5),1,1985

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - rat Embryo
DOSE/DURATION           : 41 ug/plate
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 1,190,1981

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 4,163,1982

其他信息

毒性分级:低毒
急性毒性:参考值: 口服-大鼠 LD50: 6860 毫克/公斤
Hazard Note:Irritant
可燃性危险特性:明火可燃; 遇热分解放出有毒苯胺和氮氧化物气体
灭火剂:雾状水、泡沫、砂土、二氧化碳
方法一:采用邻甲苯胺为原料，经成盐、硝化、水析、溶解脱色、中和及脱水干燥而得。将相对密度为1.4的硝酸冷至20℃以下，在搅拌下加入干粉状的邻甲基乙酰苯胺，温度控制在70℃以下，冷却得黄色固体。将其加入硫酸回流，2h后冷却滤去不溶物，在40℃以下用40%氢氧化钠中和至pH=1-2，得黄色结晶。过滤、水洗，用乙醇重结晶即得5-硝基邻甲苯胺。原料消耗定额：邻甲苯胺876kg/t、硫酸（100%）4350kg/t、硝酸（98%）520kg/t、纯碱（98%）1700kg/t、活性炭1kg/t。
类别:有毒物品
用途三:该品是坚固大红等染料的中间体。主要用作棉织物的染色和印花的显色剂（最主要用于染大红色布，即旗红布），也可用于丝绸和锦纶织物的染色。还可作有机颜料的中间体。
溶于醇、醚和丙酮，不溶于水。
Alfa Aesar:2-甲基-5-硝基苯胺,99% 2-Methyl-5-nitroaniline, 99%(99-55-8)
图谱信息:2-氨基-4-硝基甲苯(99-55-8)红外图谱(IR2) 2-氨基-4-硝基甲苯(99-55-8)红外图谱(IR3) 2-氨基-4-硝基甲苯(99-55-8)核磁图( 13 CNMR) 2-氨基-4-硝基甲苯(99-55-8)核磁图( 1 HNMR) 2-氨基-4-硝基甲苯(99-55-8)红外图谱(IR1) 2-氨基-4-硝基甲苯(99-55-8)质谱(MS)
储运特性:库房通风低温干燥; 与食品原料分开储运
用途二:用于有机合成
Acros Organics:2-氨基-4-硝基甲苯(2-甲基-5-硝基苯胺) 2-Methyl-5-nitroaniline, 99%(99-55-8)
上游原料:硝酸 --> 邻甲基苯胺 --> 2-甲基乙酰苯胺
下游产品:颜料红 8 --> 3-溴-6-氨基吲唑 --> 3-碘-6-硝基吲唑 --> 3-氯-6-氨基吲唑 --> 3-氯-6-硝基吲唑 --> 坚固大红G --> 3-溴-6-硝基吲唑 --> 6-羟基吲唑 --> 涂料大红 --> 6-硝基吲唑 --> 分散黄S-3GL
Sigma Aldrich:99-55-8(sigmaaldrich)
MSDS 信息:C.I. 37105(99-55-8).msds
TCI Shanghai:2-甲基-5-硝基苯胺 2-Methyl-5-nitroaniline,>;98.0%(GC)(99-55-8)
用途一:作为冰染染料显色基用作棉织物的染色和印花，还可作为有机颜料和染料的中间体
MOL 文件:99-55-8.mol
2-氨基-4-硝基甲苯价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 N0115 2-甲基-5-硝基苯胺 2-Methyl-5-nitroaniline 500G 2460元 2014/06/02 N0115 2-甲基-5-硝基苯胺 2-Methyl-5-nitroaniline 25G 292元 2010/06/21 364911000 2-氨基-4-硝基甲苯 2-Methyl-5-nitroaniline 96% 100 GR 349元