CAS 99-30-9 MFCD00007677-2,6-Dichloro-4-Nitroaniline 2,6-二氯-4-硝基苯胺 TAO{mole}

2,6-Dichloro-4-Nitroaniline 2,6-二氯-4-硝基苯胺

CAS 99-30-9 MFCD00007677

化学结构图

SMILES: Nc1c(Cl)cc([N+](=O)[O-])cc1Cl

化学属性

Mol. Formula	C6H4Cl2N2O2
Mol. Weight	207.01
Melting Point	190-192 °C
TSCA	Yes
Boiling Point	130 °C at 2 mmHg
Flash Point	149.1±26.5 °C
Solubility	1 g/L (60 °C)
Density	1.624

别名和识别编码

Chemical Name	2,6-Dichloro-4-Nitroaniline
MDL Number	MFCD00007677
CAS Number	99-30-9
Synonym	2,6-Dichloro-4-nitroaniline {LY} 2,6-Dichloro-4-nitroaniline {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {} {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {} {} {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {} {} {} {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dichloro-4-nitroaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {}
PubChem Substance ID	87567068
Beilstein Registry Number	1459581
EC Number	202-746-4
Chemical Name Translation	2,6-二氯-4-硝基苯胺
Reaxys-RN	1459581
Wiswesser Line Notation	ZR BG FG DNW
LabNetwork Molecule ID	LN00225197
InChI	InChI=1S/C6H4Cl2N2O2/c7-4-1-3(10(11)12)2-5(8)6(4)9/h1-2H,9H2
Canonical SMILES	NC1=C(C=C([N+]([O-])=O)C=C1Cl)Cl

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产品应用

用作重要的染料中间体，用于分散黄棕3GL、分解黄棕2RFL、分散棕3R、分散棕5R。在50年代末期，开始作为杀菌剂商品出售。作为广谱性农用杀菌剂，可防治甘薯、洋麻、黄瓜、莴苣、棉花、烟草、草莓、马铃薯等的菌核病；甘薯、棉花及桃子的软腐病；马铃薯和西红柿的晚疫病；杏、扁桃及苹果的枯萎病；小麦的黑穗病；蚕豆花腐病。氯硝胺可与大多数杀虫剂、杀菌剂、波尔多合剂及石灰硫磺等混配使用。

安全信息

RTECSBX2975000

GHS Symbol

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P301+P310
P302+P350
P302+P352+P332+P313+P362+P364
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用

Hazard statements

H300 Fatal if swallowed 吞食致命
H303 May be harmfully swallowed 吞食可能有害
H310 Fatal in contact with skin 皮肤接触致命
H330 Fatal if inhaled 吸入致命
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。

WGK Germany3

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Signal word Danger

Safety Statements

S24 Avoid contact with skin 避免皮肤接触；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S37 Wear suitable gloves 戴适当手套；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
R33 Danger of cumulative effects 有累积作用的危险
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R51/53

Hazard Codes 9

Packing GroupIII

Hazard Class6.1(b)

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

UN Number 3077

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 80 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2400 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - ataxia
REFERENCE :
   TSCAT* Office of Toxic Substances Report.  (U.S. Environmental Protection
   Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460)
   Volume(issue)/page/year: OTS 206512

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >21600 mg/m3/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,265,1991

TYPE OF TEST            : LD50 - Let

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,265,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,87,1971

TYP

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Mold - Aspergillus nidulans
DOSE/DURATION           : 14 umol/L
REFERENCE :
   PHYTAJ Phytopathology.  (American Phytopathological Soc., 3340 Pilot Knob
   Rd., St. Paul, MN 55121) V.1-    1911-  Volume(issue)/page/year: 66,217,1976

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   19(Suppl 21),2,1992

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Mold - Aspergillus nidulans
DOSE/DURATION           : 38 umol/L
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 31,81,1979

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2500 ug/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

其他信息

毒性分级:中毒
用途一:用作染料及有机颜料中间体
MSDS 信息:氯硝胺(99-30-9).msds
图谱信息:2,6-二氯-4-硝基苯胺(99-30-9)质谱(MS) 2,6-二氯-4-硝基苯胺(99-30-9)红外图谱(IR2) 2,6-二氯-4-硝基苯胺(99-30-9)红外图谱(IR1)
难溶于水，易溶于乙醇，对光和热稳定，可升华
海关编码:29214210
灭火剂:砂土、干粉、泡沫
储运特性:库房通风低温干燥; 与食品原料分开储运
类别:农药
急性毒性:口服-大鼠 LD50: 2400 毫克/公斤; 口服-小鼠 LD50: 1500 毫克/公斤
方法一:主要有下列方法：对硝基苯胺在盐酸-冰醋酸中氯化；2-磺酸基-4-硝基苯胺氯化；对硝基苯胺在稀盐酸及次氯酸钠中氯化；对硝基苯胺在过氧化氢及盐酸中反应；对硝基苯胺在浓硫酸中先磺化再氯化；对硝基苯胺在浓盐酸中与氯酸钠反应。
用途二:用作重要的染料中间体，用于分散黄棕3GL、分解黄棕2RFL、分散棕3R、分散棕5R。在50年代末期，开始作为杀菌剂商品出售。作为广谱性农用杀菌剂，可防治甘薯、洋麻、黄瓜、莴苣、棉花、烟草、草莓、马铃薯等的菌核病；甘薯、棉花及桃子的软腐病；马铃薯和西红柿的晚疫病；杏、扁桃及苹果的枯萎病；小麦的黑穗病；蚕豆花腐病。氯硝胺可与大多数杀虫剂、杀菌剂、波尔多合剂及石灰硫磺等混配使用。
TCI Shanghai:2,6-二氯-4-硝基苯胺 2,6-Dichloro-4-nitroaniline,>;97.0%(GC)(99-30-9)
外观性质:原药为黄色针状结晶。
可燃性危险特性:受热分解有毒氯化物、氧化氮气体
Alfa Aesar:2,6-二氯-4-硝基苯胺,95% 2,6-Dichloro-4-nitroaniline, 95%(99-30-9)
2,6-二氯-4-硝基苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 D0385 2,6-二氯-4-硝基苯胺 2,6-Dichloro-4-nitroaniline 500G 787元 2014/06/02 D0385 2,6-二氯-4-硝基苯胺 2,6-Dichloro-4-nitroaniline 25G 124元 2010/06/21 113491000 2,6-二氯-4-硝基苯胺 2,6-Dichloro-4-nitroaniline 95% 100 GR 277元
上游原料:盐酸 --> 过氧化氢 --> 氯 --> 次氯酸钠 --> 4-硝基苯胺 --> 稀盐酸
下游产品:3,5-二氯苯胺 --> 分散黄棕S-2RFL --> 分散橙 30 --> 分散黄棕 S-3GL --> 分散橙 76 --> 分散黄 163 --> 分散黄棕H-2RL --> 分散蓝S-BBL --> 分散棕 1 --> 分散蓝 CR-E --> 分散棕 19 --> 阳离子橙 GLH
Sigma Aldrich:99-30-9(sigmaaldrich)
Acros Organics:2,6-二氯-4-硝基苯胺 2,6-Dichloro-4-nitroaniline, 95%(99-30-9)
MOL 文件:99-30-9.mol