2,4,5-Trichloroaniline 2,4,5-三氯苯胺
CAS 636-30-6 MFCD00007662
化学结构图
SMILES: Nc1cc(Cl)c(Cl)cc1Cl
化学属性
| Mol. Formula | C6H4Cl3N |
|---|---|
| Mol. Weight | 196 |
| Boiling Point | 270 |
| Melting Point | 93-95 |
| Flash Point | 175°(347°F) |
| TSCA | Yes |
| Solubility | 0.094 G/L (15 ºC) |
| Density | 1.54 |
别名和识别编码
| Chemical Name | 2,4,5-Trichloroaniline |
|---|---|
| CAS Number | 636-30-6 |
| Synonym | 2,4,5-trichloro-benzenamin 2,4,5-TRICHLOROANILINE PESTANAL 2,4,5-Trichloroaniline 2,4,5-三氯苯胺,97% 2,4,5-三氯苯胺 2,4,5-Trichloroaniline, tech., 97% 2,4,5-TRICHLOROANILINE 1-AMINO-2,4,5-TRICHLORO-BENZENE 2,4,5-Trichloroaniline, 97%,tech. 2,4,5-Trichlorobenzenamine 2,4,5-Trichloraniline Benzenamine, 2,4,5-trichloro- Aniline, 2,4,5-trichloro- TIMTEC-BB SBB003585 2,4,5-Trichloroaniline,97% 1-氨基-2，4，5-三氯苯 NSC 64139 2,4,5-trichloro-aniline AKOS BBS-00003553 2,4,5-TRICHLOROBENZENAMINE 2,4,5-Trichloraminobenzol 2，4，5-三氯苯胺 |
| MDL Number | MFCD00007662 |
| PubChem Substance ID | 87576338 |
| Beilstein Registry Number | 12,627 |
| EC Number | 211-254-9 |
| Reaxys-RN | 879091 |
| Chemical Name Translation | 2,4,5-三氯苯胺 |
| LabNetwork Molecule ID | LN00226425 |
| InChI | InChI=1S/C6H4Cl3N/c7-3-1-5(9)6(10)2-4(3)8/h1-2H,10H2 |
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专业采购外包团队在线服务
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分类
- {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Amines, Analytical Standards, Analytical/Chromatography, Aromat
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- {SNA} Amines, Building Blocks, C6, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
- {SNA} Alphabetical Index of Analytical Standards, Chemical Class, All alphabetically sorted, Amines, Analytical Standards, Analytical/Chromatography, Aromatics, Chromatography, Environmental Standards, Pesticides & Metabolites, Q-Z, T, TP - TZ
产品应用
- 有机合成和燃料的中间体。
相关文献及参考
- Beilstein:12,627
- Kreutzberger, A. et al.: Arch. Pharm., 320, 37 (1987); Lee, K.S. et al.: Han. Nong. Hakh., 22, 109 (1979); Peters, A.T. et al.: Dyes Pigm., 30, 291 (1996);
- Short: EINECS
- Short: III/20b
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P310+P330
- P302+P350
- P302+P352+P312+P361+P364
- P304+P340+P311
- P305+P351+P338
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H301 Toxic if swallowed 吞食有毒
- H301+H311+H331
- H311 Toxic in contact with skin 皮肤接触中毒
- H331 Toxic if inhaled 吸入中毒
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R33 Danger of cumulative effects 有累积作用的危险
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R50/53
其他信息
- 海关编码:29214210
- 水中溶解度:0.094 g/l (15°C)，溶于醇，醚和二硫化碳，难溶于石油醚。能随水蒸汽挥发。
- 图谱信息:2,4,5-三氯苯胺(636-30-6)Raman光谱 2,4,5-三氯苯胺(636-30-6)质谱(MS) 2,4,5-三氯苯胺(636-30-6)红外图谱(IR1) 2,4,5-三氯苯胺(636-30-6)核磁图( 13 CNMR) 2,4,5-三氯苯胺(636-30-6)红外图谱(IR2)
- 方法一:将1500kg95%硫酸、3000kg1,2,4-三氯苯加入硝化锅，搅拌，于40-50℃加入混酸（HNO335%，H2SO465%）300kg，于48-50℃搅拌2h，然后加水150kg稀释成75%硫酸，分离出上层油状物，水洗，得三氯硝基苯粗品3650kg。将水125L、铁粉125kg、苯150kg、纯三氯硝基苯150kg和甲酸1kg投入还原锅，加热煮沸，必要时补加铁粉，还原反应3h后，检查苯层相对密度达0.83（50℃）为止。蒸馏出苯，减压蒸馏出2,4,5-三氯苯胺，收率84%。
- 2,4,5-三氯苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0374 2,4,5-三氯苯胺 2,4,5-Trichloroaniline 500G 1210元 2014/06/02 T0374 2,4,5-三氯苯胺 2,4,5-Trichloroaniline 25G 169元 2010/06/21 139380250 2,4,5-三氯苯胺 2,4,5-Trichloroaniline 97%, tech. 25 GR 326元
- Acros Organics:2,4,5-三氯苯胺 2,4,5-Trichloroaniline, tech., 97%(636-30-6)
- 用途三:有机合成和燃料的中间体。
- 上游原料:甲醇 --> 硫酸 --> 硝酸 --> 铁粉 --> 三氯苯
- 用途二:有机合成和染料的中间体。2,4,5-三氯苯胺经重氮化后，与色酚AS-D在弱酸性介质中偶合，可制得颜料永固红FGR（C.I.Pigment Red 112）。永固红FGR用于油墨、乳化漆、水浆涂料，也可用于纸、漆布和皮等的着色及涂料印花。
- Alfa Aesar:2,4,5-三氯苯胺,97% 2,4,5-Trichloroaniline, 97%(636-30-6)
- 外观性质:浅黄色针状结晶。
- Hazard Note:Toxic
- MOL 文件:636-30-6.mol
- Sigma Aldrich:636-30-6(sigmaaldrich)
- 用途一:主要用作分散染料中间体
- TCI Shanghai:2,4,5-三氯苯胺 2,4,5-Trichloroaniline,>;98.0%(GC)(636-30-6)
- MSDS 信息:2,4,5-三氯苯胺(636-30-6).msds
