CAS 583-68-6 MFCD00007635-2-Bromo-4-methylaniline 2-溴-4-甲基苯胺 TAO{mole}

2-Bromo-4-methylaniline 2-溴-4-甲基苯胺

CAS 583-68-6 MFCD00007635

化学结构图

SMILES: Cc1ccc(N)c(Br)c1

化学属性

Mol. Formula	C7H8BrN
Mol. Weight	186.05
Refractive index	1.6000 to 1.6030
Boiling Point	240°C at 760 mmHg
Density	1.5
Melting Point	14-16°C
Flash Point	110°C
TSCA	Yes
Appearance	无色液体。熔点26℃，沸点240℃，相对密度1.500，折光率1.6020。与醇、醚混溶，不溶于水。
pH	:A

别名和识别编码

Chemical Name	2-Bromo-4-methylaniline
CAS Number	583-68-6
Alfabeta Name	BROMOMETHYLANILINE 24---
MDL Number	MFCD00007635
Synonym	2-Bromo-4-methylaniline {LY} 2-Bromo-4-methylaniline {} {LY} 2-Bromo-4-methylaniline {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {} { {} {} {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	11422
EC Number	209-515-7
Beilstein Registry Number	1931711
Reaxys-RN	1931711
Chemical Name Translation	2-溴-4-甲基苯胺
InChIKey	UVRRJILIXQAAFK-UHFFFAOYSA-N
Wiswesser Line Notation	ZR BE D1
LabNetwork Molecule ID	LN00009140
InChI	InChI=1S/C7H8BrN/c1-5-2-3-7(9)6(8)4-5/h2-4H,9H2,1H3
Canonical SMILES	C1=C(C(=CC=C1C)N)Br

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安全信息

Warnings IRRITANT

GHS Symbol

WGK Germany3

Hazard statements

H331 Toxic if inhaled 吸入中毒
H311 Toxic in contact with skin 皮肤接触中毒
H301 Toxic if swallowed 吞食有毒
H301+H311+H331

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes T,Xi T

RTECSXU4300000

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310+P330
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P332+P313
P302+P352+P312+P361+P364
P501 Dispose of contents/container to..… 处理内容物/容器.....
P405 Store locked up. 上锁保管。
P304+P340+P311
P305+P351+P338+P337+P313
P403+P233

Signal word

Safety Statements

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R33 Danger of cumulative effects 有累积作用的危险
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

UN Number UN2810

Packing GroupIII

Hazard Class6.1

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 umol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 77,317,1980

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

方法一:将对甲苯胺与冰乙酸加热回流2h转化为N-乙酰对甲苯胺，冷却至45℃，滴加溴，溴化反应控制在50-55℃下进行。将反应物注入亚硫酸钠水溶液中，析出3-溴-4-乙酰氨基甲苯。然后用浓盐酸水解，所得盐酸盐与氢氧化钠溶液作用，即得游离的2-溴-4-甲基苯胺。产率51-57%。
储运特性:库房通风低温干燥
灭火剂:水,二氧化碳、砂土、泡沫、砂土
MOL 文件:583-68-6.mol
Hazard Note:Irritant/Toxic
图谱信息:2-溴-4-甲基苯胺(583-68-6)核磁图( 1 HNMR) 2-溴-4-甲基苯胺(583-68-6)红外图谱(IR2) 2-溴-4-甲基苯胺(583-68-6)核磁图( 13 CNMR) 2-溴-4-甲基苯胺(583-68-6)红外图谱(IR1) 2-溴-4-甲基苯胺(583-68-6)质谱(MS)
上游原料:亚硫酸钠 --> 4-甲基乙酰苯胺 --> 4-乙酰氨基甲苯
2-溴-4-甲基苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B0540 2-溴-4-甲基苯胺 2-Bromo-4-methylaniline 25G 787元 2010/06/21 154240500 2-溴-4-甲基苯胺 2-Bromo-4-methylaniline 98% 50 ML 2259元 2010/06/21 154240100 2-溴-4-甲基苯胺 2-Bromo-4-methylaniline 98% 10 ML 617元
用途一:有机合成中间体。
Alfa Aesar:2-溴-4-甲基苯胺,99% 2-Bromo-4-methylaniline, 99%(583-68-6)
下游产品:3-溴甲基苯 --> 5-甲基吲哚 --> 2-溴-4-甲基苯酚
海关编码:29214300
TCI Shanghai:2-溴-4-甲基苯胺 2-Bromo-4-methylaniline,>;98.0%(GC)(583-68-6)
MSDS 信息:4-Amino-3-bromotoluene(583-68-6).msds
类别:有毒物品
Acros Organics:2-溴-4-甲基苯胺 2-Bromo-4-methylaniline, 98%(583-68-6)
可燃性危险特性:明火可燃; 受热分解有毒溴化物气体