Ethyl carbazate 肼基甲酸乙酯
CAS 4114-31-2 MFCD00007595
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Protected Amines
- {SA} Building Blocks, Carbonyl Compounds, Chemical Synthesis, Hydrazides, Organic Building Blocks
相关文献及参考
- Reaction with methyl ketones, followed by treatment with SOCl2, leads to 4-substituted 1,2,3-thiadiazoles: J. Am. Chem. Soc., 77, 5359 (1955). In the presence of base, these readily lose N2 to give alkynethiolates: Can. J. Chem., 46, 1057 (1968):
- Forms crystalline ethoxycarbonyl hydrazones with aldehydes and ketones. With o-acylphenols, Pb(OAc)4 treatment of the resulting hydrazone results in replacement of the phenolic OH with ethoxycarbonyl, providing a route to ethyl o-acylbenzoates: Tetrahedron Lett ., 31, 6781 (1990).
- More recently, this sequence has been used in the synthesis of dendrimers from 1,3,5-triacetylbenzene: J. Chem. Soc., Perkin 1, 2203 (1994).
安全信息
GHS Symbol
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- R25 Toxic if swallowed 吞咽有毒
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P310+P330
- P301+P316
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P319
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H300 Fatal if swallowed 吞食致命
- H301 Toxic if swallowed 吞食有毒
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- 下游产品:4-(1,2,3-噻唑-4-基)苯甲酰氯 --> 4-(1,2,3-噻二唑-4-基)苄胺盐酸盐 --> 4-甲基-5-氰基-1,2,3-噻重氮 --> 4-(4-氯苯基)-1,2,3-硫二唑-5-胺 --> 4-苯基-5-氨基-1,2,3-噻重氮 --> 4-(1,2,3-噻重氮-4-基)苯甲醛 --> N-苯基-N-1,2,3-噻二唑-5-脲 --> 4-甲基-1,2,3-噻重氮-5-甲酰胺 --> 4-(4-甲氧基苯基)-1,2,3-噻重氮-5-胺 --> 4-4-(三氟甲基)苯基-1,2,3-噻二唑-5-胺 --> 4-甲基-1,2,3-噻二唑-5-羧酸 --> 4-(4-溴苯基)-1,2,3-噻重氮 --> 4-(1,2,3-噻二唑-4-基)苯甲酸 --> 4-(1,2,3-噻重氮-4-基)苯酚 --> 4-(1,2,3-噻二唑)苯胺 --> 4-异丙基-1,2,3-噻重氮-5-羧酸 --> 4-(4-甲苯基)-1,2,3-噻重氮 --> (1,2,3-噻重氮-4-基)甲醇 --> 4-(4-硝基苯基)-1,2,3-噻二唑 --> 4-(4-甲氧基苯基)-1,2,3-噻重氮 --> 4-[4-(1,2,3-噻重氮)]苯甲腈 --> 4-(4-溴苯基)1,2,3-噻唑 --> 4-甲基-1,2,3-噻二唑-5-羰酰氯 --> 4-异丙基-1,2,3-噻重氮-5-羧酸乙酯 --> 1,2,3-噻重氮-4-羧酸 --> 4-甲基-1,2,3-噻重氮-5-羧酸乙酯 --> 1,2,3-噻重氮-4-羧酸乙酯 --> 卡浊拉嗪
- TCI Shanghai:肼基甲酸乙酯 Ethyl Carbazate,>;99.0%(T)(4114-31-2)
- 方法一:将无水肼和碳酸二乙酯混合,在蒸汽浴上加热3.5h,减压蒸馏,收集102-103(2.4kPa)馏分,即产品肼基甲酸甲酯。
- Acros Organics:肼基甲酸乙酯 Ethyl carbazate, 97%(4114-31-2)
- Sigma Aldrich:4114-31-2(sigmaaldrich)
- 用途一:有机合成中间体。
- 上游原料:碳酸二乙酯 --> 肼(无水) --> 肼基甲酸甲酯
- 检测方法:T
- Alfa Aesar:肼基甲酸乙酯,97% Ethyl carbazate, 97%(4114-31-2)
- 海关编码:29280090
- MOL 文件:4114-31-2.mol
- MSDS 信息:Carboethoxy hydrazine(4114-31-2).msds
- 敏感性:Moisture Sensitive
- 肼基甲酸乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010161 肼基甲酸乙酯 100g 400元 2011/04/16 C1097 肼基甲酸乙酯 Ethyl Carbazate 25G 291元 2011/04/16 C1097 肼基甲酸乙酯 Ethyl Carbazate 500G 2870元