Silver p-toluenesulfonate 对甲苯磺酸银
CAS 16836-95-6 MFCD00007511
化学结构图
SMILES: [Ag+].CC1=CC=C(C=C1)S([O-])(=O)=O
化学属性
| Mol. Formula | CH3C6H4SO3Ag |
|---|---|
| Mol. Weight | 279.06 |
| TSCA | Yes |
别名和识别编码
| Chemical Name | Silver p-toluenesulfonate |
|---|---|
| Synonym | 对甲苯磺酸 银盐 甲苯磺酸银 甲苯磺酸银 Silver tosylate Silver tosylatep-Toluenesulfonic acid silver salt 对甲苯磺酸 银盐 对甲苯磺酸银 |
| MDL Number | MFCD00007511 |
| Beilstein Registry Number | 3598937 |
| EC Number | 240-859-0 |
| CAS Number | 16836-95-6 |
| PubChem Substance ID | 24850577 |
| Chemical Name Translation | 对甲苯磺酸银 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Silver Additives, Silver Catalysts, Silver Complexes, Silver Salts, 材料科学
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis,
相关文献及参考
- Silver salt soluble in many organic solvents; useful, e.g. in promotion of the leaving ability of halogens. For use in the conversion of alkyl halides to alkyl tosylates, see: J. Am. Chem. Soc., 81, 4113 (1959); J. Chem. Soc., 6748 (1965).
- Induces carbocation rearrangements in alkyl halides, e.g. promotes the stereospecific disrotatory ring-opening of the cyclopropyl cation resulting from ionization of gem-dibromocyclopropanes: J. Org. Chem., 41, 384 (1976).
- For conversion of benzylic bromides to styrenes, see: Bul. Chem. Soc. Jpn., 66, 589 (1993).
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R50 Very toxic to aquatic organisms 对水生生物极毒
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
