CAS 7669-54-7 MFCD00007128-2-Nitrobenzenesulfenyl Chloride 2-硝基苯亚磺酰氯 TAO{mole}

2-Nitrobenzenesulfenyl Chloride 2-硝基苯亚磺酰氯

CAS 7669-54-7 MFCD00007128

化学结构图

SMILES: O=[N+]([O-])c1ccccc1SCl

化学属性

Mol. Formula	C6H4ClNO2S
Mol. Weight	189.62
Melting Point	70-75 °C
TSCA	Yes
Solubility	分解
Boiling Point	350 °C at 760 mmHg

别名和识别编码

Chemical Name	2-Nitrobenzenesulfenyl Chloride
Synonym	2-Nitrophenyl hypochlorothioite {LY} 2-Nitrophenyl hypochlorothioite {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00007128
CAS Number	7669-54-7
EC Number	231-644-2
Beilstein Registry Number	473741
Chemical Name Translation	2-硝基苯亚磺酰氯
Reaxys-RN	473741
PubChem Substance ID	24319
InChIKey	NTNKNFHIAFDCSJ-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00730736
InChI	InChI=1S/C6H4ClNO2S/c7-11-6-4-2-1-3-5(6)8(9)10/h1-4H
Canonical SMILES	ClSC1=CC=CC=C1[N+]([O-])=O

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安全信息

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Packing GroupII

UN Number 3261

Risk Statements

R34 Causes burns 会导致灼伤

Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Codes 8

Hazard Class8

GHS Symbol

Signal word Danger

Precautionary statements

P234 Keep only in original container. 只保留在原来的容器中。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P301+P330+P331+P310
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
P405 Store locked up. 上锁保管。
P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H290 May be corrosive to metals 可能腐蚀金属。
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H318 Causes serious eye damage 严重伤害眼睛

其他信息

MOL 文件:7669-54-7.mol
上游原料:四氯化碳 --> 1,3-二硝基苯
图谱信息:2-硝基苯硫氯(7669-54-7)红外图谱(IR1)
TCI Shanghai:2-硝基苯硫氯 2-Nitrophenylsulfenyl Chloride [N-Protecting Agent for Peptides Research],>;95.0%(T)(7669-54-7)
2-硝基苯硫氯价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 N0363 2-硝基苯硫氯[肽研究用N-保护试剂] 2-Nitrophenylsulfenyl Chloride [N-Protecting Agent for Peptides Research] 25G 1300元 2014/06/02 N0363 2-硝基苯硫氯[肽研究用N-保护试剂] 2-Nitrophenylsulfenyl Chloride [N-Protecting Agent for Peptides Research] 100G 3880元 2010/06/21 161330500 2-硝基苯硫氯 2-Nitrobenzenesulfenyl chloride 99% 50 GR 2480元
Acros Organics:2-硝基苯次磺酰氯 2-Nitrobenzenesulfenyl chloride, 99%(7669-54-7)
用途二:肽合成的N-保护基。
Alfa Aesar:2-硝基苯亚磺酰氯,98% 2-Nitrobenzenesulfenyl chloride, 98%(7669-54-7)
方法一:将干燥氯气通入二硫-2,2-二（硝基苯）、四氯化碳和少许碘的混合物中，温度保持在50-60℃。反应液冷至5℃，即结晶析出，得邻硝基苯硫氯，收率61-71%。
Sigma Aldrich:7669-54-7(sigmaaldrich)
敏感性:Moisture Sensitive
用途一:用作医药、染料中间体
MSDS 信息:2-Nitrophenylsulfenyl chloride(7669-54-7).msds